(-)-Taddol
- ₹3700 - ₹16031.83
- Product name: (-)-Taddol
- CAS: 93379-48-7
- MF: C31H30O4
- MW: 466.58
- EINECS:
- MDL Number:MFCD00064467
- Synonyms:(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE;(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-DIOXOLANE;(-)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2,2-DIMETHYL-1,3-DIOXOLANE;(R,R)-TADDOL;(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL;(-)-TADDOL;TADDOL;SEEBACH REAGENT
3 prices
Selected condition:
Brand
- TCI Chemicals (India)
- Sigma-Aldrich(India)
Package
- 1G
- 5G
- ManufacturerTCI Chemicals (India)
- Product numberB1614
- Product description(-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
- Packaging1G
- Price₹3700
- Updated2022-05-26
- Buy
- ManufacturerTCI Chemicals (India)
- Product numberB1614
- Product description(-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
- Packaging5G
- Price₹9800
- Updated2022-05-26
- Buy
- ManufacturerSigma-Aldrich(India)
- Product number265004
- Product description(4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol 97%
- Packaging1G
- Price₹16031.83
- Updated2022-06-14
- Buy
Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|
TCI Chemicals (India) | B1614 | (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane | 1G | ₹3700 | 2022-05-26 | Buy |
TCI Chemicals (India) | B1614 | (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane | 5G | ₹9800 | 2022-05-26 | Buy |
Sigma-Aldrich(India) | 265004 | (4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol 97% | 1G | ₹16031.83 | 2022-06-14 | Buy |
Properties
Melting point :193-195 °C(lit.)
alpha :-65.5 º (c=1, CHCl3)
Boiling point :489.39°C (rough estimate)
Density :1.0864 (rough estimate)
refractive index :-69 ° (C=1, CHCl3)
storage temp. :Inert atmosphere,Room Temperature
pka :12.28±0.29(Predicted)
form :Powder
color :white
optical activity :[α]19/D 62.6°, c = 1 in chloroform
BRN :3657855
InChIKey :RNSJHECWLNVNFE-KYJUHHDHSA-N
CAS DataBase Reference :93379-48-7(CAS DataBase Reference)
alpha :-65.5 º (c=1, CHCl3)
Boiling point :489.39°C (rough estimate)
Density :1.0864 (rough estimate)
refractive index :-69 ° (C=1, CHCl3)
storage temp. :Inert atmosphere,Room Temperature
pka :12.28±0.29(Predicted)
form :Powder
color :white
optical activity :[α]19/D 62.6°, c = 1 in chloroform
BRN :3657855
InChIKey :RNSJHECWLNVNFE-KYJUHHDHSA-N
CAS DataBase Reference :93379-48-7(CAS DataBase Reference)
Safety Information
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Description
Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bondingCatalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amides
Reactant or reagent involved in:
- Enantioswitching of catalytic asymmetric hydroboration
- Synthesis of derivative ligands for asymmetric hydroformylation of alkenes
- Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes
- Addition of deactivated alkyl Grignard reagents to aldehydes
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