DL-METHIONINE METHYLSULFONIUM CHLORIDE
- CAS No.
- 1115-84-0
- Chemical Name:
- DL-METHIONINE METHYLSULFONIUM CHLORIDE
- Synonyms
- MMSC;u-vit;yucron;C04078;cabagin;ardesyl;Vitas U;merastom;epadyn-u;cabaginu
- CBNumber:
- CB7249996
- Molecular Formula:
- C6H14ClNO2S
- Molecular Weight:
- 199.7
- MOL File:
- 1115-84-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/10/25 17:25:43
Melting point | 134 °C (decomp) |
---|---|
FEMA | 3445 | DL-(3-AMINO-3-CARBOXYPROPYL)DIMETHYLSULFONIUM CHLORIDE |
storage temp. | Hygroscopic, Refrigerator, Under inert atmosphere |
solubility | Water (Soluble), Methanol (Slightly) |
form | Solid |
color | White to Off-White |
Odor | at 100.00 %. malty tomato potato sulfury green |
Odor Type | malty |
JECFA Number | 1427 |
Stability | Hygroscopic |
LogP | 0.28 |
CAS DataBase Reference | 1115-84-0(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H319-H335-H315 |
Precautionary statements | P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362 |
Toxicity | LD50 oral in rat: > 6gm/kg |
DL-METHIONINE METHYLSULFONIUM CHLORIDE Chemical Properties,Uses,Production
Chemical Properties
Naturally occurs as the L-form in a variety of vegetables. Although used in food as a flavoring ingredient in fish products, it has also been used therapeutically in the treatment of peptic ulcers, colitis and gastritis.
Occurrence
Reported found in asparagus, cabbage, cabbage juice, celery, sweet corn, milk, potato, tea, green tea and tomato.
Uses
A derivative of L-Methionine (M260440). Naturally occurring sulfonium compound found in a large number of plants. Identification of antiulcer vitamin in cabbage leaves. Antiulcerative.
Application
Methiosulfonium chloride is used for its protective effect on the liver and gastrointestinal mucosa, whereas the iodide finds use for rheumatic disorders.
Trade name
Chloride: Ardesyl (Beytout, France), withdrawn from the market; Cabagin (Kowa, Japan). Iodide: Lobarthrose (Opodex, France), withdrawn from the market.
Purification Methods
Likely impurities are methionine, methionine sulfoxide and methionine sulfone. Crystallise Vitamin U from water by adding a large excess of EtOH. It is hygroscopic. It should be stored in a cool, dry place and protected from light. It has also been purified on a column of Dowex 50 H+ form, washed with H2O and eluted with 6N ammonia, lyophilised, the residue is dissolved in dilute HCl, lyophilised again and then it is obtained as colourless prisms by vapour diffusion of Et2O in a 1:1 (v/v) mixture of MeOH/EtOH in which the hydrochloride is dissolved [Del Re Acta Cryst B 33 3289 1977]. The iodide salt, m ~ 150o(dec), is obtained by dissolving it in 50% aqueous EtOH and adding ~3.5 volumes of absolute EtOH. The bromide salt has m 140o(dec) [Toennies & Kolb J Amer Chem Soc 67 849 1945].
DL-METHIONINE METHYLSULFONIUM CHLORIDE Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21669 | 55 | Inquiry |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49391 | 58 | Inquiry |
Shaanxi Dideu Medichem Co. Ltd | 18192627656 | China | 2674 | 58 | Inquiry |
TargetMol Chemicals Inc. | +1-781-999-5354 +1-00000000000 | United States | 19892 | 58 | Inquiry |
Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | China | 30253 | 58 | Inquiry |
LEAP CHEM CO., LTD. | +86-852-30606658 | China | 24738 | 58 | Inquiry |
Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | China | 49739 | 58 | Inquiry |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 | China | 49999 | 58 | Inquiry |
Aladdin Scientific | +1-+1(833)-552-7181 | United States | 57511 | 58 | Inquiry |
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