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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphine ligand >(-)-Taddol

(-)-Taddol

(-)-Taddol Structure
  • ₹3700 - ₹16031.83
  • Product name: (-)-Taddol
  • CAS: 93379-48-7
  • MF: C31H30O4
  • MW: 466.58
  • EINECS:
  • MDL Number:MFCD00064467
  • Synonyms:(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE;(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-DIOXOLANE;(-)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2,2-DIMETHYL-1,3-DIOXOLANE;(R,R)-TADDOL;(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL;(-)-TADDOL;TADDOL;SEEBACH REAGENT
3 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • ManufacturerTCI Chemicals (India)
  • Product numberB1614
  • Product description(-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
  • Packaging1G
  • Price₹3700
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1614
  • Product description(-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
  • Packaging5G
  • Price₹9800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number265004
  • Product description(4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol 97%
  • Packaging1G
  • Price₹16031.83
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B1614 (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane 1G ₹3700 2022-05-26 Buy
TCI Chemicals (India) B1614 (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane 5G ₹9800 2022-05-26 Buy
Sigma-Aldrich(India) 265004 (4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol 97% 1G ₹16031.83 2022-06-14 Buy

Properties

Melting point :193-195 °C(lit.)
alpha :-65.5 º (c=1, CHCl3)
Boiling point :489.39°C (rough estimate)
Density :1.0864 (rough estimate)
refractive index :-69 ° (C=1, CHCl3)
storage temp. :Inert atmosphere,Room Temperature
pka :12.28±0.29(Predicted)
form :Powder
color :white
optical activity :[α]19/D 62.6°, c = 1 in chloroform
BRN :3657855
InChIKey :RNSJHECWLNVNFE-KYJUHHDHSA-N
CAS DataBase Reference :93379-48-7(CAS DataBase Reference)

Safety Information

Symbol(GHS):
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Hazard statements:
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Description

Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bonding

Catalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amides

Reactant or reagent involved in:
  • Enantioswitching of catalytic asymmetric hydroboration
  • Synthesis of derivative ligands for asymmetric hydroformylation of alkenes
  • Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes
  • Addition of deactivated alkyl Grignard reagents to aldehydes

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