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9-(Chloromethyl)anthracene

9-(Chloromethyl)anthracene Structure
CAS No.
24463-19-2
Chemical Name:
9-(Chloromethyl)anthracene
Synonyms
icr448;ICR 448;9-Chlormethyl-anthracen;9-Chloromethyanthracene;9-chloromethyl-anthracen;9-CHLOROMETHYLANTHRACENE;9-(choromethyl)anthracene;9-(chloroMethyl)antracene;(9-Anthrylmethyl) chloride;(9-Anthryl)methyl chloride
CBNumber:
CB9740578
Molecular Formula:
C15H11Cl
Molecular Weight:
226.7
MOL File:
24463-19-2.mol
MSDS File:
SDS
Modify Date:
2023/4/27 16:27:43

9-(Chloromethyl)anthracene Properties

Melting point 138-140 °C (lit.)
Boiling point 294.66°C (rough estimate)
Density 1.1510 (rough estimate)
refractive index 1.6281 (estimate)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
solubility chloroform: soluble
form Powder
color Yellow
Water Solubility Soluble in chloroform. Insoluble in water.
Sensitive Light Sensitive
BRN 1873394
CAS DataBase Reference 24463-19-2(CAS DataBase Reference)
NIST Chemistry Reference 9-(Chloromethyl)anthracene(24463-19-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS05
Signal word  Warning
Hazard statements  H315-H319-H335-H290-H314-H318
Precautionary statements  P260h-P301+P330+P331-P303+P361+P353-P501a-P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501-P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  UN 3261 8/PG 2
WGK Germany  3
RTECS  CA9600000
19
HazardClass  8
PackingGroup  III
HS Code  29039990
Toxicity mouse,LDLo,intravenous,2267ug/kg (2.267mg/kg),Cancer Research. Vol. 36, Pg. 2423, 1976.
NFPA 704
1
3 0

9-(Chloromethyl)anthracene price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemicals (India) C1046 9-Chloromethylanthracene 24463-19-2 1G ₹2800 2022-05-26 Buy
TCI Chemicals (India) C1046 9-Chloromethylanthracene 24463-19-2 5G ₹6200 2022-05-26 Buy
TCI Chemicals (India) C1046 9-Chloromethylanthracene 24463-19-2 25G ₹19400 2022-05-26 Buy
TCI Chemicals (India) A5502 9-Chloromethylanthracene [for HPLC Labeling] 24463-19-2 1G ₹2900 2022-05-26 Buy
TCI Chemicals (India) A5502 9-Chloromethylanthracene [for HPLC Labeling] 24463-19-2 5G ₹8600 2022-05-26 Buy
Product number Packaging Price Buy
C1046 1G ₹2800 Buy
C1046 5G ₹6200 Buy
C1046 25G ₹19400 Buy
A5502 1G ₹2900 Buy
A5502 5G ₹8600 Buy

9-(Chloromethyl)anthracene Chemical Properties,Uses,Production

Chemical Properties

YELLOW POWDER

Uses

9-(Chloromethyl)anthracene is used as a blocking group reagent used for carboxylic acids, phenols, mercaptans and thiophenols. It is a derivatizing agent for carboxylic acids giving esters with enhanced UV and fluorescence detection in HPLC.

Purification Methods

If it is free from OH in the IR then recrystallisation from hexane/*C6H6 or *C6H6 (as needles). If OH is present, then some solvolysis has occurred. In this case treat 8.5g of it with SOCl2 (4.8g) in dioxane (60mL) and reflux for 5hours, then evaporate to dryness and wash the residue with cold *C6H6 and recrystallise it. With KI/Me2CO it forms the iodomethyl derivative. [Fierens et al. Helv Chim Acta 38 2009 1955, Hunter et al. J Org Chem 21 1512 1956, Beilstein 5 III 3152, 5 IV 2313.]

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9-(choromethyl)anthracene 9-CHLOROMETHYL-ANTHRACENE, FOR FLUOR-ESC ENCE 9-(CHLOROMETHYL)ANTHRACENE, 98+% (9-Anthryl)methyl chloride (9-Anthrylmethyl) chloride 9-(chloroMethyl)antracene 9-(ChloroMethyl)anthracene, 98+% 10GR 9-(ChloroMethyl)anthracene, 98+% 2.5GR 9-(Chloromethyl)anthracene BioReagent, suitable for fluorescence, >=97.0% (AT) 9-CHLOROMETHYLANTHRACENE, FOR HPLC LABELING 9-anthracenylmethylchloride 9-Chlormethyl-anthracen 9-Chloromethyanthracene 9-chloromethyl-anthracen Anthracene, 9-(chloromethyl)- ICR 448 9-CHLOROMETHYLANTHRACENE 9-Chloromethylanthracene > 9-Chloromethylanthracene [for HPLC Labeling]> 9-Chloromethylanthracene, 98%, reagent grade icr448 24463-19-2 463-19-2 24463-98-3 C15H11Cl BENZYL HALIDE HPLC Labeling Reagents Fluorescence Detection (HPLC Labeling Reagents) Carboxyl Group Labeling Reagents for HPLC UV Detection (HPLC Labeling Reagents) Anthracenes Carboxyl Group Labeling Reagents for Fluorescence HPLC Detection Derivatization agents Fluorescent Probes, Labels, Particles and Stains Luminescent Compounds/Detection BioChemical Biochemicals and Reagents Other APIs Aromatic Hydrocarbons (substituted) & Derivatives Analytical Chemistry Anthracenes Carboxyl Group Labeling Reagents for Fluorescence HPLC Carboxyl Group Labeling Reagents for HPLC Fluorescence Detection (HPLC Labeling Reagents) HPLC Labeling Reagents UV Detection (HPLC Labeling Reagents) Derivatization agentsOrganic Electronics and Photonics Biochemicals and Reagents Luminescent Compounds/Detection Synthetic Intermediates Synthetic Tools and Reagents AlphabeticalFluorescent Labels Carbohydrate Labels Carbohydrate Labels for ChromatographyBiochemicals and Reagents DetectionFluorescent Probes, Labels, Particles and Stains Fluorescent Labels Fluorescent Probes, Labels, Particles and Stains