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HEXAFLUOROACETYLACETONE

HEXAFLUOROACETYLACETONE Structure
CAS No.
1522-22-1
Chemical Name:
HEXAFLUOROACETYLACETONE
Synonyms
HFACAC;HFAC;1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE;1,1,1,5,5,5-HEXAFLUOROACETYLACETONE;1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONE;1,1,1,5,5,5-HEXAFLUOROACETYLACETONATE;uoroacetyL;HEXAFLUOROACETYLACETONE;Hexafluoroacetylacetone99%;Hexafluoroacetylacetone>
CBNumber:
CB8188414
Molecular Formula:
C5H2F6O2
Molecular Weight:
208.06
MOL File:
1522-22-1.mol
MSDS File:
SDS
Modify Date:
2024/2/19 12:30:55

HEXAFLUOROACETYLACETONE Properties

Boiling point 70-71 °C (lit.)
Density 1.47 g/mL at 25 °C (lit.)
refractive index n20/D 1.332(lit.)
Flash point 32 °C
storage temp. Inert atmosphere,Room Temperature
form Liquid
pka 4.30±0.10(Predicted)
color Clear colorless to slightly yellow
Specific Gravity 1.470
Water Solubility Not miscible in water.
Sensitive Hygroscopic
BRN 1790138
InChIKey QAMFBRUWYYMMGJ-UHFFFAOYSA-N
CAS DataBase Reference 1522-22-1(CAS DataBase Reference)
EPA Substance Registry System 2,4-Pentanedione, 1,1,1,5,5,5-hexafluoro- (1522-22-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H226-H302+H312+H332-H314
Precautionary statements  P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C,F,Xi
Risk Statements  10-20/21/22-34
Safety Statements  26-36/37/39-45
RIDADR  UN 2920 8/PG 2
WGK Germany  3
3
Hazard Note  Flammable/Corrosive
TSCA  T
HazardClass  8
PackingGroup  II
HS Code  29147000
NFPA 704
3
3 1

HEXAFLUOROACETYLACETONE price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 238309 Hexafluoroacetylacetone 98% 1522-22-1 5G ₹2825.33 2022-06-14 Buy
Sigma-Aldrich(India) 238309 Hexafluoroacetylacetone 98% 1522-22-1 25G ₹8887.33 2022-06-14 Buy
ALFA India ALF-L01693-22 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+% 1522-22-1 100g ₹35988 2022-05-26 Buy
ALFA India ALF-L01693-14 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+% 1522-22-1 25g ₹8217 2022-05-26 Buy
ALFA India ALF-L01693-06 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+% 1522-22-1 5g ₹4485 2022-05-26 Buy
Product number Packaging Price Buy
238309 5G ₹2825.33 Buy
238309 25G ₹8887.33 Buy
ALF-L01693-22 100g ₹35988 Buy
ALF-L01693-14 25g ₹8217 Buy
ALF-L01693-06 5g ₹4485 Buy

HEXAFLUOROACETYLACETONE Chemical Properties,Uses,Production

Chemical Properties

clear colorless to slightly yellow liquid

Uses

1,1,1,5,5,5-Hexafluoro-2,4-pentanedione acts as a chelating ligand. It is used as liquid crystal intermediate.

General Description

Hexafluoroacetylacetone forms metal-chelate complexes with Cu(II), Ni(II), Co(II), Nd(III), Rh(III), Fe(III) and Cr(III). Hexafluoroacetylacetone on hydration yields 1,1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraol.

Purification Methods

It forms a dihydrate which has no UV spectrum compared with max (CHCl3) 273nm ( 7,800) for the anhydrous ketone. The dihydrate decomposes at ~90o. The hydrate (10g) plus anhydous CaSO4 (Drierite, 30g) are heated and distilled, the distillate is treated with more CaSO4 and redistilled. When the distillate is treated with aqueous NaOH and heated, the dihydrate crystallises on cooling. The Cu complex has m 135o (after sublimation). [Gilman et al. J Am Chem Soc 78 2790 1956, Belford et al. J Inorg Nucl Chem 2 11 1956, Beilstein 1 IV 3681.]

Global( 286)Suppliers
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JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
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Spectrochem Private Limited 08048372608Ext 246 Maharashtra, India 1056 58 Inquiry
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Capot Chemical Co.,Ltd. 571-85586718 +8613336195806 China 29798 60 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 16209 58 Inquiry
1,1,1,5,5,5-hexafluoro-4-pentanedione 1,1,1,5,5,5-hexafluoro-pentan-2,4-dione 1,3-Bis(trifluoromethyl)propane-1,3-dione Hexafluoro-2,4-pentanedione 1,1,1,5,5,5-Hexafluoroacetylacetone, 99% 25GR 1,1,1,5,5,5-Hexafluoroacetylacetone, 99% 5GR 1,1,1,5,5,5-HEXAFLUOROACETYLACETONE FOR 1,1,1,5,5,5-Hexafluoropentane-2,4-dione, 1,1,1-Trifluoro-3-(trifluoroacetyl)acetone, 2,4-Dioxo-1,1,1,5,5,5-hexafluoropentane, HFAA 3H,3H-Hexafluoropentane-2,4-dione Hexafluoroacetylacetone 98% Hexafluoroacetylacetone,98% HFAA 1,1,1,5,5,5-Hexafluoropentane Hexafluoroacetylacetone99% Hexafluoroacetylacetone (HFAcAc) 1,1,1,5,5,5-Hexafluoroacetylacetone for synthesis HEXAFLUOROACETYLACETONE 1,1,1,5,5-HEXAFLUORO-2,4-PENTANDIONE 1,1,1,5,5,5-HEXAFLUORO-2,4-PENTADIONE 1,1,5,5,5-HEXAFLUORO-2,4-PENTADIONE 1,1,1,5,5,5-Hexafluoropentane-2,4-dione [HFAA] Hexafluoroacetylacetone,min.98%HFAA 2,4-Pentanedione, 1,1,1,5,5,5-hexafluoro- HEXAFLUOROACETYLACETONE HFAC HEXAFLUOROACETYLACETONE, ELECTRONIC GRADE 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+% 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 99+% 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 1,1,1,5,5,5-Hexafluoroacetylacetone 1,1,1,5,5,5-Hexafluoroacetylacetone 99% 1,1,1,5,5,5-Hexafluoroacetylacetone99% 1,1,1,5,5,5-Hexafluoroacetylacetone,96% Hexafluoroacetylacetone,1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 1,1,1,5,5,5-Hexafluoroacetylacetone 1,1,1,5,5,5-Hexafluoroacetylacetone, 98+% ##DISCONTINUED USE L01693## 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 97% Hexafluoroacetylacetone> uoroacetyL HFAC HFACAC 1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE 1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONE 1,1,1,5,5,5-HEXAFLUOROACETYLACETONATE 1,1,1,5,5,5-HEXAFLUOROACETYLACETONE 1522-22-1 C5H2F6O2 CF3COCH2COCF3 Organic Building Blocks Ketones Building Blocks C3 to C6 Carbonyl Compounds organofluorine compounds Halogen compounds