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2-Mercaptobenzimidazole

2-Mercaptobenzimidazole Structure
CAS No.
583-39-1
Chemical Name:
2-Mercaptobenzimidazole
Synonyms
1H-BENZO[D]IMIDAZOLE-2-THIOL;Mercaptobenzimidazole;Vulkanox;SuMilizer MB;Benzimidazole-2-thiol;2-BENZIMIDAZOLETHIOL;Benzimidazol-2-thiol;2-Mercapto benzanidazole;AOMB;asmmb
CBNumber:
CB8490256
Molecular Formula:
C7H6N2S
Molecular Weight:
150.2
MOL File:
583-39-1.mol
MSDS File:
SDS
Modify Date:
2024/8/21 22:41:43

2-Mercaptobenzimidazole Properties

Melting point 300-304 °C (lit.)
Boiling point 270.6±23.0 °C(Predicted)
Density 1.42
vapor pressure 0-0.001Pa at 25℃
refractive index 1.5500 (estimate)
Flash point >250°C
storage temp. 2-8°C
solubility 0.3g/l
form Powder
pka 10.24±0.10(Predicted)
color White to beige
Water Solubility <0.1 g/100 mL at 23.5 ºC
Merck 14,1082
BRN 119867
Stability Stable. Incompatible with strong oxidizing agents.
LogP 0.88-1.66 at 20-25℃
CAS DataBase Reference 583-39-1(CAS DataBase Reference)
NIST Chemistry Reference 2-Mercaptobenzimidazole(583-39-1)
EPA Substance Registry System 2-Mercaptobenzimidazole (583-39-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08
Signal word  Danger
Hazard statements  H301-H317-H373-H412
Precautionary statements  P260-P273-P280-P301+P310-P302+P352-P314
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38-22
Safety Statements  26-36-24/25
RIDADR  UN 2811 6.1/PG 3
WGK Germany  2
RTECS  DE1050000
Autoignition Temperature 480 °C
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29339910
Toxicity LD50 orally in Rabbit: 300 mg/kg
NFPA 704
1
3 0

2-Mercaptobenzimidazole price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) M3205 2-Mercaptobenzimidazole 98% 583-39-1 5G ₹2143.35 2022-06-14 Buy
Sigma-Aldrich(India) M3205 2-Mercaptobenzimidazole 98% 583-39-1 100G ₹2143.35 2022-06-14 Buy
Sigma-Aldrich(India) PHR3123 Rabeprazole Related Compound C pharmaceutical secondary standard, certified reference material 583-39-1 50MG ₹49253.75 2022-06-14 Buy
Sigma-Aldrich(India) M3205 2-Mercaptobenzimidazole 98% 583-39-1 500G ₹4665.58 2022-06-14 Buy
Sigma-Aldrich(India) 51810 2-Mercaptobenzimidazole analytical standard 583-39-1 50MG ₹5260.95 2022-06-14 Buy
Product number Packaging Price Buy
M3205 5G ₹2143.35 Buy
M3205 100G ₹2143.35 Buy
PHR3123 50MG ₹49253.75 Buy
M3205 500G ₹4665.58 Buy
51810 50MG ₹5260.95 Buy

2-Mercaptobenzimidazole Chemical Properties,Uses,Production

Chemical Properties

yellow or white crystals

Uses

2-Mercaptobenzimidazole is used as an antidegradant. It is utilized for protecting rubber from oxidation. It is also employed as an intermediate in the preparation of rabeprazole. Further, it finds application in anti-leprosy drugs in medicine. In addition to this, it is used as a copper plating brightener.

General Description

White to yellow crystals or cream colored powder. Slight odor.

Air & Water Reactions

Dust explosion: 0.140 oz/ft3. Insoluble in water. 2-Mercaptobenzimidazole is moisture sensitive. .

Reactivity Profile

An organosulfide and an amine. Organosulfides are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Fire Hazard

Flash point data for 2-Mercaptobenzimidazole are not available; however, 2-Mercaptobenzimidazole is probably combustible.

Safety Profile

Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion. Skin and eye irritant. When heated to decomposition it emits toxic fumes of SO, and NO,. See also MERCAPTANS.

Purification Methods

Crystallise it from aqueous EtOH, AcOH or aqueous ammonia. It complexes with many metals. [Brown J Chem Soc 1976 1958, Beilstein 24 II 65, 24 III/IV 287.]

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1,3-dihydro-2h-benzimidazole-2-thion 1,3-Dihydro-2H-benzimidazole-2-thione 1,3-Dihydro-benzoimidazole-2-thione 1H-Benzimidazol-2-yl hydrosulfide 2,3-Dihydro-1H-benzimidazole-2-thiol 2-Benzimidazolethione 2-Benzimidazolinethione 2-benzimidazolinthion 2H-Benzimidazole-2-thione, 1,3-dihydro- 2H-Benzimidazole-2-thione,1,3-dihydro- 2-Mercaptobenzoimidazole usafek-6540 usafxf-21 Vulkanox MB Vulkanox MBI 2-Mercaptobenzimidazole≥ 99.5% 2-Benzimidazolethiol 1H-Benzo[d]imidazole-2-thiol 1,3-dihydro-2H-Benzimidazole-2-thione Antioxidant MB 2-benzimidazolinthion 2-Mercaptobenzimidaz 2-MercaptobenziMidazole, 98% 100GR 2-MercaptobenziMidazole, 98% 250GR 2-MercaptobenziMidazole, 98% 5GR 2-Mercapto-1H-benziMidazole o-Phenyleneth Sandant MB Lansoprazole related substance E 2-Mercapto beziMidazole 1H-BenziMidazol-2-thiol Lansoprazole EP IMpurity E 1H-benzo[d]iMidazole-2(3H)-thione 2-Mercapto-1H-benzimidazole, 2-Sulphanyl-1H-benzimidazole Rabeprazole Related CoMpound C 2-MercaptobenziMidazole, 98.0%(T) 2 - Mercapto benzene and iMidazole 2-Mercaptobenzimidazole, MBI 2-merkaptobenzimidazol 2-Thiobenzimidazole 2-Thiol benzimidazole Anitiegene MB Antiegene MB antiegenemb Antigen MB Antigene MB Antioxidant mb AntioxidantMB AOMB Asm MB asmmb Mercaptobenzoimidazole Merkaptobenzimidazol NCI-C56268 nci-c60980 Nocrac MB o-Phenylenethiourea Permanax 21 USAF ek-6540 USAF xf-21 Mercaptophenylimidazole Zinc salt of 2-Mercaptobenzimidazole (MBZ antioxidant)