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potassium trifluoromethanesulfonate

potassium trifluoromethanesulfonate Structure
CAS No.
41804-89-1
Chemical Name:
potassium trifluoromethanesulfonate
Synonyms
POTASSIUM TRIFLATE;Potassium triflinate;POTASSIUM TRIFLUOROMETHANESULFINATE;potassium trifluoromethanesulphinate;POTASSIUM TRIFLUOROMETHANESULPHONATE;POTASSIUM TRIFLUOROMETHANESULFONIC ACID;TRIFLUOROMETHANESULFONIC ACID POTASSIUM SALT;TRIFLUOROMETHANESULFINIC ACID, POTASSIUM SALT;Trifluoromethane sulphinic acid potassium salt;Methanesulfinic acid,1,1,1-trifluoro-, potassium salt (1:1)
CBNumber:
CB5687198
Molecular Formula:
CF3O2S.K
Molecular Weight:
172.17
MOL File:
41804-89-1.mol
Modify Date:
2024/3/13 10:27:56

potassium trifluoromethanesulfonate Properties

Melting point 236-241 °C
Stability Stable. Incompatible with astrong oxidizing agents. Protect from moisture. Hygroscopic.

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P271-P261-P280
Hazard Codes  Xi
Risk Statements  36/37/38-38-37-36
Safety Statements  26-36
WGK Germany  3
3-10
HS Code  2930200090

potassium trifluoromethanesulfonate Chemical Properties,Uses,Production

Chemical Properties

white powder

Uses

Potassium Trifluoromethanesulfinate is used in preparation of trifluoromethanesulfonyl compounds.

Application

Potassium trifluoromethanesulfonate is used as a reagent in the synthesis of guanine-quadruplex hybrid materials. 

Synthesis

At first, an aqueous solution was prepared by dissolving 125 g of potassium sulfite in 290 g of water. Then, a metal pressure-proof reactor was charged with this aqueous solution. Then, the atmosphere of the reactor was removed to obtain a reduced pressure. After that, 30.7 g of trifluoromethanesulfonic fluoride was added to the reactor, stirring from 0° C. to room temperature for 12 hr. The resulting reaction liquid was neutralized with potassium carbonate, followed by water removal. Then, methanol was added to the remaining solid matter to extract the target product. The resulting methanol solution was concentrated to dryness, obtaining 32.6 g of potassium trifluoromethanesulfonate (94%).

potassium trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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POTASSIUM TRIFLATE POTASSIUM TRIFLUOROMETHANESULFONIC ACID POTASSIUM TRIFLUOROMETHANESULPHONATE TRIFLUOROMETHANESULFONIC ACID POTASSIUM SALT TRIFLUOROMETHANESULFINIC ACID, POTASSIUM SALT POTASSIUM TRIFLUOROMETHANESULFINATE potassium trifluoromethanesulphinate Trifluoromethane sulphinic acid potassium salt Potassium triflinate Methanesulfinic acid,1,1,1-trifluoro-, potassium salt (1:1) 41804-89-1 2927-26-4 CHF3O3SK CF3KO2S Catalysts for Organic Synthesis Metal Triflates Building Blocks Organic Building Blocks Sulfur Compounds Sulfonic/Sulfinic Acid Salts Homogeneous Catalysts