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(-)-Taddol

(-)-Taddol Structure
CAS No.
93379-48-7
Chemical Name:
(-)-Taddol
Synonyms
5R)-2;TADDOL;(-)-TADDOL;(R,R)-TADDOL;SEEBACH REAGENT;(-)-TADDOL 98%, (99% E.E.);(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-;(2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHY;(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)2, 2-DIMETHYL;(-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol
CBNumber:
CB1399332
Molecular Formula:
C31H30O4
Molecular Weight:
466.58
MOL File:
93379-48-7.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

(-)-Taddol Properties

Melting point 193-195 °C(lit.)
alpha -65.5 º (c=1, CHCl3)
Boiling point 489.39°C (rough estimate)
Density 1.0864 (rough estimate)
refractive index -69 ° (C=1, CHCl3)
storage temp. Inert atmosphere,Room Temperature
pka 12.28±0.29(Predicted)
form Powder
color white
optical activity [α]19/D 62.6°, c = 1 in chloroform
BRN 3657855
InChIKey RNSJHECWLNVNFE-KYJUHHDHSA-N
CAS DataBase Reference 93379-48-7(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Hazard Codes  Xi,Xn
Risk Statements  36/38-36/37/38-20/21/22
Safety Statements  24/25-36-26
WGK Germany  3
HS Code  29329970

(-)-Taddol price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 265004 (4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol 97% 93379-48-7 1G ₹16031.83 2022-06-14 Buy
TCI Chemicals (India) B1614 (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane 93379-48-7 1G ₹3700 2022-05-26 Buy
TCI Chemicals (India) B1614 (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane 93379-48-7 5G ₹9800 2022-05-26 Buy
Product number Packaging Price Buy
265004 1G ₹16031.83 Buy
B1614 1G ₹3700 Buy
B1614 5G ₹9800 Buy

(-)-Taddol Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bonding

Catalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amides

Reactant or reagent involved in:

  • Enantioswitching of catalytic asymmetric hydroboration
  • Synthesis of derivative ligands for asymmetric hydroformylation of alkenes
  • Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes
  • Addition of deactivated alkyl Grignard reagents to aldehydes

(-)-Taddol Preparation Products And Raw materials

Global( 173)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
OCEAN TRADING CORPORATION +91(22) 24921669 New Delhi, India 6211 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Reax Chemicals 08048372701Ext 416 Hyderabad, India 4223 58 Inquiry
Clearsynth Labs 91-22-45045900 Maharashtra, India 3889 58 Inquiry
Khandelwal Laboratories Pvt., Ltd. 91-22-23724214 Maharashtra, India 25 58 Inquiry
Chiral Chemicals 91-22-66332438 Maharashtra, India 143 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 18656 58 Inquiry
ATK CHEMICAL COMPANY LIMITED +undefined-21-51877795 China 32835 60 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29899 58 Inquiry
(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-DIOXOLANE (-)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2,2-DIMETHYL-1,3-DIOXOLANE (R,R)-TADDOL (R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL (-)-TADDOL TADDOL SEEBACH REAGENT (4R,5R)-2,2-DIMETHYL-ALPHA, ALPHA, ALPHA', ALPHA'-TETRAPHENYLDIOXOLANE-4,5-DIMETHANOL (4R,5R)-(-)-2,2-DIMETHYL-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOL TADDOL, (4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane, 1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol, (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol TADDOL, (4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane, 1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol, (-)-trans-α,αμ-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol), (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol (-)-trans-a,a'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) [(4R,5R)-5-(hydroxy-diphenyl-methyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-diphenyl-methanol 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-a,a,a',a'-tetraphenyl-, (4R,5R)- (4R)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4β,5α-bismethanol (4R,5R)-2,2-Dimethyl-4,5-bis(hydroxydiphenylmethyl)-1,3-dioxolane (4R,5R)-4,5-Bis(hydroxydiphenylmethyl)-2,2-dimethyl-1,3-dioxolane (4R,5R)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4,5-bismethanol α,α'-[(4R,5R)-2,2-Dimethyl-1,3-dioxolane-4β,5α-diyl]bis(diphenylmethanol) (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol(-TADDOL) (-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol, TADDOL (4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol ,97% (4R,5R)-(-)-2,2-Dimethyl-a,a,a',a'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol (-)-TRANS-4,5-BIS-(DIPHENYL-HYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (-)-TRANS-ALPHA,ALPHA'-(2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(DIPHENYLMETHANOL) (-)-TRANS-ALPHA,ALPHA'-(DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(DIPHENYLMETHANOL) (-)-2,3-O-Isopropylidene-1,1,4,4-Tetraphenyl-L-Threitol(4R,5R)-2,2-Dimethyl-Alpha,Alpha,Alpha',Alpha'-Tetraphenyldioxolane-4,5-Dimethanol (4R,5R)-2,2-Dimethyl-a,a,a',a'-tetraphenyldioxolane-4,5-dimethanol ( - )-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl- L-threitol [(4R,5R)-2,2-Dimethyl-a,a,a’, a’-tetraphenyldioxolane-4,5-dimethanol (-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol (-)-TRANS-A,A'-(2,2-DIMETHYL-1,3-DIOXOLA NE -4,5-DIYL)BIS(DIPHENYLMETHANOL) (4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)2, 2-DIMETHYL (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethan (-)-Trans-A,A'-(2,2-Dimethyl-1,3-Dioxolane-4,5-Diyl)Bis(Diphenylmethanol),ChemAbs (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol[(4R,5R)-2,2-
Dimethyl-a,a,aatetraphenyldioxolane-4,5-dimethanol
(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanol(R,R)-TADDOL (4r,5r)-2,2-dimethyl-α,α,α',α'-tetraphenyldioxolane-4,5-dimethanol (-)-TADDOL 98%, (99% E.E.) (2R,3R)-(-)-1,1,4,4-TETRAPHENYL-2,3-(2-PROPYLIDENEDIOXY)-BUTANE-1,4-DIOL (2R,3R)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-1,2,3,4-BUTANETETROL (2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL (-)-(4R,5R)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOL (-)-trans-alpha,alpha'-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (2R,3R)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-1,2,3,4-butanetetrol (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol (2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHY (-)-Taddol (-)-trans-alpha,alpha'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol 97% 5R)-2 (R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4- (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL '-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane > (-)-trans-α,α'-(2,2-Dimethyl-1,3-dioxane-4,5-diyl)bis(diphenylmethanol) 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetraphenyl-, (4R,5R)- (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxol...