(-)-Taddol
- CAS No.
- 93379-48-7
- Chemical Name:
- (-)-Taddol
- Synonyms
- 5R)-2;TADDOL;(-)-TADDOL;(R,R)-TADDOL;SEEBACH REAGENT;(-)-TADDOL 98%, (99% E.E.);(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-;(2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHY;(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)2, 2-DIMETHYL;(-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol
- CBNumber:
- CB1399332
- Molecular Formula:
- C31H30O4
- Molecular Weight:
- 466.58
- MOL File:
- 93379-48-7.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
Melting point | 193-195 °C(lit.) |
---|---|
alpha | -65.5 º (c=1, CHCl3) |
Boiling point | 489.39°C (rough estimate) |
Density | 1.0864 (rough estimate) |
refractive index | -69 ° (C=1, CHCl3) |
storage temp. | Inert atmosphere,Room Temperature |
pka | 12.28±0.29(Predicted) |
form | Powder |
color | white |
optical activity | [α]19/D 62.6°, c = 1 in chloroform |
BRN | 3657855 |
InChIKey | RNSJHECWLNVNFE-KYJUHHDHSA-N |
CAS DataBase Reference | 93379-48-7(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Hazard Codes | Xi,Xn |
---|---|
Risk Statements | 36/38-36/37/38-20/21/22 |
Safety Statements | 24/25-36-26 |
WGK Germany | 3 |
HS Code | 29329970 |
(-)-Taddol price More Price(3)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 265004 | (4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol 97% | 93379-48-7 | 1G | ₹16031.83 | 2022-06-14 | Buy |
TCI Chemicals (India) | B1614 | (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane | 93379-48-7 | 1G | ₹3700 | 2022-05-26 | Buy |
TCI Chemicals (India) | B1614 | (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane | 93379-48-7 | 5G | ₹9800 | 2022-05-26 | Buy |
(-)-Taddol Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powde
Uses
Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bonding
Catalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amides
Reactant or reagent involved in:
- Enantioswitching of catalytic asymmetric hydroboration
- Synthesis of derivative ligands for asymmetric hydroformylation of alkenes
- Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes
- Addition of deactivated alkyl Grignard reagents to aldehydes
(-)-Taddol Preparation Products And Raw materials
Raw materials
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93379-48-7((-)-Taddol)Related Search:
DIOXOPROMETHAZINE HCL
DIOXOPROMETHAZINE
(4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOL
(3AR,8AR)-(-)-(2,2-DIMETHYL-4,4,8,8-TETRAPHENYL-TETRAHYDRO-[1,3]DIOXOLO[4,5-E][1,3,2]DIOXAPHOSPHEPIN-6-YL)DIMETHYLAMINE
(+)-Taddol,(+)-TADDOL,(+)-Taddol,(+)-TADDOL
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(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE
(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-DIOXOLANE
(-)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2,2-DIMETHYL-1,3-DIOXOLANE
(R,R)-TADDOL
(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL
(-)-TADDOL
TADDOL
SEEBACH REAGENT
(4R,5R)-2,2-DIMETHYL-ALPHA, ALPHA, ALPHA', ALPHA'-TETRAPHENYLDIOXOLANE-4,5-DIMETHANOL
(4R,5R)-(-)-2,2-DIMETHYL-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOL
TADDOL, (4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane, 1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol, (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol
TADDOL, (4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane, 1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol, (-)-trans-α,αμ-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol), (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol
(-)-trans-a,a'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol)
[(4R,5R)-5-(hydroxy-diphenyl-methyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-diphenyl-methanol
1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-a,a,a',a'-tetraphenyl-, (4R,5R)-
(4R)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4β,5α-bismethanol
(4R,5R)-2,2-Dimethyl-4,5-bis(hydroxydiphenylmethyl)-1,3-dioxolane
(4R,5R)-4,5-Bis(hydroxydiphenylmethyl)-2,2-dimethyl-1,3-dioxolane
(4R,5R)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4,5-bismethanol
α,α'-[(4R,5R)-2,2-Dimethyl-1,3-dioxolane-4β,5α-diyl]bis(diphenylmethanol)
(4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol(-TADDOL)
(-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol, TADDOL
(4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol ,97%
(4R,5R)-(-)-2,2-Dimethyl-a,a,a',a'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL
(4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol
(-)-TRANS-4,5-BIS-(DIPHENYL-HYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE
(-)-TRANS-ALPHA,ALPHA'-(2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(DIPHENYLMETHANOL)
(-)-TRANS-ALPHA,ALPHA'-(DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(DIPHENYLMETHANOL)
(-)-2,3-O-Isopropylidene-1,1,4,4-Tetraphenyl-L-Threitol(4R,5R)-2,2-Dimethyl-Alpha,Alpha,Alpha',Alpha'-Tetraphenyldioxolane-4,5-Dimethanol
(4R,5R)-2,2-Dimethyl-a,a,a',a'-tetraphenyldioxolane-4,5-dimethanol
( - )-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl- L-threitol [(4R,5R)-2,2-Dimethyl-a,a,a’, a’-tetraphenyldioxolane-4,5-dimethanol
(-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol
(-)-TRANS-A,A'-(2,2-DIMETHYL-1,3-DIOXOLA NE -4,5-DIYL)BIS(DIPHENYLMETHANOL)
(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)2, 2-DIMETHYL
(4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethan
(-)-Trans-A,A'-(2,2-Dimethyl-1,3-Dioxolane-4,5-Diyl)Bis(Diphenylmethanol),ChemAbs
(-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol[(4R,5R)-2,2-
Dimethyl-a,a,aatetraphenyldioxolane-4,5-dimethanol (4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanol(R,R)-TADDOL (4r,5r)-2,2-dimethyl-α,α,α',α'-tetraphenyldioxolane-4,5-dimethanol (-)-TADDOL 98%, (99% E.E.) (2R,3R)-(-)-1,1,4,4-TETRAPHENYL-2,3-(2-PROPYLIDENEDIOXY)-BUTANE-1,4-DIOL (2R,3R)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-1,2,3,4-BUTANETETROL (2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL (-)-(4R,5R)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOL (-)-trans-alpha,alpha'-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (2R,3R)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-1,2,3,4-butanetetrol (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol (2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHY (-)-Taddol (-)-trans-alpha,alpha'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol 97% 5R)-2 (R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4- (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL '-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane > (-)-trans-α,α'-(2,2-Dimethyl-1,3-dioxane-4,5-diyl)bis(diphenylmethanol) 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetraphenyl-, (4R,5R)- (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxol...
Dimethyl-a,a,aatetraphenyldioxolane-4,5-dimethanol (4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanol(R,R)-TADDOL (4r,5r)-2,2-dimethyl-α,α,α',α'-tetraphenyldioxolane-4,5-dimethanol (-)-TADDOL 98%, (99% E.E.) (2R,3R)-(-)-1,1,4,4-TETRAPHENYL-2,3-(2-PROPYLIDENEDIOXY)-BUTANE-1,4-DIOL (2R,3R)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-1,2,3,4-BUTANETETROL (2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL (-)-(4R,5R)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOL (-)-trans-alpha,alpha'-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (2R,3R)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-1,2,3,4-butanetetrol (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol (2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHY (-)-Taddol (-)-trans-alpha,alpha'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol 97% 5R)-2 (R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4- (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL '-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane > (-)-trans-α,α'-(2,2-Dimethyl-1,3-dioxane-4,5-diyl)bis(diphenylmethanol) 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetraphenyl-, (4R,5R)- (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxol...