ChemicalBook > Product Catalog >Organic Chemistry >Amides >Acyclic polyamines and their derivatives >Diethylaminosulfur trifluoride

Diethylaminosulfur trifluoride

Diethylaminosulfur trifluoride Structure
CAS No.
38078-09-0
Chemical Name:
Diethylaminosulfur trifluoride
Synonyms
DAST;ET2NSF3;DIETHYLAMINOSULPHUR TRIFLUORIDE;(diethylamino)trifluorosulfur;Diethylamine sulfur trifluoride;amino)suL;fur trifL;(beta-4)-sulfu;(T-4)-(N-ethyl;Oleamide 301-02-0
CBNumber:
CB5153161
Molecular Formula:
C4H10F3NS
Molecular Weight:
161.19
MOL File:
38078-09-0.mol
MSDS File:
SDS
Modify Date:
2024/6/17 17:42:23

Diethylaminosulfur trifluoride Properties

Boiling point 30-32 °C3 mm Hg(lit.)
Density 1.22 g/mL at 25 °C(lit.)
refractive index 1.41-1.416
Flash point 75 °F
storage temp. 2-8°C
solubility Benzene, Chloroform (Slightly)
pka -4.87±0.70(Predicted)
form liquid
Specific Gravity 1.220
color Colorless to Yellow to Orange
Water Solubility decomposes
Sensitive Moisture Sensitive
Merck 14,3113
BRN 1849066
Exposure limits ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
Stability Reacts with Moisture in the Air, Reacts With Moisture In The Air, Unstable in So
InChIKey CSJLBAMHHLJAAS-UHFFFAOYSA-N
CAS DataBase Reference 38078-09-0(CAS DataBase Reference)
NIST Chemistry Reference Diethylaminosulfur trifluoride(38078-09-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05
Signal word  Danger
Hazard statements  H226-H242-H314
Precautionary statements  P210-P280-P303+P361+P353-P305+P351+P338-P370+P378-P403+P235
Hazard Codes  C,T,F
Risk Statements  10-14-20/21/22-34-5-35-40
Safety Statements  16-26-36/37/39-45
RIDADR  UN 2920 8/PG 1
WGK Germany  3
3-10-21
Hazard Note  Corrosive/Keep Cold
HazardClass  8
PackingGroup  I
HS Code  29309070
NFPA 704
3
3 2
W

Diethylaminosulfur trifluoride price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 774642 (Diethylamino)sulfur trifluoride solution 1.0?M in dichloromethane 38078-09-0 10ML ₹5401.68 2022-06-14 Buy
Sigma-Aldrich(India) 774642 (Diethylamino)sulfur trifluoride solution 1.0?M in dichloromethane 38078-09-0 25ML ₹6040.35 2022-06-14 Buy
Sigma-Aldrich(India) 774642 (Diethylamino)sulfur trifluoride solution 1.0?M in dichloromethane 38078-09-0 100ML ₹16951.95 2022-06-14 Buy
Sigma-Aldrich(India) 235253 (Diethylamino)sulfur trifluoride 95% 38078-09-0 1G ₹1558.8 2022-06-14 Buy
Sigma-Aldrich(India) 235253 (Diethylamino)sulfur trifluoride 95% 38078-09-0 5G ₹5304.25 2022-06-14 Buy
Product number Packaging Price Buy
774642 10ML ₹5401.68 Buy
774642 25ML ₹6040.35 Buy
774642 100ML ₹16951.95 Buy
235253 1G ₹1558.8 Buy
235253 5G ₹5304.25 Buy

Diethylaminosulfur trifluoride Chemical Properties,Uses,Production

Chemical Properties

Pale yellow liquid. Soluble in most non-polar organic solvents, commonly used in CH2Cl2, CHCl3 and CCl4.

Uses

Diethylaminosulfur Trifluoride is a very useful Nucleophilic fluorinating agent in chemical synthesis. It is also used as a reagent in the preparation of 2-thiazolines from (1,2)-thioam ido-alcohols.

Application

Diethylaminosulfur trifluoride (DAST) is used as a precursor to prepare 2,6-dimethoxybenzoyl fluoride and 2-thiazolines. It is a useful fluorinating agent used for a variety of compounds including alcohols, thioethers, alkenols and cyanohydrins. It also serves as a catalyst for Friedel-Crafts allylation reaction using tertiary cyclopropyl silyl ethers and in the rearrangement of homoallylic alcohols to unsaturated aldehydes. It plays an important role for gem difluorination of ketopipecolinic acids.

Global( 450)Suppliers
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Triveni chemicals 08048762458 New Delhi, India 6093 58 Inquiry

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