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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organolithium >Lithium acetylide ethylenediamine complex

Lithium acetylide ethylenediamine complex

Lithium acetylide ethylenediamine complex Structure
  • ₹3810.4 - ₹13919
  • Product name: Lithium acetylide ethylenediamine complex
  • CAS: 6867-30-7
  • MF: C4H7LiN2
  • MW: 90.05
  • EINECS:229-967-9
  • MDL Number:MFCD00013183
  • Synonyms:LITHIUM ACETYLIDE-ETHYLENEDIAMINE COMPLE X, 25 WT. % SLURRY IN TOLUENE;1,2-ethanediamine,compd.withlithiumacetylide(li(c2h))(1:1) ;Lithium, (1,2-ethanediamine-.kappa.N,.kappa.N)ethynyl-;LITHIUM ACETYLIDE ETHYLENEDIAMINE COMPLEX: TECH., 90%;lithium acetylene, ethylenediamine complex;LithiuM acetylide ethylenediaMine coMplex, 85% 50GR;LithiuM acetylide ethylenediaMine coMplex, 25 wt.% slurry in toluene, AcroSeal;LITHIUM ACETYLIDE-ETHYLENEDIAMINE COMPLE
Price5 Properties Safety Information Description
5 prices
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Brand

  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 10G
  • 25g
  • 50G
  • 100G
  • ManufacturerSigma-Aldrich(India)
  • Product number186155
  • Product descriptionLithium acetylide, ethylenediamine complex 90%
  • Packaging10G
  • Price₹3810.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number186155
  • Product descriptionLithium acetylide, ethylenediamine complex 90%
  • Packaging50G
  • Price₹10002.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number186155
  • Product descriptionLithium acetylide, ethylenediamine complex 90%
  • Packaging100G
  • Price₹10597.68
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L12401-22
  • Product descriptionLithium acetylide ethylenediamine complex, tech. 85%
  • Packaging100g
  • Price₹13919
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L12401-14
  • Product descriptionLithium acetylide ethylenediamine complex, tech. 85%
  • Packaging25g
  • Price₹5259
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 186155 Lithium acetylide, ethylenediamine complex 90% 10G ₹3810.4 2022-06-14 Buy
Sigma-Aldrich(India) 186155 Lithium acetylide, ethylenediamine complex 90% 50G ₹10002.3 2022-06-14 Buy
Sigma-Aldrich(India) 186155 Lithium acetylide, ethylenediamine complex 90% 100G ₹10597.68 2022-06-14 Buy
ALFA India ALF-L12401-22 Lithium acetylide ethylenediamine complex, tech. 85% 100g ₹13919 2022-05-26 Buy
ALFA India ALF-L12401-14 Lithium acetylide ethylenediamine complex, tech. 85% 25g ₹5259 2022-05-26 Buy

Properties

Melting point :76 °C (dec.)
Boiling point :110.6 °C (lit.)
Density :1,04 g/cm3
Flash point :7 °F
storage temp. :2-8°C
solubility :Soluble in ethylene diamine, n-propyl amine, n-butyl amine, pyridine, dimethyl formamaide, diglyme, dioxan and dimethylsulfoxide.
form :Crystals or Crystalline Powder
color :Slightly yellow to light brownor
Sensitive :Moisture Sensitive
BRN :3593824
InChIKey :QJQWXTYPTBEPGS-UHFFFAOYSA-N
CAS DataBase Reference :6867-30-7(CAS DataBase Reference)
EPA Substance Registry System :Lithium, (1,2-ethanediamine-.kappa.N,.kappa.N')ethynyl- (6867-30-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

Description

Lithium acetylide ethylenediamine complex is used in the synthesis of a chiral cyclopropanol. It is also used as an alkynylating reagent for the enantioselective alkynylation of ketones catalyzed by lithium binaphtholate without using other metal sources.

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Suppliers and manufacturers

JSK Chemicals ALS INDIA LIFE SCIENCES Anand Agencies Parad Chem Corporation ASM Organics TCI Chemicals (India) Pvt. Ltd. CLEARSYNTH LABS LTD. CHEMSWORTH Alfa Aesar Avra Synthesis Pvt Ltd