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Hydrazine monohydrochloride

Hydrazine monohydrochloride Structure
CAS No.
2644-70-4
Chemical Name:
Hydrazine monohydrochloride
Synonyms
Hydrazinium chloride;HydrazineHCl;HYDRAZINE MONO HCL;Hydrazine,chloride;Hydrazine monohydroc;hydrazinemonochloride;Hydrazine monohydrochL;Adrenaline Impurity 37;HYDRAZINIUM MONOCHLORIDE;HYDRAZINE MONOHYDROCHLORIDE
CBNumber:
CB3236358
Molecular Formula:
ClH5N2
Molecular Weight:
68.51
MOL File:
2644-70-4.mol
MSDS File:
SDS
Modify Date:
2023/10/20 13:11:28

Hydrazine monohydrochloride Properties

Melting point 89 °C(lit.)
Boiling point 240°C
Density 1.500
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form white orthorhombic crystals
color White to Almost white
Water Solubility 370 g/L (20 ºC)
Stability Hygroscopic
InChIKey BIVUUOPIAYRCAP-UHFFFAOYSA-N
CAS DataBase Reference 2644-70-4(CAS DataBase Reference)
EPA Substance Registry System Hydrazine, monohydrochloride (2644-70-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H311+H331-H317-H350-H410
Precautionary statements  P202-P273-P280-P301+P310-P302+P352+P312-P304+P340+P311
Hazard Codes  T,N
Risk Statements  45-23/24/25-43-50/53
Safety Statements  53-45-60-61
RIDADR  UN 2923 8/PG 2
WGK Germany  3
RTECS  MV4625000
HazardClass  6.1(a)
PackingGroup  II
HS Code  28251090
NFPA 704
0
3 0

Hydrazine monohydrochloride price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 216194 Hydrazine monohydrochloride 97% 2644-70-4 5G ₹3994.43 2022-06-14 Buy
Sigma-Aldrich(India) 216194 Hydrazine monohydrochloride 97% 2644-70-4 250G ₹10803.35 2022-06-14 Buy
TCI Chemicals (India) H0174 Hydrazine Monohydrochloride 2644-70-4 25G ₹3000 2022-05-26 Buy
TCI Chemicals (India) H0174 Hydrazine Monohydrochloride 2644-70-4 500G ₹6900 2022-05-26 Buy
Product number Packaging Price Buy
216194 5G ₹3994.43 Buy
216194 250G ₹10803.35 Buy
H0174 25G ₹3000 Buy
H0174 500G ₹6900 Buy

Hydrazine monohydrochloride Chemical Properties,Uses,Production

Chemical Properties

Hydrazine monohydrochloride is white to slightly beige crystals or cryst. powder; melts at 93°C; decomposes around 200°C; very soluble in water (37 g/100mL at 20°C); slightly soluble in alcohol.

Physical properties

White flakes; orthorhombic crystals; density 1.5 g/cm3; melts at 93°C;decomposes around 200°C; very soluble in water (37 g/100mL at 20°C); slightly soluble in alcohol.

Uses

Hydrazine monohydrochloride has been used:

  • as catalyst in the synthesis of titanium oxide polymers via catalytic sol-gel process
  • in fabrication of amorphous titanium dioxide (TiO2) thin films exhibiting high refractive indices and high transparency
  • in preparation of ethyl 3-ethoxy-1H-pyrazole-4-carboxylate

Preparation

Hydrazine hydrochloride is prepared by the reaction of hydrazine with hydrogen chloride:
N2H4 + HCl → N2H4 •HCl

Hazard

Hydrazine hydrochloride is moderately toxic by all routes of exposure. Theoral LD50in mice is 126 mg/kg.

Purification Methods

Prepare it by dropwise addition of cold conc HCl to cold liquid hydrazine in equimolar amounts. The crystals are harvested from water and are twice recrystallised from absolute MeOH and dried under a vacuum. [Kovack et al. J Am Chem Soc 107 7360 1985.]

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