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Potassium sulfate

Potassium sulfate Structure
CAS No.
7778-80-5
Chemical Name:
Potassium sulfate
Synonyms
POTASSIUM SULPHATE;K2SO4;sop;231-915-5;KSO;Kso4;KSO2;WATER R PHE;Kaliumsulfat;Potassium in
CBNumber:
CB9854321
Molecular Formula:
K2O4S
Molecular Weight:
174.2592
MOL File:
7778-80-5.mol
MSDS File:
SDS
Modify Date:
2024/5/28 19:59:05

Potassium sulfate Properties

Melting point 1067°C
Boiling point 1689°C
Density 2.66
Flash point 1689°C
storage temp. Inert atmosphere,Room Temperature
solubility H2O: 0.5 M at 20 °C, clear, colorless
form Very Fine Crystals or Powder
color White
Specific Gravity 2.662
Odor Odorless
PH Range ~7
PH 5.5-7.5 (25℃, 0.5M in H2O)
Water Solubility 110 g/L (20 ºC)
λmax λ: 260 nm Amax: 0.01
λ: 280 nm Amax: 0.01
Merck 14,7674
Dielectric constant 5.9(0.0℃)
Stability Stable.
InChIKey OTYBMLCTZGSZBG-UHFFFAOYSA-L
CAS DataBase Reference 7778-80-5(CAS DataBase Reference)
NIST Chemistry Reference Potassium sulfate(7778-80-5)
EPA Substance Registry System Potassium sulfate (7778-80-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P260-P262-P305+P351+P338
Safety Statements  22-24/25
WGK Germany  1
RTECS  TT5900000
TSCA  Yes
HS Code  31043000
Toxicity LD50 orally in Rabbit: 6600 mg/kg
NFPA 704
1
1 0

Potassium sulfate price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) P9458 Potassium sulfate BioXtra, ≥99.0% 7778-80-5 250G ₹6635.73 2022-06-14 Buy
Sigma-Aldrich(India) P9458 Potassium sulfate BioXtra, ≥99.0% 7778-80-5 1KG ₹17298.35 2022-06-14 Buy
Sigma-Aldrich(India) P0772 Potassium sulfate ReagentPlus?, ≥99.0% 7778-80-5 250G ₹6430.05 2022-06-14 Buy
Sigma-Aldrich(India) P8541 Potassium sulfate suitable for plant cell culture 7778-80-5 1KG ₹9839.93 2022-06-14 Buy
Sigma-Aldrich(India) P0772 Potassium sulfate ReagentPlus?, ≥99.0% 7778-80-5 1KG ₹8638.35 2022-06-14 Buy
Product number Packaging Price Buy
P9458 250G ₹6635.73 Buy
P9458 1KG ₹17298.35 Buy
P0772 250G ₹6430.05 Buy
P8541 1KG ₹9839.93 Buy
P0772 1KG ₹8638.35 Buy

Potassium sulfate Chemical Properties,Uses,Production

Description

Potassium sulfate (K2SO4) is a kind of chemical compounds that is commonly used in agriculture. The dominant application of potassium sulfate is as a fertilizer, which is commonly applied to offer both potassium and sulfur, thus improving the quality and yield of crops growing in soils that lack an adequate supply of this essential elements. Besides, the crude potassium sulfate is sometimes employed in the production of glass. It also has applications in other industries, which is used as a flash reducer in artillery propellant charges and as an alternative blast media similar to soda in the process of soda blasting.
potassium sulfate powder
potassium sulfate powder

Chemical Properties

Potassium sulfate,K2804, also known as salt of Lemery and arcanite, is a colorless crystalline solid that melts at 1072°C(1960 OF). It is soluble in water,but insoluble in alcohol. Potassium sulfate is used in manufacturing glass, aluminum, fertilizers, and in medicine.

Physical properties

Colorless or white crystals or white granules or powder; rhombohedral structure; bitter taste; density 2.66 g/cm3; melts at 1,069°C; vaporizes at 1,689°C; moderately soluble in water, 12 g/100mL at 25°C and 24g/100mL at 100°C; slightly soluble in glycerol; insoluble in alcohol, acetone, and carbon disulfide.

Occurrence

Potassium and sodium sulfates and their double sulfates with calcium and magnesium occur naturally in various salt lakes. Potassium sulfate also occurs in certain volcanic lava. Its double salt with magnesium occurs in nature, as the mineral langbeinite.
Potassium sulfate is used in fertilizers as a source of potassium and sulfur, both of which are essential elements for plant growth. Either in sim-ple form or as a double salt with magnesium sulfate, potassium sulfate is one of the most widely consumed potassium salts in agricultural applications. It is preferred over potassium chloride for certain types of crops; such as, tobac-co, citrus, and other chloride-sensitive crops. Some other applications include making gypsum cements; to make potassium alum; in the analysis of Kjeldahl nitrogen; and in medicine.

Uses

potassium sulfate is a reagent in cosmetics. Potassium sulfate is an inorganic salt with a primary function as a viscosity-increasing agent.

Production Methods

Potassium sulfate is produced by various methods, selection of process depending on availability and cost of raw materials.
The salt may be obtained from its naturally occurring mineral, langbeinite,K2SO4?2MgSO4. The ore first is crushed and washed with water to separate sodium chloride. After that, magnetite is separated from the washed langbei-nite by magnetic separation. After the separation of these two major impuri-ties, the purified double salt is treated with an aqueous solution of potassium chloride to obtain potassium sulfate:
K2SO4?2MgSO4 + 4KCl →3K2SO4+ 2MgCl2
The solution is filtered to remove insoluble residues and the products are separated from their aqueous mixture by crystallization.
Potassium sulfate also is produced from the mineral kieserite, MgSO4?H2O by treatment with potassium chloride. The intermediate double salt obtained reacts further with potassium chloride to form potassium sulfate:MgSO4?H2O + 2KCl + 4H2O →K2SO4?MgSO4?6H2O + MgCl2
K2SO4?MgSO4?6H2O + 2KCl →2K2SO4+ MgCl2
Potassium sulfate is separated from the more soluble magnesium chloride by crystallization.
Also, potassium sulfate can be made by two other processes in which no naturally occurring mineral is employed. In the Mannheim process, the salt is produced by action of sulfuric acid on potassium chloride:2KCl + H2SO4→K2SO4+ 2HCl
In Hargreaves process, which is a slight variation of the Mannheim method, potassium sulfate is made by heating a mixture of potassium chlo-ride, sulfur dioxide, air and water:4KCl + 2SO2+ 2H2O + o2→2K2SO4+ 4HCl.

Definition

Potassium sulfate is a potassium salt and an inorganic potassium salt. It is a white crystalline powder, K2SO4, soluble inwater and insoluble in ethanol;rhombic or hexagonal; r.d. 2.66; m.p.1069°C. It occurs naturally assch nite (Strassfurt deposits) and inlake brines, from which it is separatedby fractional crystallization. Ithas also been produced by the Hargreavesprocess, which involves theoxidation of potassium chloride withsulphuric acid. In the laboratory itmay be obtained by the reaction ofeither potassium hydroxide or potassiumcarbonate with sulphuric acid.Potassium sulphate is used in cements,in glass manufacture, as a food additive, and as a fertilizer(source of K+) for chloride-sensitiveplants, such as tobacco and citrus.

General Description

Potassium sulfate is an inorganic salt that can be prepared by reacting phosphogypsum and potassium chloride. It forms needlelike mullite particles on heating with aluminum sulfate (Al2(SO4)3) and silicon dioxide (SiO2). Its application to the soil has been reported to minimize the bronzing of rice plants. Its surface integration growth kinetics has been obtained in the temperature range of 20-50°C. The theoretical heat capacity curve of potassium sulfate in vapor phase has been obtained.

Safety Profile

Moderately toxic to humans by ingestion. Moderately toxic experimentally by subcutaneous route. Swallowing large doses causes severe gastrointestinal tract effects. When heated to decomposition it emits toxic fumes of K2O and SOx. See also SULFATES.

Purification Methods

Potassium sulfate [7778-80-5] M 174.3, m 1069o, d 4 2.67 It crystallised from distilled water (4mL/g at 20o; 8mL/g at 100o) between 100o and 0o.

References

https://en.wikipedia.org/wiki/Potassium_sulfate
http://www.cropnutrition.com/potassium-sulfate
http://study.com/academy/lesson/what-is-potassium-sulfate-structure-uses-formula.html

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Arcanum duplicatum arcanumduplicatum dipotassiumsulfate Glazier's salt kaliumsulphuricum Potassium sulfate, alpha potassiumsulfate(2:1) POTASSIUM SULFATE ANHYDROUS POWDER POTASSIUM SULPHATE extrapure AR Potassium Sulfate, granular Potassium Sulfate, granular(low nitrogen) FISHERTAB ST-35 KJELDAHL TABLETS FISHERTAB ST-AUTO KJELDAHL TABLETS KELMATE(R) KJELDAHL DIGESTION MIXTURE KELMATE(R) KJELDAHL DIGESTION MIXTURE CT-37 KELMATE(R) KJELDAHL DIGESTION MIXTURE MT-37 KELMATE(R) KJELDAHL DIGESTION MIXTURE ST-35 KELMATE(R) KJELDAHL DIGESTION MIXTURE ST-AUTO KELMATE(R) KJELDAHL DIGESTION MIXTURE TT-35 KELMATE(R) KJELDAHL DIGESTION MIXTURE TT-50 KELMATE(R) N KJELDAHL DIGESTION MIXTURE NO 100 KELMATE(R) N KJELDAHL DIGESTION MIXTURE NO 200 KELMATE(R) N KJELDAHL DIGESTION MIXTURE NO 210 KELMATE(R) N KJELDAHL DIGESTION MIXTURE NO 510 KELMATE(R) N KJELDAHL DIGESTION MIXTURE NO 600 KELMATE(R) N KJELDAHL DIGESTION MIXTURE NO 610 KELMATE(R) N KJELDAHL DIGESTION MIXTURE PACKETS, NO 100 KELMATE(R) N KJELDAHL DIGESTION MIXTURE PACKETS, NO 110 KELMATE(R) N KJELDAHL DIGESTION MIXTURE PACKETS, NO 200 KELMATE(R) N KJELDAHL DIGESTION MIXTURE PACKETS, NO 210 KELMATE(R) N KJELDAHL DIGESTION MIXTURE PACKETS, NO 300 KELMATE(R) N KJELDAHL DIGESTION MIXTURE PACKETS, NO 410 KELMATE(R) N KJELDAHL DIGESTION MIXTURE PACKETS, NO 510 KELMATE(R) N KJELDAHL DIGESTION MIXTURE PACKETS, NO 600 KELMATE(R) N KJELDAHL DIGESTION MIXTURE PACKETS, NO 610 KELMATE(R) NT KJELDAHL DIGESTION MIXTURE, NO 710 KELMATE(R) NT KJELDAHL DIGESTION MIXTURE NO 810 KJELTAB CATALYSTS KJELTABS IB 61 Potassium sulfate,99+%,for analysis,anhydrous, granular Potassium sulfate,99+%,for analysis,anhydrouspowder POTASSIUM SULFATE, 99+%, FOR ANALYSIS ACS Potassium sulfate, anhydrous, granular, for analysis Potassium sulfate, anhydrous powder, for analysis Potassium sulfate, for analysis ACS Potassium sulfate,agricultural POTASSIUM SULFATE POWDER 99+% A.C.S.& POTASSIUM SULFATE SIGMAULTRA POTASSIUM SULFATE POWDER, PURE POTASSIUM SULFATE R. G., REAG. ACS, REAG. ISO, REAG. PH. POTASSIUM SULFATE PLANT CELL CULTURE*TES TED POTASSIUM SULFATE, ACS Potassium Sulfate, Powder, Reagent Kalii sulfas WATER R PHE Potassium sulfate(VI) Potassium sulfate, 99.995% trace metals basis POTASSIUM SULFATE BIOXTRA