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Ferrous sulfate heptahydrate

Ferrous sulfate heptahydrate Structure
CAS No.
7782-63-0
Chemical Name:
Ferrous sulfate heptahydrate
Synonyms
Iron(II) sulfate heptahydrate;FERROIN;sulfate heptahydrate;FERROIN INDICATOR SOLUTION;FERROIN INDICATOR;Ferrous sulfate hept;ferrous sulfate granular;Iron(Ⅱ) sulfate heptahydrate;25lbs;Fesofor
CBNumber:
CB9232125
Molecular Formula:
FeH14O11S
Molecular Weight:
278.01
MOL File:
7782-63-0.mol
MSDS File:
SDS
Modify Date:
2024/6/28 14:37:56

Ferrous sulfate heptahydrate Properties

Melting point 64 °C
Density 1.898 g/mL at 25 °C (lit.)
vapor pressure 14.6 mm Hg ( 25 °C)
storage temp. Store at +15°C to +25°C.
solubility 25.6 g/100 mL (20°C)
form Solution
color Slightly greenish to blue
Specific Gravity 1.898
PH 3.0-4.0 (25℃, 50mg/mL in H2O)
Odor pale bluish-grn. cryst. or gran., odorless
Water Solubility 25.6 g/100 mL (20 ºC)
Sensitive Air Sensitive & Hygroscopic
Merck 14,4057
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability Stable. Substances to be avoided include strong oxidizing agents. Air and moisture sensitive.
InChIKey SURQXAFEQWPFPV-UHFFFAOYSA-L
LogP -1.031 (est)
CAS DataBase Reference 7782-63-0(CAS DataBase Reference)
EPA Substance Registry System Ferrous sulfate heptahydrate (7782-63-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319
Precautionary statements  P264-P270-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn
Risk Statements  22-36/38
Safety Statements  36/37/39-46
WGK Germany  1
RTECS  NO8510000
10-23
TSCA  Yes
HS Code  28332950
Toxicity LD50 in mice: 65 mg/kg i.v.; 1.52 g/kg orally (Hoppe)
NFPA 704
1
2 1

Ferrous sulfate heptahydrate price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) F8633 Iron(II) sulfate heptahydrate BioReagent, suitable for cell culture, suitable for insect cell culture, ≥99% 7782-63-0 250G ₹5228.48 2022-06-14 Buy
Sigma-Aldrich(India) F8633 Iron(II) sulfate heptahydrate BioReagent, suitable for cell culture, suitable for insect cell culture, ≥99% 7782-63-0 1KG ₹9785.8 2022-06-14 Buy
Sigma-Aldrich(India) F8263 Iron(II) sulfate heptahydrate suitable for plant cell culture, ≥99% 7782-63-0 500G ₹7826.48 2022-06-14 Buy
Sigma-Aldrich(India) F8263 Iron(II) sulfate heptahydrate suitable for plant cell culture, ≥99% 7782-63-0 1KG ₹8151.23 2022-06-14 Buy
Sigma-Aldrich(India) F7002 Iron(II) sulfate heptahydrate ReagentPlus?, ≥99% 7782-63-0 250G ₹3301.63 2022-06-14 Buy
Product number Packaging Price Buy
F8633 250G ₹5228.48 Buy
F8633 1KG ₹9785.8 Buy
F8263 500G ₹7826.48 Buy
F8263 1KG ₹8151.23 Buy
F7002 250G ₹3301.63 Buy

Ferrous sulfate heptahydrate Chemical Properties,Uses,Production

Description

§184.1315(a) Ferrous sulfate heptahydrate (iron (II) sulfate heptahydrate, FeS04-7H2O) is prepared by the action of sulfuric acid on iron. It occurs as pale, blueish-green crystals or granules. Progressive heating of ferrous sulfate heptahydrate produces ferrous sulfate (dried). Ferrous sulfate (dried) consists primarily of ferrous sulfate monohydrate (CAS No. 17375-41-6) with varying amounts of ferrous sulfate tetrahydrate (CAS No. 20908-72-9) and occurs as a grayish-white to buff-colored powder.

Chemical Properties

light blue or light blue-green solid

Uses

Used in quantitative analysis of nitrates .

Definition

ChEBI: A hydrate that is the heptahydrate form of iron(2+) sulfate. It is used as a source of iron in the treatment of iron-deficiency anaemia (generally in liquid-dosage treatments; for solid-dosage treatments, the monohydrate is normally used).

General Description

A greenish or yellow-brown crystalline solid. Density 15.0 lb /gal. Melts at 64°C and loses the seven waters of hydration at 90°C. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Used for water or sewage treatment, as a fertilizer ingredient.

Air & Water Reactions

Water soluble

Reactivity Profile

Ferrous sulfate heptahydrate is a weak reducing agent.

Health Hazard

INGESTION: abdominal pain, retching, diarrhea, dehydration, shock, pallor, cyanosis, rapid or weak pulse, shallow respiration, low blood pressure.

Safety Profile

Poison by intravenous, intraperitoneal, and subcutaneous routes. Moderately toxic by ingestion and rectal routes. Mutation data reported. When heated to decomposition it emits toxic fumes of SOx.

Potential Exposure

It is used as a fertilizer, food or feed additive; and in herbicides; process engraving; dyeing, and water treatment. A byproduct of various chemical and metal treating operations.

Purification Methods

Crystallise the sulfate from 0.4M H2SO4, or precipitate it from an aqueous solution with EtOH. It is efflorescent in dry air, and is converted to the tetrahydrate at 57o, then to the monohydrate at 65o (or by heating the heptahydrate in a vacuum at 140o). It forms a brown-black complex, FeSO4.NO, with nitric oxide and is used in a qualitative test for nitrates (“brown ring” test).

Incompatibilities

Aqueous solution is acidic. Contact with alkalies form iron. Keep away from alkalies, soluble carbo nates; gold and silver salts; lead acetate; lime water, potassium iodide; potassium and sodium tartrate; sodium borate; tannin.

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