ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Tosylate >2,2,2-Trifluoroethyl trifluoromethanesulfonate
2,2,2-Trifluoroethyl trifluoromethanesulfonate
- CAS No.
- 6226-25-1
- Chemical Name:
- 2,2,2-Trifluoroethyl trifluoromethanesulfonate
- Synonyms
- 2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULPHONATE;2,2,2-TRIFLUOROETHYL TRIFLATE;TFOL-TF;2,2,2-Trifluoroethyl Triflante;2,2,2-Trifluoroethyl trifluoromethanesulf;2-Trifluoroethyl trifluoromethanesulfonate;2,2,2-Trifluoroethyl trifluoromethanesulfote;2,2,2-Trifluoroethytrifluoromethanesulfonate;2,2,2-Trifluoroethyl trifluoroMethylsulfonate;2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULFONATE
- CBNumber:
- CB5142808
- Molecular Formula:
- C3H2F6O3S
- Molecular Weight:
- 232.1
- MOL File:
- 6226-25-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/3/13 9:24:55
| Boiling point | 89-91°C |
|---|---|
| Density | 1,61 g/cm3 |
| refractive index | 1.3037 |
| RTECS | PB2775000 |
| Flash point | >110°(230°F) |
| storage temp. | 2-8°C |
| solubility | Chloroform, Methanol (Slightly) |
| form | Liquid |
| color | Colorless to yellow |
| Water Solubility | Slightly soluble in water. |
| Sensitive | Moisture Sensitive |
| InChIKey | RTMMSCJWQYWMNK-UHFFFAOYSA-N |
| CAS DataBase Reference | 6226-25-1(CAS DataBase Reference) |
| EPA Substance Registry System | Methanesulfonic acid, trifluoro-, 2,2,2-trifluoroethyl ester (6226-25-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H314-H330 | |||||||||
| Precautionary statements | P260-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,T,C | |||||||||
| Risk Statements | 36/37/38-34-23/25 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | 3265 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| HazardClass | TOXIC, CORROSIVE | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | Ⅱ | |||||||||
| HS Code | 29055900 | |||||||||
| NFPA 704 |
|
2,2,2-Trifluoroethyl trifluoromethanesulfonate price More Price(2)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemicals (India) | T1604 | 2,2,2-Trifluoroethyl Trifluoromethanesulfonate min. 97.0 % | 6226-25-1 | 5G | ₹10800 | 2022-05-26 | Buy |
| TCI Chemicals (India) | T1604 | 2,2,2-Trifluoroethyl Trifluoromethanesulfonate min. 97.0 % | 6226-25-1 | 25G | ₹31200 | 2022-05-26 | Buy |
2,2,2-Trifluoroethyl trifluoromethanesulfonate Chemical Properties,Uses,Production
Uses
2,2,2-Trifluoroethyl trifluoromethanesulfonate is a powerful trifluoroethylating agent which is useful for synthesis of fluorinated amino acids. It is used as a reagent in thenantioselective preparation of cyclic N-aryl hydroxamic acids via phase-transfer catalyzed alkylation of nitrobenzyl bromides to give nirophenylalanines.
Synthesis
In a 100-ml flask equipped with a stirrer, a thermometer, a nitrogen introducing pipe, and a condenser, 50 ml (0.297 mol) of trifluoromethane sulfonic anhydride and 25 ml (0.342 moles) of 2,2,2-trifluoroethanol were placed at room temperature and stirred for 30 minutes in a nitrogen atmosphere, followed by reflux for 3 hours. After distillation, 50.3 g of 2,2,2-trifluoroethyl trifluoromethanesulfonate was obtained in a yield of 73%.
2,2,2-Trifluoroethyl trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
2,2,2-Trifluoroethanol
2,2,3,3,3-Pentafluoropropyl 2,2,2-trifluoroethyl carbonate
4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-1-(2,2,2-trifluoroethyl)-1H-pyrazole
TFEC
tert-butyl (1-(2,2,2-trifluoroethyl)piperidin-4-yl)carbaMate
4-NITRO-1-(2,2,2-TRIFLUOROETHYL)-1H-PYRAZOLE
ethyl 1-(2,2,2-trifluoroethyl)piperidine-4-carboxylate
3-Methyl-5-(2,2,2-trifluoroethoxy)picolinonitrile
2H-1-BENZAZEPIN-2-ONE 6-FLUORO-1,3,4,5-TETRAHYDRO-3-[4-[3-METHOXY-4-(4-METHYL-1H-IMIDAZOL-1-YL)PHENYL]-1H-1,2,3-TRIAZOL-1-YL]-1-(2,2,2-TRIFLUOROETHYL)-
(5-(2,2,2-trifluoroethoxy)pyridin-2-yl)methanol
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2,2,2-trifluoroethyltrifluorometanesulfonicacid
methanesulfonicacid,trifluoro-,2,2,2-trifluoroethylester
TRIFLUOROMETHANESULFONIC ACID 2,2,2-TRIFLUOROETHYL ESTER
TFOL-TF
2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULFONATE
2,2,2-Trifluoroethyltrifluoromethanesulphonate97%
TRIFLUOROMETHANESULPHONICACID2,2,2-TRIFLUOROETHYLESTER
2,2,2 Trifluoroethyl TrifluoroMathane sulfonate
2,2,2-Trifluoroethyl trifluoromethanesulphonate 97%
2,2,2-Trifluoroethanol TrifluoroMethanesulfonate
2,2,2-Trifluoroethyl trifluoroMethylsulfonate
2,2,2-Trifluoroethyl Triflate
Trifluoromethanesulfonic Acid 2,2,2-Trifluoroethyl Ester
2,2,2-Trifluoroethyl trifluoromethanesulfote
2-Trifluoroethyl trifluoromethanesulfonate
Trifluoromethane sulfonate trifluoroethyl ester
2,2,2-Trifluoroethytrifluoromethanesulfonate
1,1,1-Trifluoro-2,2,2-trifluoroethyl Ester Methanesulfonic Acid
Methanesulfonic acid, 1,1,1-trifluoro-, 2,2,2-trifluoroethyl ester
High purity CAS 6226-25-1 2,2,2-Trifluoroethyl trifluoromethanesulfonate in stock
2,2,2-TRIFLUOROETHYL TRIFLATE
2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULPHONATE
2,2,2-TRIFLUOROETHYL TRIFLATE
2,2,2-Trifluoroethyl Trifluoromethanesulfonate
2,2,2-Trifluoroethyl Triflante
2,2,2-Trifluoroethyl trifluoromethanesulf
6226-25-1
56226-25-1
C3H2F6O3S
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