2-Amino-4,8-naphthalenedisulfonic acid
![2-Amino-4,8-naphthalenedisulfonic acid Structure](CAS/GIF/131-27-1.gif)
- CAS No.
- 131-27-1
- Chemical Name:
- 2-Amino-4,8-naphthalenedisulfonic acid
- Synonyms
- C ACID;acidiv;kyselinac;AMINO C ACID;CASSELLA ACID;JACS-131-27-1;2-Amino-4,8-naphthal;4,8-disulfo-2-naphthalamine;4,8-Disulfo-2-naphthylamine;2-Ethylamino-4,8-dinaphthalene
- CBNumber:
- CB5200922
- Molecular Formula:
- C10H9NO6S2
- Molecular Weight:
- 303.31
- MOL File:
- 131-27-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/11/6 11:25:17
Boiling point | 205.8°C (rough estimate) |
---|---|
Density | 1.6329 (rough estimate) |
refractive index | 1.7330 (estimate) |
storage temp. | 2-8°C |
pka | -1.16±0.40(Predicted) |
CAS DataBase Reference | 131-27-1(CAS DataBase Reference) |
EPA Substance Registry System | 1,5-Naphthalenedisulfonic acid, 3-amino- (131-27-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302-H315-H319-H335 |
Precautionary statements | P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501 |
Risk Statements | 36/37/38 |
Safety Statements | 26-36/37/39 |
Toxicity | rat,LD50,oral,11400mg/kg (11400mg/kg),"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1058, 1986. |
2-Amino-4,8-naphthalenedisulfonic acid Chemical Properties,Uses,Production
Chemical Properties
2-Aminonaphthalene-4,8-disulfonic acid [131-27-1]. (3-aminonaphthalene-1,5-disulfonic acid), Cassella acid, C acid, C10H9NO6S2, Mr 303.32, and its salts are readily soluble in water. Reduction with sodium amalgam desulfonates 2-Aminonaphthalene-4,8-disulfonic acid to give 2-aminonaphthalene-8-sulfonic acid, whereas boiling with dilute sulfuric acid results in desulfonation and hydrolysis to give 2- hydroxynaphthalene-4-sulfonic acid. Alkali fusion (KOH, 215℃) produces 2-amino-4-hydroxynaphthalene-8-sulfonic acid.
Uses
Cassella acid is an important diazo component for yellow direct and reactive dyes.
Production Methods
The iron(II) salt of 3-nitronaphthalene-1,5-disulfonic acid (nitro-Armstrong acid) is reduced with iron in dilute acid. A claimed improvement involves isolation of nitro-Armstrong acid from the nitration products of naphthalene-1,5-disulfonic acid as the crystalline magnesium salt prior to catalytic reduction to C acid.
2-Amino-4,8-naphthalenedisulfonic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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