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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >Hexamethylphosphorous triamide

Hexamethylphosphorous triamide

Hexamethylphosphorous triamide Structure
  • ₹4687.23 - ₹36900
  • Product name: Hexamethylphosphorous triamide
  • CAS: 1608-26-0
  • MF: C6H18N3P
  • MW: 163.2
  • EINECS:216-534-4
  • MDL Number:MFCD00008301
  • Synonyms:HEXAMETHYLTRIAMINOPHOSPHINE;HEXAMETHYLPHOSPHOROUS TRIAMIDE;Trisdimethylaminophosphorus;HEXAMETHYLPHOSPHOROUS TRIAMIDE, 97 %;LABOTEST-BB LT00067758;HEXAMETHYLPHOSPHOROUS TRIAMIDE, TECH., 8 5%;Tris(dimethylamino)phosphine,min.98%HMPT;Tris(dimethylamino)phosphine (may contain precipitate)
4 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5ML
  • 25ML
  • 250ML
  • ManufacturerTCI Chemicals (India)
  • Product numberT1317
  • Product descriptionTris(dimethylamino)phosphine (may contain precipitate) min. 96.0 %
  • Packaging25ML
  • Price₹4800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT1317
  • Product descriptionTris(dimethylamino)phosphine (may contain precipitate) min. 96.0 %
  • Packaging250ML
  • Price₹36900
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number393290
  • Product descriptionTris(dimethylamino)phosphine 97%
  • Packaging5ML
  • Price₹4687.23
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number393290
  • Product descriptionTris(dimethylamino)phosphine 97%
  • Packaging25ML
  • Price₹11972.45
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) T1317 Tris(dimethylamino)phosphine (may contain precipitate) min. 96.0 % 25ML ₹4800 2022-05-26 Buy
TCI Chemicals (India) T1317 Tris(dimethylamino)phosphine (may contain precipitate) min. 96.0 % 250ML ₹36900 2022-05-26 Buy
Sigma-Aldrich(India) 393290 Tris(dimethylamino)phosphine 97% 5ML ₹4687.23 2022-06-14 Buy
Sigma-Aldrich(India) 393290 Tris(dimethylamino)phosphine 97% 25ML ₹11972.45 2022-06-14 Buy

Properties

Melting point :-44 °C
Boiling point :48-50 °C/12 mmHg (lit.)
Density :0.898 g/mL at 25 °C (lit.)
refractive index :n20/D 1.463(lit.)
Flash point :73 °F
storage temp. :Inert atmosphere,2-8°C
pka :8.03±0.70(Predicted)
form :Liquid
Specific Gravity :0.8980
color :Clear colorless to slightly yellow
Water Solubility :REACTS
Sensitive :Moisture Sensitive
BRN :906778
Stability :Stable. Highly flammable - note low flash point. Incompatible with oxidizing agents.
InChIKey :XVDBWWRIXBMVJV-UHFFFAOYSA-N
CAS DataBase Reference :1608-26-0(CAS DataBase Reference)
NIST Chemistry Reference :Phosphorous triamide, hexamethyl-(1608-26-0)
EPA Substance Registry System :Phosphorous triamide, hexamethyl- (1608-26-0)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H340 May cause genetic defects Germ cell mutagenicity Category 1A, 1B Danger GHS hazard pictograms
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger GHS hazard pictograms
Precautionary statements:
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

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