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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >tert-Butyldichlorophosphine

tert-Butyldichlorophosphine

tert-Butyldichlorophosphine Structure
  • ₹1757 - ₹46244
  • Product name: tert-Butyldichlorophosphine
  • CAS: 25979-07-1
  • MF: C4H9Cl2P
  • MW: 158.99
  • EINECS:247-386-9
  • MDL Number:MFCD00013615
  • Synonyms:DICHLORO-TERT-BUTYLPHOSPHINE;AURORA KA-1260;T-BUTYLDICHLOROPHOSPHINE;T-BUTYLPHOSPHONOUS DICHLORIDE;TERT-BUTYLDICHLOROPHOSPHINE;Phosphonous dichloride, (1,1-dimethylethyl)-;tert-Butylphosphonous dichloride;tert-C4H9PCl2
5 prices
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Brand

  • ALFA India
  • Sigma-Aldrich(India)

Package

  • 1g
  • 10g
  • 50g
  • 100ML
  • ManufacturerALFA India
  • Product numberALF-H27360-03
  • Product descriptiontert-Butyldichlorophosphine, 98%
  • Packaging1g
  • Price₹1757
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H27360-09
  • Product descriptiontert-Butyldichlorophosphine, 98%
  • Packaging10g
  • Price₹10500
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H27360-18
  • Product descriptiontert-Butyldichlorophosphine, 98%
  • Packaging50g
  • Price₹46244
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number707230
  • Product descriptiontert-Butyldichlorophosphine solution 1.0?M in diethyl ether
  • Packaging100ML
  • Price₹3690
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number381020
  • Product descriptiontert-Butyldichlorophosphine 98%
  • Packaging10G
  • Price₹7263.58
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-H27360-03 tert-Butyldichlorophosphine, 98% 1g ₹1757 2022-05-26 Buy
ALFA India ALF-H27360-09 tert-Butyldichlorophosphine, 98% 10g ₹10500 2022-05-26 Buy
ALFA India ALF-H27360-18 tert-Butyldichlorophosphine, 98% 50g ₹46244 2022-05-26 Buy
Sigma-Aldrich(India) 707230 tert-Butyldichlorophosphine solution 1.0?M in diethyl ether 100ML ₹3690 2022-06-14 Buy
Sigma-Aldrich(India) 381020 tert-Butyldichlorophosphine 98% 10G ₹7263.58 2022-06-14 Buy

Properties

Melting point :44-49 °C(lit.)
Boiling point :142-150 °C
Density :0.766 g/mL at 25 °C
storage temp. :Inert atmosphere,2-8°C
form :Low Melting Crystalline Mass
color :White to light yellow
Water Solubility :Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.
Sensitive :Air Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
CAS DataBase Reference :25979-07-1(CAS DataBase Reference)
NIST Chemistry Reference :Tert-butyldichlorophosphine(25979-07-1)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363 Wash contaminated clothing before reuse.

Description

Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

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