ChemicalBook > Product Catalog >Organic Chemistry >Aldehydes >(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Structure
CAS No.
15186-48-8
Chemical Name:
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde
Synonyms
2,3-O-ISOPROPYLIDENE-D-GLYCERALDEHYDE;(4R)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBALDEHYDE;NSC 89869;EOS-61843;ane-4-carboxaL;4-carboxaldehyde;R-(+)-Solketaldehyde;(R)-(+)-2,2-Dimethyl;Gemcitabine Impurity 17;R-glyceraldehyde acetal
CBNumber:
CB9184468
Molecular Formula:
C6H10O3
Molecular Weight:
130.14
MOL File:
15186-48-8.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Properties

alpha 53.8 º (c=2, CHCl3)
Boiling point 139 °C (lit.)
Density 1.045 g/mL at 25 °C (lit.)
refractive index n20/D 1.454(lit.)
Flash point 143 °F
storage temp. -20°C
solubility Difficult to mix.
form Liquid
color Colorless to Pale Yellow
optical activity [α]22/D +53.8°, c = 2 in chloroform
CAS DataBase Reference 15186-48-8(CAS DataBase Reference)
NIST Chemistry Reference Acetone D-glyceraldehyde(15186-48-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS08
Signal word  Danger
Hazard statements  H227-H303-H333-H351
Precautionary statements  P201-P210e-P280-P403+P235-P405-P501a
WGK Germany  3
HazardClass  6.1
HS Code  29329990

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 454486 (R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde 15186-48-8 500MG ₹7306.88 2022-06-14 Buy
ALFA India ALF-J66337-09 2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane 15186-48-8 10g ₹13062 2022-05-26 Buy
ALFA India ALF-J66337-06 2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane 15186-48-8 5g ₹15827 2022-05-26 Buy
ALFA India ALF-J66337-03 2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane 15186-48-8 1g ₹10078 2022-05-26 Buy
Product number Packaging Price Buy
454486 500MG ₹7306.88 Buy
ALF-J66337-09 10g ₹13062 Buy
ALF-J66337-06 5g ₹15827 Buy
ALF-J66337-03 1g ₹10078 Buy

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Chemical Properties,Uses,Production

Chemical Properties

Colorless Transparent Liquid

Uses

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde is a reactant involved in organic reactions including:• ;Henry condensation reactions1• ;Synthesis of highly functionalized chiral aziridines2• ;Olefination of aldehydes3• ;C-H oxidations4• ;Aldol-type condensations5• ;Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents6• ;Hosomi-Sakurai reactions7

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Preparation Products And Raw materials

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1,3-DIOXOLANE-4-CARBOXALDEHYDE, 2,2-DIMETHYL-, (R)- (R)-2,2-DIMETHYL-[1,3]DIOXOLANE-4-CARBALDEHYDE (R)-(+)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBOXALDEHYDE (R)-2,3-ISOPROPYLIDENE GLYCERALDEHYDE 2,3-O-(R)-ISOPROPYLIDENE-L-GLYCERALDEHYDE D-(R)-GLYCERALDEHYDE ACETONIDE R-(+)-Solketaldehyde D-Glyceraldehyde-acetonide R-Glyceraldehyde-acetonide ( R)-(+)-2,2-dimethyl-1,3-dioxolan-4-carboxaldehyde (R)-(+)-2,2-Dimethyl-1,3-Dioxylane-4-Carboxadehyde R-(+)-2,3-O-Isopropylidene-D-glyceraldehyd (R)-(+)-2,2-Dimethyl-1,3-Dioxo (R)-(+)-2,2-DIMETHYL-1,3-DIOXOLANE-4 (R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehydeDiscontined, Unstable (R)-(+)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBOXALDEHYDE(INTERMEDIATEOFGEMCITABINE) R-(+)-2,3-O-Isopropylidene-D-glyceraldehyde (R)-2,2-DiMethyl-1,3-dioxolane-4-carboxaldehyde) 50% in Methylene chloride (R)-(+)-2,2-DiMethyl-1,3-dioxolane-4-carboxaldehyde, 97%,50% in DichloroMethane (4R)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde (R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde,98% (R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Discontinued, Unstable (R)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde(needs distilling as oligomeric form) (R)-(+)-2,2-Dimethyl 2,3-O-(R)-Isopropylidene-D-glyceraldehyde - 50% DCM solution (R)-Isopropylideneglyceraldehyde NSC 89869 2,3-isopropylidene-glyceraldehyde EOS-61843 (R)-acetone glyceraldehyde Gemcitabine Impurity 17 R-glyceraldehyde acetal 2,3-O-Isopropylidene-D-glyceraldehyde - 50% solution in DCM 4-carboxaldehyde ane-4-carboxaL 1,3-Dioxolane-4-carboxaldehyde, 2,2-dimethyl-, (4R)- (R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde ISO 9001:2015 REACH (R)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde(50% in Chlorocyclohexane) (R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde, 97%, 2,3-O-ISOPROPYLIDENE-D-GLYCERALDEHYDE (4R)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBALDEHYDE 2, 3-0-isopropyli dene-D-glyceral dehyde (R) - (+) -2,2-dimethyl-1,3-dioxolane-4-formaldehyde (R)-(+)-2, 2-dimethyl-1, 3-dioxopentyclo-4-formaldehyde D-(R)-Glyceraldehyde acetonide (R)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde 15186-48-8 Aldehydes Organic Building Blocks Chiral Building Blocks Asymmetric Synthesis Asymmetric Synthesis Building Blocks C1 to C6 Carbonyl Compounds Chemical Synthesis Chiral Building Blocks Organic Building Blocks Aldehydes