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Potassium phthalimide

Potassium phthalimide Structure
CAS No.
1074-82-4
Chemical Name:
Potassium phthalimide
Synonyms
PotassiuM 1,3-dioxoisoindolin-2-ide;PHTHALIMIDE POTASSIUM;PHTHALIMIDE POTASSIUM SALT;POTASSIUM PHTHALAMIDE;potassiumphthalimidate;Potasium phthalimide;Nsc167070;Phthlimide;Potassium PhthaL;N-Kaliumphthalimid
CBNumber:
CB9265842
Molecular Formula:
C8H4KNO2
Molecular Weight:
185.22
MOL File:
1074-82-4.mol
MSDS File:
SDS
Modify Date:
2024/5/16 17:35:26

Potassium phthalimide Properties

Melting point >300°C
Boiling point 366C
Density 1.63
storage temp. Inert atmosphere,Room Temperature
solubility water: soluble50mg/mL, clear to slightly hazy, colorless to yellow
form Crystalline Powder
color White to yellow or greenish
PH pH (50g/l, 25℃) : 10.5~12.5
Water Solubility Soluble in water.
Sensitive Moisture Sensitive
BRN 3598719
LogP -1.859
CAS DataBase Reference 1074-82-4(CAS DataBase Reference)
EPA Substance Registry System Potassium phthalimide (1074-82-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-26-60-37
WGK Germany  3
TSCA  Yes
HS Code  29251995
NFPA 704
0
1 0

Potassium phthalimide price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 79790 Phthalimide potassium salt purum, ≥99.0% (NT) 1074-82-4 100G ₹2890.28 2022-06-14 Buy
Sigma-Aldrich 160385 Phthalimide potassium salt 98% 1074-82-4 5G ₹1104.15 2022-06-14 Buy
Sigma-Aldrich(India) 160385 Phthalimide potassium salt 98% 1074-82-4 5G ₹1104.15 2022-06-14 Buy
Sigma-Aldrich(India) 79790 Phthalimide potassium salt purum, ≥99.0% (NT) 1074-82-4 500G ₹8703.3 2022-06-14 Buy
Sigma-Aldrich 160385 Phthalimide potassium salt 98% 1074-82-4 100G ₹2273.25 2022-06-14 Buy
Product number Packaging Price Buy
79790 100G ₹2890.28 Buy
160385 5G ₹1104.15 Buy
160385 5G ₹1104.15 Buy
79790 500G ₹8703.3 Buy
160385 100G ₹2273.25 Buy

Potassium phthalimide Chemical Properties,Uses,Production

Chemical Properties

slight yellow-green to white powder

Uses

Potassium phthalimide is usually used as organocatalyst for the cyanosilylation of various carbonyl compounds under extremely mild conditions,and also used as reagent for the transformation of allyl- and alkyl halides into protected primary amines.

Purification Methods

The solid may contain phthalimide and K2CO3 from hydrolysis. If too much hydrolysis has occurred (this can be checked by extraction with cold Me2CO in which the salt is insoluble, evaporate the Me2CO and weigh the residue), it would be better to prepare it afresh. If little hydrolysis has occurred, then recrystallise it from a large volume of EtOH, and wash the solid with a little Me2CO and dry it in a continuous vacuum to constant weight. [Salzerg & Supriawski Org Synth Coll Vol I 119 1941, Raman & IR: Hase J Mol Struct 48 33 1978, Dykman Chem Ind (London) 40 1972, IR, NMR: Assef et al. Bull Soc Chim Fr II 167 1979, Beilstein 21/10 V 270.]

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