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Furfuryl mercaptan

Furfuryl mercaptan Structure
CAS No.
98-02-2
Chemical Name:
Furfuryl mercaptan
Synonyms
2-Furfurylthiol;2-FURANMETHANETHIOL;FURFURYL THIOL;Furfural mercaptan;usafb-58;NSC 41142;USAF B-58;FEMA 2493;Coffee mercaptan;FUFURYL MERCAPTAN
CBNumber:
CB9387119
Molecular Formula:
C5H6OS
Molecular Weight:
114.17
MOL File:
98-02-2.mol
MSDS File:
SDS
Modify Date:
2023/8/15 17:37:19

Furfuryl mercaptan Properties

Melting point 157.5 °C
Boiling point 155 °C(lit.)
Density 1.132 g/mL at 25 °C(lit.)
refractive index n20/D 1.531(lit.)
FEMA 2493 | FURFURYL MERCAPTAN
Flash point 113 °F
storage temp. Flammables area
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
pka 9.59±0.10(Predicted)
form Liquid
color Clear colorless to pale yellow
Odor at 0.10 % in dipropylene glycol. sulfury roasted coffee oily fatty burnt smoky
Odor Type coffee
Water Solubility insoluble
Sensitive Air Sensitive
JECFA Number 1072
BRN 383594
Stability Air Sensitive
LogP 1.73
CAS DataBase Reference 98-02-2(CAS DataBase Reference)
NIST Chemistry Reference 2-Furanmethanethiol(98-02-2)
EPA Substance Registry System 2-Furanmethanethiol (98-02-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Warning
Hazard statements  H226
Precautionary statements  P210
Hazard Codes  F,Xn
Risk Statements  10-36/37-20/21/22
Safety Statements  23-24/25-16-36-26-7/9
RIDADR  UN 3336 3/PG 3
WGK Germany  3
RTECS  LU2100000
10-13-23
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29321900
NFPA 704
2
1 0

Furfuryl mercaptan price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) W249311 Furfuryl mercaptan natural, 98%, FG 98-02-2 1SAMPLE-K ₹6419.23 2022-06-14 Buy
Sigma-Aldrich(India) W249311 Furfuryl mercaptan natural, 98%, FG 98-02-2 100G ₹59017.9 2022-06-14 Buy
Sigma-Aldrich(India) W249311 Furfuryl mercaptan natural, 98%, FG 98-02-2 500G ₹293887.93 2022-06-14 Buy
Sigma-Aldrich(India) W249300 Furfuryl mercaptan ≥97%, FG 98-02-2 1SAMPLE-K ₹5141.88 2022-06-14 Buy
Sigma-Aldrich(India) W249300 Furfuryl mercaptan ≥97%, FG 98-02-2 1KG ₹21249.48 2022-06-14 Buy
Product number Packaging Price Buy
W249311 1SAMPLE-K ₹6419.23 Buy
W249311 100G ₹59017.9 Buy
W249311 500G ₹293887.93 Buy
W249300 1SAMPLE-K ₹5141.88 Buy
W249300 1KG ₹21249.48 Buy

Furfuryl mercaptan Chemical Properties,Uses,Production

Description

Furfuryl mercaptan has a characteristic unpleasant odor. It is prepared by reacting thiourea and furfuryl chloride with subsequent hydrolysis of the reaction product; also by reduction of difurfuryl disulfide in alcoholic solution using zinc dust and a small amount of acetic acid or using activated alumina. Furfuryl mercaptan tends to polymerize when heated in the presence of mineral acids.

Chemical Properties

Furfuryl mercaptan has a characteristic unpleasant odor.

Occurrence

Reported found in raw and roasted chicken, cooked beef, grilled pork, sesame seed oil, coffee and popcorn; tends to polymerize when heated in the presence of mineral acids

Uses

Furfuryl Mercaptam is a volatile flavor component of corn tortilla chips.

Preparation

Furfuryl mercaptan is prepared from furfuryl alcohol, thiourea, and hydrogen chloride.The resulting S-furfurylisothiouronium chloride is cleaved with sodium hydroxide to give furfuryl mercaptan.

General Description

Darkens on storage

Safety Profile

Poison by intraperitoneal route. Experimental reproductive effects. Used as a flavoring in chocolate, fruit, nuts, and coffee. When heated to decomposition it emits toxic fumes of SOx. See also MERCAPTANS.

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