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Hydrazine sulfate

Hydrazine sulfate Structure
CAS No.
10034-93-2
Chemical Name:
Hydrazine sulfate
Synonyms
HYDRAZINIUM SULFATE;HYDRAZINE SULPHATE;Diamine sulfate;HYDRAZINIUM SULPHATE;nsc-150014;siranhydrazinu;idrazinasolfato;Hydrazine Sulfat;diamidogensulfate;HYDRAZINE SULFATE
CBNumber:
CB2679815
Molecular Formula:
H6N2O4S
Molecular Weight:
130.12
MOL File:
10034-93-2.mol
MSDS File:
SDS
Modify Date:
2024/7/3 13:03:20

Hydrazine sulfate Properties

Melting point 254 °C(lit.)
Density 1,37 g/cm3
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility 30g/l
form Crystalline Powder
Specific Gravity 1.37
color White
PH 1.5 (50g/l, H2O, 20℃)
Odor Odorless
PH Range 1.3 (0.2 M solution)
Water Solubility 30 g/L (20 ºC)
Merck 14,4772
BRN 8778859
Stability Stable. Incompatible with nitrites, strong oxidizing agents.
InChIKey ZGCHATBSUIJLRL-UHFFFAOYSA-N
CAS DataBase Reference 10034-93-2(CAS DataBase Reference)
NIST Chemistry Reference Hydrazine dihydrogen sulfate (salt)(10034-93-2)
EPA Substance Registry System Hydrazine sulfate (1:1) (10034-93-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H311+H331-H314-H317-H350-H410
Precautionary statements  P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T,N
Risk Statements  45-23/24/25-43-50/53-35
Safety Statements  53-45-60-61-36/37/39-26
RIDADR  UN 2923 8/PG 3
WGK Germany  3
RTECS  MV9625000
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  28251090
Toxicity Hydrazine sulfate is moderately toxic. Symptoms of ingestion are paresthesia, somnolence, nausea, and vomiting. It also is an irritant to the eye. It is a confirmed carcinogen and an experimental teratogen.
NFPA 704
0
3 1

Hydrazine sulfate price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 53900 Hydrazine sulfate salt puriss. p.a., ACS reagent, ≥99.0% 10034-93-2 100G ₹3702.15 2022-06-14 Buy
Sigma-Aldrich(India) 216046 Hydrazine sulfate salt ACS reagent, ≥99.0% 10034-93-2 5G ₹4459.9 2022-06-14 Buy
Sigma-Aldrich(India) 53900 Hydrazine sulfate salt puriss. p.a., ACS reagent, ≥99.0% 10034-93-2 500G ₹12329.68 2022-06-14 Buy
Sigma-Aldrich(India) 216046 Hydrazine sulfate salt ACS reagent, ≥99.0% 10034-93-2 100G ₹5531.58 2022-06-14 Buy
Sigma-Aldrich(India) 216046 Hydrazine sulfate salt ACS reagent, ≥99.0% 10034-93-2 500G ₹11203.88 2022-06-14 Buy
Product number Packaging Price Buy
53900 100G ₹3702.15 Buy
216046 5G ₹4459.9 Buy
53900 500G ₹12329.68 Buy
216046 100G ₹5531.58 Buy
216046 500G ₹11203.88 Buy

Hydrazine sulfate Chemical Properties,Uses,Production

Chemical Properties

colourless crystals or white powder

Physical properties

Colorless orthorhombic crystal; density 1.378 g/cm3; melts at 254°C; sparingly soluble in cold water 1.64% at 0°C and 3.41% at 25°C; more soluble inhot water; practically insoluble in alcohol (0.04% at 25°C).

Uses

Hydrazine sulfate is used in the gravimetric estimation of nickel, cobalt and cadmium; in the refining of rare metals; as an antioxidant in soldering flux for light metals; as a reducing agent in the analysis of minerals and slags; in separating polonium from tellurium; in tests for blood; for destroying fungi and molds; in the preparation of hydrazine hydrate; press ure stabilizer in cutting oils.

Preparation

Hydrazine sulfate may be synthesized from aqueous ammonia and sodium hypochlorite solution in a two-step process. In the first stage, aqueous solution of ammonia is boiled with a normal solution of sodium hypochlorite in the presence of 10% gelatin solution to yield hydrazine. In the second stage, the hydrazine solution is ice-cooled followed by slow addition of concentrated sulfuric acid (Adams, R., and B.K. Brown. 1964. In Organic Synthesis, Collective Volume I, ed. H. Gilman and A. H. Blatt, 2nd ed. pp 309-310, New York: John Wiley & Sons). The reaction steps are as follows:
2NH3 + NaOCl → NH2NH2 + H2O + NaCl
NH2NH2 + H2SO4 → NH2NH2 •H2SO4

General Description

Hydrazine sulfate salt is a potential anticachexia agent for treating cancer patients.

Hazard

A carcinogen (OSHA).

Carcinogenicity

Hydrazine and hydrazine sulfate are reasonably anticipated to be human carcinogens based on sufficient evidence of carcinogenicity from studies in experimental animals.

Purification Methods

Its solubility in H2O is 3% at room temperature, but is very soluble in hot H2O. It is a suspected carcinogen. [Adams & Brown Org Synth Coll Vol I 309 1941, Audrieth & Nickles Inorg Synth I 90 1939.]

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HYDRAZINIUM SULFATE GR FOR ANALYSIS ACS Hydrazine sulfate salt 99.999% trace metals basis Hydrazine sulfate salt ACS reagent, >=99.0% Hydrazine sulfate salt puriss. p.a., ACS reagent, >=99.0% Hydrazine sulfate salt Vetec(TM) reagent grade, 97% Diamine sulfate hydrazine sulfate Hydrazine sulfate, reagent grade, ACS Hydrazine sulfate, 99+% 100GR Hydrazine sulfate, ACS reagent 100GR Hydrazine sulfate, ACS reagent 50GR Hydrazine Sulfate, Acs Min HYDRAZINE SULFATE, 99+%, A.C.S. REAGENT HYDRAZINE SULFATE, ACS HYDRAZINIUM SULFATE R. G., REAG. ACS HYDRAZINE SULFATE, 99.999% HYDRAZINE SULFATE ACS REAGENT HydrazineSulphateGr Hydrazine sulfate, 99+% hydrazine,sulfate(1:1) hydrazinedihydrogensulfatesalt 6,8-Dichlorocaprylic Acid Ethyl Ester hydrazinium(2+) sulphate Hydrazine sulfate salt Diamine sulfate Hydrazine sulfate Hydrazinium sulfate GR for analysis ACS,Reag. Ph Eur Hydrazine sulfate, p.a. diamidogensulfate HYDRAZINE SULFATE REAGENT (ACS) HYDRAZINE SULFATE SALT HYDRAZINE SULFATE HYDRAZINESULFATE,ACS(BULK HYDRAZINESULFATE,CP HYDRAZINESULFATE,CRYSTAL,REAGENT,ACS Hydrazinium(2+)-sulfat hydrazinehydrogensulfate hydrazinemonosulfate Hydrazinesulfate(1:1) hydrazoniumsulfate idrazinasolfato nsc-150014 siranhydrazinu siranhydrazinu(czech) Hydrazine sulfate, ACS, 99.0% min Hydrazine Sulfate, Crystal HYDRAZINE SULPHATE extrapure AR Hydrazine sulfate, 99%, for analysis HYDRAZINE SULFATE XTL HYDRAZINE SULFATE, REAGENT (ACS)HYDRAZINE SULFATE, REAGENT (ACS)HYDRAZINE SULFATE, REAGENT (ACS) Dihydralazine Impurity 3 Sulfate(Hydrazine Sulfate) Hydrazine sulfate salt,>99% Hydrazine sulfate ISO 9001:2015 REACH hydrazine sulphate uses Hydrazine sulphate, GR 99%+ Hydrazine Sulphate AR 100GM Hydrazine Sulphate extrapure 100GM Hydrazine sulfate 10034-93-2 Hydrazine Sulphate extrapure AR, 99.5% Hydrazine Sulphate extrapure AR, ACS, ExiPlus, Multi-Compendial, 99.5% Hydrazine Sulphate extrapure, 99%