Hydrazine sulfate
![Hydrazine sulfate Structure](CAS/GIF/10034-93-2.gif)
- CAS No.
- 10034-93-2
- Chemical Name:
- Hydrazine sulfate
- Synonyms
- HYDRAZINIUM SULFATE;HYDRAZINE SULPHATE;Diamine sulfate;HYDRAZINIUM SULPHATE;nsc-150014;siranhydrazinu;idrazinasolfato;Hydrazine Sulfat;diamidogensulfate;HYDRAZINE SULFATE
- CBNumber:
- CB2679815
- Molecular Formula:
- H6N2O4S
- Molecular Weight:
- 130.12
- MOL File:
- 10034-93-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/3 13:03:20
Melting point | 254 °C(lit.) |
---|---|
Density | 1,37 g/cm3 |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
solubility | 30g/l |
form | Crystalline Powder |
Specific Gravity | 1.37 |
color | White |
PH | 1.5 (50g/l, H2O, 20℃) |
Odor | Odorless |
PH Range | 1.3 (0.2 M solution) |
Water Solubility | 30 g/L (20 ºC) |
Merck | 14,4772 |
BRN | 8778859 |
Stability | Stable. Incompatible with nitrites, strong oxidizing agents. |
InChIKey | ZGCHATBSUIJLRL-UHFFFAOYSA-N |
CAS DataBase Reference | 10034-93-2(CAS DataBase Reference) |
NIST Chemistry Reference | Hydrazine dihydrogen sulfate (salt)(10034-93-2) |
EPA Substance Registry System | Hydrazine sulfate (1:1) (10034-93-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() ![]() GHS05,GHS06,GHS08,GHS09 |
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Signal word | Danger | |||||||||
Hazard statements | H301+H311+H331-H314-H317-H350-H410 | |||||||||
Precautionary statements | P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
Hazard Codes | T,N | |||||||||
Risk Statements | 45-23/24/25-43-50/53-35 | |||||||||
Safety Statements | 53-45-60-61-36/37/39-26 | |||||||||
RIDADR | UN 2923 8/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | MV9625000 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 28251090 | |||||||||
Toxicity | Hydrazine sulfate is moderately toxic. Symptoms of ingestion are paresthesia, somnolence, nausea, and vomiting. It also is an irritant to the eye. It is a confirmed carcinogen and an experimental teratogen. | |||||||||
NFPA 704 |
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Hydrazine sulfate price More Price(20)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 53900 | Hydrazine sulfate salt puriss. p.a., ACS reagent, ≥99.0% | 10034-93-2 | 100G | ₹3702.15 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 216046 | Hydrazine sulfate salt ACS reagent, ≥99.0% | 10034-93-2 | 5G | ₹4459.9 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 53900 | Hydrazine sulfate salt puriss. p.a., ACS reagent, ≥99.0% | 10034-93-2 | 500G | ₹12329.68 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 216046 | Hydrazine sulfate salt ACS reagent, ≥99.0% | 10034-93-2 | 100G | ₹5531.58 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 216046 | Hydrazine sulfate salt ACS reagent, ≥99.0% | 10034-93-2 | 500G | ₹11203.88 | 2022-06-14 | Buy |
Hydrazine sulfate Chemical Properties,Uses,Production
Chemical Properties
colourless crystals or white powder
Physical properties
Colorless orthorhombic crystal; density 1.378 g/cm3; melts at 254°C; sparingly soluble in cold water 1.64% at 0°C and 3.41% at 25°C; more soluble inhot water; practically insoluble in alcohol (0.04% at 25°C).
Uses
Hydrazine sulfate is used in the gravimetric estimation of nickel, cobalt and cadmium; in the refining of rare metals; as an antioxidant in soldering flux for light metals; as a reducing agent in the analysis of minerals and slags; in separating polonium from tellurium; in tests for blood; for destroying fungi and molds; in the preparation of hydrazine hydrate; press ure stabilizer in cutting oils.
Preparation
Hydrazine sulfate may be synthesized from aqueous ammonia and sodium hypochlorite solution in a two-step process. In the first stage, aqueous solution of ammonia is boiled with a normal solution of sodium hypochlorite in the presence of 10% gelatin solution to yield hydrazine. In the second stage, the hydrazine solution is ice-cooled followed by slow addition of concentrated sulfuric acid (Adams, R., and B.K. Brown. 1964. In Organic Synthesis, Collective Volume I, ed. H. Gilman and A. H. Blatt, 2nd ed. pp 309-310, New York: John Wiley & Sons). The reaction steps are as follows:
2NH3 + NaOCl → NH2NH2 + H2O + NaCl
NH2NH2 + H2SO4 → NH2NH2 •H2SO4
General Description
Hydrazine sulfate salt is a potential anticachexia agent for treating cancer patients.
Hazard
A carcinogen (OSHA).
Carcinogenicity
Hydrazine and hydrazine sulfate are reasonably anticipated to be human carcinogens based on sufficient evidence of carcinogenicity from studies in experimental animals.
Purification Methods
Its solubility in H2O is 3% at room temperature, but is very soluble in hot H2O. It is a suspected carcinogen. [Adams & Brown Org Synth Coll Vol I 309 1941, Audrieth & Nickles Inorg Synth I 90 1939.]
Hydrazine sulfate Preparation Products And Raw materials
Raw materials
Preparation Products
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GLR Innovations | 58 |
ANJI BIOSCIENCES | 58 |
Suchmi Organics | 58 |
Shree Sidhdhanath Industries | 58 |
VGS SYNTHESIS PRIVATE LIMITED | 58 |
S D Fine Chem Limited | 58 |
Medinex Laboratories Pvt Ltd | 58 |
JSK Chemicals | 58 |
VASIN BIO LIFE SCIENCES PVT LTD | 58 |
Pharma Affiliates | 58 |
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