2,3-Dimethyl-2,3-diphenylbutane
- CAS No.
- 1889-67-4
- Chemical Name:
- 2,3-Dimethyl-2,3-diphenylbutane
- Synonyms
- Dicumyl;DICUMENE;Perkadox 30;Bicumyl;3-Dimethyl-2;Interox CC-DFB;3-diphenylbutane;alpha,alpha'-Dicumyl;SALOR-INT L170127-1EA;Bibenzyl, alpha,alpha,alpha
- CBNumber:
- CB5194892
- Molecular Formula:
- C18H22
- Molecular Weight:
- 238.37
- MOL File:
- 1889-67-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/4/10 11:19:08
Melting point | 90-110 °C |
---|---|
Boiling point | 335.97°C (estimate) |
Density | 0.9859 (estimate) |
vapor pressure | 0.015Pa at 20℃ |
refractive index | 1.5413 (estimate) |
storage temp. | Sealed in dry,2-8°C |
form | Flakes, Crystalline Powder or Chunks |
color | White to light yellow |
Water Solubility | insoluble |
InChI | InChI=1S/C18H22/c1-17(2,15-11-7-5-8-12-15)18(3,4)16-13-9-6-10-14-16/h5-14H,1-4H3 |
InChIKey | HGTUJZTUQFXBIH-UHFFFAOYSA-N |
SMILES | C(C1=CC=CC=C1)(C)(C)C(C1=CC=CC=C1)(C)C |
LogP | 6.68 at 25℃ |
NIST Chemistry Reference | Benzene, 1,1'-(1,1,2,2-tetramethyl-1,2-ethanediyl)bis-(1889-67-4) |
EPA Substance Registry System | 2,3-Dimethyl-2,3-diphenylbutane (1889-67-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02 |
---|---|
Signal word | Warning |
Hazard statements | H226 |
Precautionary statements | P501-P240-P210-P233-P243-P241-P242-P280-P370+P378-P303+P361+P353-P403+P235 |
Safety Statements | 24/25 |
HS Code | 29029090 |
2,3-Dimethyl-2,3-diphenylbutane Chemical Properties,Uses,Production
Description
2,3-Dimethyl-2,3-diphenylbutane is one of the decomposition of Dicumylperoxide (DCP). Diallyl orthophthalate (DAOP) is a reactive plasticizer initiated by 2,3-dimethyl-2,3-diphenylbutane for improving polyphenylene oxide (PPO) processing.
Chemical Properties
white to light yellow flakes, crystalline powder
Uses
2,3-Dimethyl-2,3-diphenylbutane (DMDPB) is a new type of polymer material additive. It could used as a flame retardant synergist for polymer materials. This material can reduce the amount of flame retardant, reduce the effect of flame retardant on polymer performance, and endow polymer materials with flame retardant properties. It can also be used as a catalyst or initiator for polymer crosslinking, grafting, and copolymerization, and can be used for the modification of various polymer materials. For example, the thermolysis of 2,3-dimethyl-2,3-diphenylbutane at temperatures ranging from 220 to 310 °C is used to initiate the radical-mediated graft addition of vinyltriethoxysilane (VTEOS) to polyethylene[1].
Uses
2,3-Dimethyl-2,3-diphenylbutane, also known as Dicumene or 1,1 -(1,1,2,2-tetramethylethylene)dibenzene, is an environment friendly replacement for Antimony Tri-oxide (Sb2O3) and is commonly used as a flame retardant (FR) synergist for polypropylene and polystyrene, especially in expandable polystyrene (EPS).
Reactivity Profile
Adding appropriate modifiers dicumen can improve the performance of the polymer. In the case of heat or light, the product is easy to divide and form a certain free radical. The free radical is more stable due to the resonance of the benzene ring and the hyper-shock effect of methyl. In fact, the modification of Dicumene in the polymer is achieved through the free radical. It is found that when the temperature increases, the half-life of dicumen becomes shorter. The temperature of its decomposition is high. And at 230 degrees, the half-life will reach thirty minutes.
References
[1] Parent J, et al. Mechanism and selectivity of 2,3-dimethyl-2,3-diphenylbutane mediated addition of vinyltriethoxysilane to polyethylene. European Polymer Journal, 2006; 42: 971-980.
2,3-Dimethyl-2,3-diphenylbutane Preparation Products And Raw materials
Raw materials
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Metropolitan Eximchem Pvt Ltd (Metropolitan Group) | +91-2224081529 +91-2224081528 | Maharashtra, India | 70 | 58 | Inquiry |
Suryaprabha Pharmachem | +91-9850308282 +91-9850308282 | Maharashtra, India | 38 | 58 | Inquiry |
SI Group India Limited | +91-2356660401 +91-2356660401 | Maharashtra, India | 32 | 58 | Inquiry |
Metropolitan Eximchem Ltd. | 91 22 408 1529 | New Delhi, India | 148 | 38 | Inquiry |
Metropolitan Eximchem Pvt., Ltd. (Metropolitan Group) | 91-22-24081528 | Maharashtra, India | 70 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
Suryaprabha Pharmachem | 08048361347Ext 676 | Pune, India | 31 | 58 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
Taizhou Suze Chemical Materials Co.,Ltd. | +86-0523-86392777 +86-19825580222 | China | 23 | 58 | Inquiry |
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