2,6-Diethylaniline
![2,6-Diethylaniline Structure](CAS/GIF/579-66-8.gif)
- CAS No.
- 579-66-8
- Chemical Name:
- 2,6-Diethylaniline
- Synonyms
- DEA;2,6-diethyl-anilin;Benzenamine, 2,6-diethyl-;2.6-Diethylani;DEA) 2,6-Diethy;AKOS BBS-00003623;2,6-DIETHYLANALINE;2,6-DIETHYLANILINE;Aniline, 2,6-diethyl-;2,6- twoethyl aniline
- CBNumber:
- CB6259518
- Molecular Formula:
- C10H15N
- Molecular Weight:
- 149.23
- MOL File:
- 579-66-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/4/24 17:21:45
Melting point | 3-4 °C |
---|---|
Boiling point | 243 °C (lit.) |
Density | 0.906 g/mL at 25 °C (lit.) |
vapor pressure | 0.02 mm Hg ( 20 °C) |
refractive index |
n |
Flash point | 254 °F |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Liquid |
pka | 4.13±0.10(Predicted) |
color | Clear yellow to reddish-brown |
Water Solubility | 0.67g/L(26.7 ºC) |
Sensitive | Air Sensitive |
BRN | 1423626 |
Stability | Air Sensitive |
CAS DataBase Reference | 579-66-8(CAS DataBase Reference) |
NIST Chemistry Reference | Benzenamine, 2,6-diethyl-(579-66-8) |
EPA Substance Registry System | 2,6-Diethylaniline (579-66-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS07,GHS08 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H302-H315-H319-H341 | |||||||||
Precautionary statements | P201-P202-P264-P270-P280-P301+P312+P330-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P308+P313-P405-P501 | |||||||||
Hazard Codes | Xn | |||||||||
Risk Statements | 22 | |||||||||
Safety Statements | 23-24 | |||||||||
RIDADR | 2810 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | BX3500000 | |||||||||
F | 8-9-23 | |||||||||
HazardClass | 6.1(b) | |||||||||
PackingGroup | III | |||||||||
HS Code | 29214200 | |||||||||
NFPA 704 |
|
2,6-Diethylaniline price More Price(5)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 149381 | 2,6-Diethylaniline 98% | 579-66-8 | 100ML | ₹3669.68 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 149381 | 2,6-Diethylaniline 98% | 579-66-8 | 100ML | ₹3669.68 | 2022-06-14 | Buy |
TCI Chemicals (India) | D0476 | 2,6-Diethylaniline min. 98.0 % | 579-66-8 | 25ML | ₹1800 | 2022-05-26 | Buy |
TCI Chemicals (India) | D0476 | 2,6-Diethylaniline min. 98.0 % | 579-66-8 | 100ML | ₹2900 | 2022-05-26 | Buy |
ottokemi | D 9524 | 2,6-Diethylaniline 98% | 579-66-8 | 100mL | ₹9603 | 2022-05-26 | Buy |
2,6-Diethylaniline Chemical Properties,Uses,Production
Chemical Properties
Clear liquid
Production Methods
2,6-Diethylaniline is obtained in high yield when aniline is heated with ethylene at 200-300°C under high pressure in the presence of aluminum anilide (Northcott 1978).
General Description
The 2,6-diethylaniline complexes with iodine, as a sigma-acceptor, were studied spectrophotometrically in chloroform, dichloromethane and carbontetrachloride solutions. It is an intermediate for the production of alachlor, butachlor, metolachlor-herbicides, tiafentiurone-insecticide, carbodiimide and RIM-PUR.
Industrial uses
2,6-Diethylaniline is used in the synthesis of herbicides such as Nevirex G and butachlor (Vertesi and Miklos 1982; Lee et al 1982).
Metabolic pathway
Incubation of 2,6-diethylaniline (DEA) with NADPH- fortified rat liver microsomal enzymes produces 4- amino-3,5-diethylphenol (ADEP) as the major oxidation product. ADEP is shown to undergo further oxidation to 3,5-diethylbenzoquinone-4-imine (DEBQI), which is isolated as a minor metabolite during DEA oxidation.
Metabolism
Incubation of 2,6-diethylaniline with NADPH-fortified microsomes produced 4-amino-3,5-diethylphenol (ADEP) as the major oxidation product (Feng and Wratten 1987). ADEP underwent further oxidation to 3,5-diethyl-benzoquinone-4-imine which is isolated as a minor metabolite during 2,6-diethylaniline metabolism. 2,6-Diethylaniline is produced under aerobic soil conditions as a minor metabolite of the herbicide butachlor (Lee et al 1982). 2,6-Diethylaniline is degraded by the soil microorganism Chaetomium globosum to 2,6-diethylacetanilide and 2,6-diethyl-p-benzoquinone (Lee and Ryu 1982). 2,6-Diethylaniline was also very persistent towards biodegradation in pond water with and without sewage sludge inoculation (Lyons et al 1985).
2,6-Diethylaniline Preparation Products And Raw materials
Raw materials
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Supplier | Advantage |
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GLR Innovations | 58 |
Aarti Industries Limited (AIL) | 58 |
CNS CHEMICALS | 58 |
Shivam Pharma Chemicals | 58 |
Sai Quest Syn. Ltd | 58 |
AARTI INDUSTRIES LIMITED | 58 |
Siddh Interchem | 58 |
ChemOrbit International | 58 |
Cns Chemicals | 58 |
G C Int'L | 58 |
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