ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic copper >Copper(I) bromide-dimethyl sulfide
Copper(I) bromide-dimethyl sulfide
- CAS No.
- 54678-23-8
- Chemical Name:
- Copper(I) bromide-dimethyl sulfide
- Synonyms
- COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX;COPPER(I) BROMIDE DIMETHYL SULFIDE;Bromocopper;Copper(I) bromide methyL;Copper, bromothiobismethane-;COPPER(1)BROMIDE DMS COMPLEX;bromo[thiobis[methane]]copper;COPPER BROMIDE-DIMETHYL SULFIDE;BROMO(DIMETHYLSULFIDE)COPPER(I);COPPER(1) BROMIDE DMS COMPLEX 95%
- CBNumber:
- CB6332325
- Molecular Formula:
- C2H6BrCuS
- Molecular Weight:
- 205.58
- MOL File:
- 54678-23-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/10/16 16:12:12
| Melting point | 132 °C (dec.)(lit.) |
|---|---|
| form | Crystalline Powder and/or Chunks |
| color | Pale brown or pale green |
| Water Solubility | Soluble in water. Reacts with water and decomposes. |
| Sensitive | Moisture Sensitive/Air Sensitive |
| BRN | 4386581 |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 |
| InChIKey | PMHQVHHXPFUNSP-UHFFFAOYSA-M |
| CAS DataBase Reference | 54678-23-8(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P280g-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36-24/25 | |||||||||
| RIDADR | 1759 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-13-21 | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29309090 | |||||||||
| NFPA 704 |
|
Copper(I) bromide-dimethyl sulfide price More Price(2)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 230502 | Copper(I) bromide dimethyl sulfide complex 99% | 54678-23-8 | 10G | ₹9049.7 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 230502 | Copper(I) bromide dimethyl sulfide complex 99% | 54678-23-8 | 50G | ₹28534.7 | 2022-06-14 | Buy |
Copper(I) bromide-dimethyl sulfide Chemical Properties,Uses,Production
Chemical Properties
off-white to beige, grey or green crystalline
Uses
Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.
Purification Methods
Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].
Copper(I) bromide-dimethyl sulfide Preparation Products And Raw materials
Global( 171)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| DAVY CHEM LABS | +91-9603460845 +91-9493444489 | Hyderabad, India | 109 | 58 | Inquiry |
| VASISTA LIFE SCIENCES PRIVATE LIMITED | +91-04029554774 +91-9010855544 | Hyderabad, India | 153 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | China | 12460 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21675 | 55 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29900 | 58 | Inquiry |
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| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49391 | 58 | Inquiry |
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Catalysis and Inorganic Chemistry