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Sodium acrylate

Sodium acrylate Structure
CAS No.
7446-81-3
Chemical Name:
Sodium acrylate
Synonyms
ACRYLIC ACID, SODIUM SALT;DK884;Sodium acryL;SODIUM ACRYLATE;Sodium propenoate;SodiuM acrylate 97%;Sodium 2-propenoate;Sodium acrylate(~white);Sodium acrylate(~yellow);SODIUM ACRYLATE ANHYDROUS
CBNumber:
CB9343487
Molecular Formula:
C3H3NaO2
Molecular Weight:
94.04
MOL File:
7446-81-3.mol
MSDS File:
SDS
Modify Date:
2024/2/18 17:04:03

Sodium acrylate Properties

Melting point >300 °C (lit.)
Density 1.528[at 20℃]
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Aqueous Acid (Slightly), Methanol (Slightly), Water (Slightly)
form Solid
color White to Off-White
Water Solubility 479g/L at 20℃
Hydrolytic Sensitivity 0: forms stable aqueous solutions
Stability May be unstable; may spontaneously polymerize. Incompatible with strong oxidizing agents.
LogP 0.46 at 25℃
CAS DataBase Reference 7446-81-3(CAS DataBase Reference)
EPA Substance Registry System Sodium acrylate (7446-81-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS09
Signal word  Warning
Hazard statements  H400
Precautionary statements  P273-P391-P501
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
TSCA  Yes
HS Code  29161100

Sodium acrylate price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 408220 Sodium acrylate 97% 7446-81-3 25G ₹7631.63 2022-06-14 Buy
Sigma-Aldrich(India) 408220 Sodium acrylate 97% 7446-81-3 25G ₹7631.63 2022-06-14 Buy
Sigma-Aldrich 408220 Sodium acrylate 97% 7446-81-3 100G ₹18434.98 2022-06-14 Buy
Sigma-Aldrich(India) 408220 Sodium acrylate 97% 7446-81-3 100G ₹18434.98 2022-06-14 Buy
Product number Packaging Price Buy
408220 25G ₹7631.63 Buy
408220 25G ₹7631.63 Buy
408220 100G ₹18434.98 Buy
408220 100G ₹18434.98 Buy

Sodium acrylate Chemical Properties,Uses,Production

Chemical Properties

Colorless or light yellow viscous liquid, non-toxic, weakly alkaline, insoluble in organic solvents such as ethanol, acetone, etc., easily soluble in water and aqueous sodium hydroxide, but in aqueous solutions such as calcium hydroxide, magnesium hydroxide, etc., with the increase in the number of alkaline-earth metal ions, the first to dissolve and then precipitate.

Uses

Sodium Acrylate (SA) is a sodium salt of acrylic acid with antibacterial properties. Sodium polyacrylate is a sodium salt of a polymer consisting of acrylic acid, methacrylic acid or one of their simple esters. SA can be used in tuning the grain size of iron oxide microparticles for potential applications in biological assaying and in chemical sensors. Additionally, it acts as a reducing and capping agent for gold nanoparticles, beneficial for various biological applications.

General Description

Sodium acrylate (SA) is a metal salt that can be prepared by an acid-base reaction between sodium hydroxide and acrylic acid. It can be used in the preparation of poly(sodium acrylate) using bulk, solution, emulsion, and suspension polymerization techniques. It results in the formation of a water soluble polymer that can be used in a variety of industries and personal care applications.

Synthesis

An aqueous solution of sodium acrylate is prepared from 216.2 g of acrylic acid (100%=3 mol), 262.8 g of NaOH (50%) and 497 g of water. 3.7 g of N-nitrosodiphenylamine and 3.7 g of 4-methoxyphenol are added to stabilize the solution. 12 g of the quaternary ammonium salt used in Example 1 are also added. 1,125 g (9 mol) of 1,4-dichlorobutene are run in at 90° C. 15.9 g of Na2CO3 are added after 1 hour and the mixture is left to react for a further 2 hours at 90° C. After phase separation, the organic layer is distilled under vacuum. 286.0 g (1.78 mol) of 4-chloro-2-butenyl acrylate (59.4% of the theoretical yield) are obtained. 641 g (5.13 mol) of dichlorobutene are recovered.

References

[1] SIMONE MANZINI . Palladium- and Nickel-Catalyzed Synthesis of Sodium Acrylate from Ethylene, CO2, and Phenolate Bases: Optimization of the Catalytic System for a Potential Process[J]. European Journal of Organic Chemistry, 2015, 2015 32: Pages 7122-7130. DOI:10.1002/ejoc.201501113.
[2] KALRA B, GROSS R A. HRP-mediated polymerizations of acrylamide and sodium acrylate[J]. Green Chemistry, 2002, 2: 174-178. DOI:10.1039/B106735B.
[3] https://www.ewg.org/skindeep/ingredients/705976-SODIUM_ACRYLATES_COPOLYMER/

Sodium acrylate Preparation Products And Raw materials

Global( 219)Suppliers
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A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
Triveni chemicals 08048762458 New Delhi, India 6093 58 Inquiry
Shaoxing Fangxiao Chemical Co., LTD +86-13456999252 +86-13868192239 China 50 58 Inquiry
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CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49391 58 Inquiry
2-propenoic acid sodium salt Sodium 2-propenoate SODIUM ACRYLATE ANHYDROUS Propenoic acid sodium salt Sodium propenoate SodiuM acrylate 97% SODIUM ACRYLATE 2-Propenoic acid, sodium salt (1:1) Sodium acryL Sodium acrylate ISO 9001:2015 REACH Factory Supply Sodium Acrylate / 2-Propenoic Acid Sodium Salt CAS 7446-81-3 Factory supply Sodium acrylate / 2-propenoic acid sodium salt ACRYLIC ACID, SODIUM SALT Sodium acrylate(~white) Sodium acrylate(~yellow) Acrylic acid, sodium salt,Sodium acrylate DK884 7446-81-3 C3H3O2Na C3H3O2Na12H2O H2CCHCO2Na Organic Building Blocks Building Blocks Carbonyl Compounds Carboxylic Acid Salts