D(+)-10-Camphorsulfonyl chloride
- CAS No.
- 21286-54-4
- Chemical Name:
- D(+)-10-Camphorsulfonyl chloride
- Synonyms
- Camphor-10-suL;D(+)CAMPHOR SULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE;S-(+)-caMphorsulfonyl chloride;D(+)-1-CaMphorsulfonyl chloride;(+)-10-Camphorsulfonyl Chloride;(+)-CAMPHOR-10-SULFONYL CHLORIDE;D(+)-10-CAMPHORSULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE 96%;Dextro-10-camphorsulfonyl chloride
- CBNumber:
- CB5775185
- Molecular Formula:
- C10H15ClO3S
- Molecular Weight:
- 250.74
- MOL File:
- 21286-54-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
| Melting point | 67-68 °C |
|---|---|
| Boiling point | 349.4±15.0 °C(Predicted) |
| alpha | 33 º (c=1, CHCl3 22 ºC) |
| Density | 1.2078 (estimate) |
| refractive index | 32 ° (C=1, CHCl3) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| form | Crystalline Powder |
| color | Off-white to beige |
| optical activity | [α]22/D +33°, c = 1 in chloroform |
| Sensitive | Moisture Sensitive |
| BRN | 3205974 |
| InChIKey | BGABKEVTHIJBIW-UHFFFAOYSA-N |
| CAS DataBase Reference | 21286-54-4(CAS DataBase Reference) |
| NIST Chemistry Reference | (+)-Camphor-10-sulfonyl chloride(21286-54-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3261 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29147000 | |||||||||
| NFPA 704 |
|
D(+)-10-Camphorsulfonyl chloride price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 219576 | (1S)-(+)-10-Camphorsulfonyl chloride 97% | 21286-54-4 | 5G | ₹2424.8 | 2022-06-14 | Buy |
| Sigma-Aldrich | 219576 | (1S)-(+)-10-Camphorsulfonyl chloride 97% | 21286-54-4 | 25G | ₹6365.1 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 219576 | (1S)-(+)-10-Camphorsulfonyl chloride 97% | 21286-54-4 | 25G | ₹6365.1 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 219576 | (1S)-(+)-10-Camphorsulfonyl chloride 97% | 21286-54-4 | 100G | ₹16075.13 | 2022-06-14 | Buy |
| TCI Chemicals (India) | C0998 | (+)-10-Camphorsulfonyl Chloride min. 97.0 % | 21286-54-4 | 5G | ₹2100 | 2022-05-26 | Buy |
D(+)-10-Camphorsulfonyl chloride Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powde
Uses
As a useful synthetic intermediate, D(+)-10-Camphorsulfonyl chloride can be used for asymmetric hydroxylation
Purification Methods
If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]
D(+)-10-Camphorsulfonyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 219)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| ORGANO FINE CHEMICALS | +91-91-22-42128300 +91-2242128300 | Mumbai, India | 258 | 58 | Inquiry |
| Radison Labs Private Limited | +91-7337551966 +91-7337551966 | Hyderabad, India | 58 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6257 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6100 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
| Parmax Pharma Limited | 08048371844Ext 289 | Gujarat, India | 23 | 58 | Inquiry |
| Pharma Affiliates | 172-5066494 | Haryana, India | 6754 | 58 | Inquiry |
| Pharmaffiliates Analytics and Synthetics P. Ltd | +91-172-5066494 | Haryana, India | 6739 | 58 | Inquiry |
| Souvenier Chemicals | 08048372762Ext 645 | Mumbai, India | 396 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3887 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| ORGANO FINE CHEMICALS | 58 |
| Radison Labs Private Limited | 58 |
| CLEARSYNTH LABS LTD. | 58 |
| A.J Chemicals | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Parmax Pharma Limited | 58 |
| Pharma Affiliates | 58 |
| Pharmaffiliates Analytics and Synthetics P. Ltd | 58 |
| Souvenier Chemicals | 58 |
| Clearsynth Labs | 58 |
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D(+)CAMPHOR SULFONYL CHLORIDE
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(+)-10-CaMphorsulfonic Acid Chloride
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S-(+)-caMphorsulfonyl chloride
((1S,4R)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride
Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1S)-
Dextro-10-camphorsulfonyl chloride
D(+)-10-CaMphorsulfonyl chloride, 97% 5GR
(1S)-(+)-10-Camphorsulfonyl chloride 97%
[(1R,4S)-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonyl chloride
(7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl)methanesulfonyl chloride
(1S)-(+)-10-Camphorsulphonyl Chloride
Camphor-10-suL
Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1S,4R)-
(+)-10-Camphorsulfonyl Chloride
(1S)-(+)-10-Camphorsulfonyl chloride
21286-54-4
2186-54-4
C10H15ClO3S
UV-VIS
Chiral Resolving Reagents
Chiral Resolution Reagents
Optical Resolution
Asymmetric Synthesis
for Resolution of Alcohols & Thiols
Bicyclic Monoterpenes
Terpenes
for Resolution of Bases
chiral
Chiral Reagents
Bicyclic Monoterpenes
Biochemistry
for Resolution of Alcohols & Thiols
for Resolution of Bases
Optical Resolution
Synthetic Organic Chemistry
Terpenes
Intermediates & Fine Chemicals
Pharmaceuticals