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ChemicalBook > Product Catalog >Inorganic chemistry >Inorganic salts >Metal halide and Halogen salt >Metal chlorides and salt >Bismuth trichloride

Bismuth trichloride

Bismuth trichloride Structure
CAS No.
7787-60-2
Chemical Name:
Bismuth trichloride
Synonyms
BiCl3;BISMUTH(III) CHLORIDE;BISMUTH CHLORIDE;Trichlorobismuthane;Trichlorobismuth;Bismuth(III) chL;BISMUTH TRICHLORIDE;BISMUTH(+3)CHLORIDE;Bismuth(Ⅲ) chloride;trichloro-bismuthin
CBNumber:
CB3205675
Molecular Formula:
BiCl3
Molecular Weight:
315.34
MOL File:
7787-60-2.mol
MSDS File:
SDS
Modify Date:
2024/7/2 16:39:54
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Bismuth trichloride Properties

Melting point 230-232 °C(lit.)
Boiling point 447 °C(lit.)
Density 4.75
Flash point 430°C
storage temp. no restrictions.
solubility Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.
form powder
color White to beige or gray
Specific Gravity 4.75
Odor Hydrochloric acid odor
Water Solubility decomposes
Sensitive Hygroscopic
Sublimation 430 ºC
Merck 14,1262
Stability Stable, but reacts with water, moisture.
InChIKey JHXKRIRFYBPWGE-UHFFFAOYSA-K
CAS DataBase Reference 7787-60-2(CAS DataBase Reference)
NIST Chemistry Reference Bismuth trichloride(7787-60-2)
EPA Substance Registry System Bismuthine, trichloro- (7787-60-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes  Xi
Risk Statements  36/38-36/37/38
Safety Statements  26-36-37/39
RIDADR  3260
WGK Germany  2
RTECS  EB2690000
TSCA  Yes
HS Code  2827 39 85
HazardClass  8
PackingGroup  III
Toxicity LD50 orally in Rabbit: 3334 mg/kg
NFPA 704
0
2 1

Bismuth trichloride price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 450723 Bismuth(III) chloride anhydrous, powder, 99.998% trace metals basis 7787-60-2 5G ₹8844.03 2022-06-14 Buy
Sigma-Aldrich(India) 470279 Bismuth(III) chloride AnhydroBeads?, ?10?mesh, 99.999% trace metals basis 7787-60-2 5G ₹12567.83 2022-06-14 Buy
Sigma-Aldrich(India) 450723 Bismuth(III) chloride anhydrous, powder, 99.998% trace metals basis 7787-60-2 25G ₹22137.13 2022-06-14 Buy
Sigma-Aldrich(India) 224839 Bismuth(III) chloride reagent grade, ≥98% 7787-60-2 25G ₹2760.38 2022-06-14 Buy
Sigma-Aldrich(India) 224839 Bismuth(III) chloride reagent grade, ≥98% 7787-60-2 100G ₹9623.43 2022-06-14 Buy
Product number Packaging Price Buy
450723 5G ₹8844.03 Buy
470279 5G ₹12567.83 Buy
450723 25G ₹22137.13 Buy
224839 25G ₹2760.38 Buy
224839 100G ₹9623.43 Buy

Bismuth trichloride Chemical Properties,Uses,Production

Chemical Properties

Bismuth trichloride is white crystal and crystalline powder

Physical properties

Yellowish-white crystalline solid; cubic crystals; hygroscopic; density 4.75g/cm3; melts at 230°C; vaporizes at 447°C; vapor pressure 5 torr at 242°C; reacts with water; soluble in acids, alcohol and acetone.

Uses

Bismuth trichloride used as catalyst for organic reactions.

Preparation

Bismuth chloride may be synthesized directly by passing chlorine over bismuth. Alternatively, the chloride salt may be prepared by adding hydrochloric acid to basic bismuth chloride and evaporating the solution:
Bi(OH)2Cl + 2HCl → BiCl3 + 2H2O
Also, the compound can be prepared by dissolving bismuth in concentrated nitric acid and then adding solid sodium chloride into this solution. Another method of preparation is treating the metal with concentrated hydrochloric acid:
2Bi + 6HCl → 2BiCl3 + 3H2.

Definition

Bismuth trichloride is a white deliquescent solid. It can be prepared by direct combination of bismuth and chlorine. Bismuth(III) chloride dissolves in excess dilute hydrochloric acid to form a clear liquid, but if diluted it produces a white precipitate of bismuth(III) chloride oxide (bismuthyl chloride, BiOCl): BiCl3 + H2O = BiOCl + 2HCl This reaction is often used as an exam ple of a reversible reaction and as a confirmatory test for bismuth during quantitative analysis. Bismuth(V) chloride does not form.

General Description

Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine.

Purification Methods

Sublime the trichloride under high vacuum, or dry it under a current of HCl gas, followed by fractional distillation, once under HCl and once under argon. It is deliquescent. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 621 1963.]

Bismuth trichloride Preparation Products And Raw materials

Raw materials

bismuth oxyperchlorate monohydrate Bismuth trioxide Bismuth Iodine monochloride Pyridine hydrochloride
Thionyl chloride
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Preparation Products

4-METHYL-2-OXO-2 H-CHROMENE-7-CARBALDEHYDE CHLOROETHANE Triphenylbismuth 7-BROMOMETHYL-4-METHYL-CHROMEN-2-ONE 4,7-DIMETHYLCOUMARIN
Selenium
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Bismuth trichloride Suppliers

Global( 415)Suppliers
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Spectrochem Private Limited 08048372608Ext 246 Maharashtra, India 1056 58 Inquiry
5 E Scientific 91-22-28016026 Maharashtra, India 137 58 Inquiry
Krishna International 91-22-9619795639 Maharashtra, India 88 58 Inquiry
Supplier Advantage
GLR Innovations 58
SYNOVA CHEMICALS 58
PERFECT CHEMICAL 58
JSK Chemicals 58
Otto Chemie Pvt Ltd 58
Satyam Pharma Chem Pvt Ltd 58
Rivashaa Agrotech Biopharma Pvt. Ltd. 58
Spectrochem Private Limited 58
5 E Scientific 58
Krishna International 58

Bismuth trichloride Spectrum

Bismuth trichloride(7787-60-2)IR1

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