1,2-Ethanedithiol
- CAS No.
- 540-63-6
- Chemical Name:
- 1,2-Ethanedithiol
- Synonyms
- EDT;ethane-1,2-dithiol;ETHANEDITHIOL;EDT(L);L k Vadehra;Ethylenedithiol;1,2-dithioethane;dimercaptoethane;1,2-Ethandithiol;1,2-DIMERCAPTOETHANE
- CBNumber:
- CB3742510
- Molecular Formula:
- C2H6S2
- Molecular Weight:
- 94.2
- MOL File:
- 540-63-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/16 10:30:56
Melting point | -41 °C (lit.) |
---|---|
Boiling point | 144-146 °C (lit.) |
Density | 1.123 g/mL at 25 °C (lit.) |
vapor density | >1 (vs air) |
vapor pressure | 4.8 mm Hg ( 20 °C) |
refractive index |
n |
FEMA | 3484 | 1,2-ETHANEDITHIOL |
Flash point | 122 °F |
storage temp. | Store below +30°C. |
pka | pK1:8.96;pK2:10.54 (25°C) |
form | Liquid |
color | Clear slightly colored |
Odor | at 0.01 % in propylene glycol. sulfury meaty |
Odor Type | sulfurous |
Water Solubility | insoluble |
Sensitive | Air Sensitive |
Merck | 14,3725 |
JECFA Number | 532 |
BRN | 505946 |
Stability | Stable. Flammable. Incompatible with oxidizing agents, bases, reducing agents, alkali metals. |
InChIKey | VYMPLPIFKRHAAC-UHFFFAOYSA-N |
LogP | 1.31 |
CAS DataBase Reference | 540-63-6(CAS DataBase Reference) |
NIST Chemistry Reference | 1,2-Ethanedithiol(540-63-6) |
EPA Substance Registry System | 1,2-Ethanedithiol (540-63-6) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS06 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H226-H301-H310+H330 | |||||||||
Precautionary statements | P210-P262-P280-P301+P310+P330-P302+P352+P310-P304+P340+P310 | |||||||||
Hazard Codes | T,Xn,F | |||||||||
Risk Statements | 10-23/24/25-23/25-21-36-23-21/22-36/37/38-20/21/22 | |||||||||
Safety Statements | 36/37/39-45-26-16-36/37-36-7/9 | |||||||||
RIDADR | UN 3071 6.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | KI3325000 | |||||||||
F | 10-13-23 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29309070 | |||||||||
Toxicity | LD50 orally in Rabbit: 120 mg/kg LD50 dermal Rabbit 197 mg/kg | |||||||||
NFPA 704 |
|
1,2-Ethanedithiol price More Price(15)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 8.00795 | 1,2-Ethanedithiol for synthesis | 540-63-6 | 100ML | ₹12060.01 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 8.00795 | 1,2-Ethanedithiol for synthesis | 540-63-6 | 500ML | ₹32370 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 398020 | 1,2-Ethanedithiol technical grade, ≥90% | 540-63-6 | 100ML | ₹6657.38 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 02390 | 1,2-Ethanedithiol ≥98.0% (GC) | 540-63-6 | 25ML | ₹4373.3 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 398020 | 1,2-Ethanedithiol technical grade, ≥90% | 540-63-6 | 500ML | ₹17200.93 | 2022-06-14 | Buy |
1,2-Ethanedithiol Chemical Properties,Uses,Production
Chemical Properties
1,2-Ethanedithiol has a repulsive odor.
Occurrence
Reported found in beef (boiled, cooked) and chicken (cooked)
Uses
1,2-Ethanedithiol is used as a reagent in organic synthesis to convert carbonyl compounds to thioacetals (1,3-dithiolanes). It replaces the toxic reagent arsenic tirchloride, which is involved in the synthesis of membrane-permeant fluorogenic biarsenicals from precursor dyes fluorescein and resorufin. It acts bidendate ligand to form complexes with metal ions.
Preparation
Prepared by reacting ethanol, thiourea and ethylene dibromide and subsequent alkaline hydrolysis of the ethylenediisothiuronium bromide
General Description
1,2-Ethanedithiol (1,2-Dimercaptoethane, Dithioglycol, Ethylene mercaptan) is an organo sulfur compound. It affords monomeric, dimeric and polymeric complexes on reaction with Pt(PPh3)4, Pd(PPh3)4 and Ni(PPh3)4. It has been synthesized by refluxing 1,2-dichloroethane with thiourea in ethanol.
Hazard
Vapors cause severe headache and nausea.
Safety Profile
Poison by ingestion, intraperitoneal, and intravenous routes. When heated to decomposition it emits very toxic fumes of SOx. See also MERCAPTANS .
1,2-Ethanedithiol Preparation Products And Raw materials
Raw materials
Preparation Products
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Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
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