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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic aluminum >Triethylaluminum

Triethylaluminum

Triethylaluminum Structure
  • ₹0
  • Product name: Triethylaluminum
  • CAS: 97-93-8
  • MF: C6H15Al
  • MW: 114.16
  • EINECS:202-619-3
  • MDL Number:MFCD00009015
  • Synonyms:TRIETHYLALUMINUM;Triethylaluminum,93+%;Triethylaluminium, 0.6M solution in heptane;Triethylaluminium, 1.3M solution in heptane;Triethylaluminum, min. 93%;Triethylaluminium1.3M solution in heptaneAcroSeal§3;Triethylaluminium0.6M solution in heptaneAcroSeal§3;TRIETHYLALUMINUM, 1.0M in HEXANE
Manufacturer Product number Product description Packaging Price Updated Buy

Properties

Melting point :-50°C
Boiling point :128-130°C (50 mmHg)
Density :0.85 g/mL at 20 °C
vapor pressure :1 mmHg ( 62.2 °C)
Flash point :−1 °F
storage temp. :0-6°C
form :liquid
color :colorless
Water Solubility :reacts
Sensitive :Air & Moisture Sensitive
BRN :3587229
Dielectric constant :6.4(20℃)
Exposure limits :ACGIH: TWA 50 ppm (Skin)
OSHA: TWA 500 ppm(1800 mg/m3)
NIOSH: IDLH 1100 ppm; TWA 50 ppm(180 mg/m3) InChIKey :VOITXYVAKOUIBA-UHFFFAOYSA-N
CAS DataBase Reference :97-93-8(CAS DataBase Reference)
NIST Chemistry Reference :Triethylaluminum(97-93-8)
EPA Substance Registry System :Triethylaluminum (97-93-8)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H252 Self-heating in large quantities; may catch fire Self-heating substances and mixtures Category 2 Warning P235+P410, P280, P407, P413, P420
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.

Description

Triethylaluminum is used as a co-catalyst in the industrial production of polyethylene and for the production of medium chain alcohols. Used as a catalyst in Ziegler-Natta polymerization process for vinyl, olefin, diene polymerizations and linear oligomerization and cyclization of unsaturated hydrocarbons. It is also used as a catalyst to produce ethylene gas, chain growth of ethylene, longer chain aluminum alkyls, and in plating aluminum.

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