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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >The polycyclic compound >DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Structure
  • ₹21200
  • Product name: DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
  • CAS: 134524-84-8
  • MF: C44H32Cl2P2Ru
  • MW: 794.65
  • EINECS:634-379-4
  • MDL Number:MFCD01073794
  • Synonyms:(S)-(-)-2,2''-Bis-(diphenylphosphino)-1,1''-binaphthyl ruthenium dichloride;[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride;Dichloro〔(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl〕ruthenium(Ⅱ);Dichloro[(S)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(S)-BINAP]RuCl2;(S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium;-binaphthyl]dichlororuthenium;-binaphthyl]ruthenium(II),(S-BINAP)RuCl2;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
1 prices
Selected condition:

Brand

  • TCI Chemicals (India)

Package

  • 250MG
  • ManufacturerTCI Chemicals (India)
  • Product numberB3068
  • Product description[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
  • Packaging250MG
  • Price₹21200
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B3068 [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride 250MG ₹21200 2022-05-26 Buy

Properties

Melting point :>300 ºC
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
solubility :Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated)
form :Powder
color :orange
Sensitive :air sensitive
Stability :Air Sensitive, Moisture Sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.

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