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ChemicalBook > Product Catalogue >API >Synthetic Anti-infective Drugs >Sulfonamides and synergist >(S)-(-)-2-Methyl-2-propanesulfinamide

(S)-(-)-2-Methyl-2-propanesulfinamide

(S)-(-)-2-Methyl-2-propanesulfinamide Structure
  • ₹2000 - ₹61269.5
  • Product name: (S)-(-)-2-Methyl-2-propanesulfinamide
  • CAS: 343338-28-3
  • MF: C4H11NOS
  • MW: 121.2
  • EINECS:640-158-3
  • MDL Number:MFCD05861480
  • Synonyms:2-METHYL-2-PROPANE-SULFINAMIDE(S-ISOMER);(S)-tert-Butylsulfinamide, (>98.0% ee), 97+%;(S)-(-)-2-METHYL-2-PROPANESULPHINAMIDE;(S)-(-)-2-METHYL-PROPANE-2-SULFINIC ACID AMIDE;(S)-(-)-TERT-BUTYLSULFINAMIDE;(S)-(-)-TERT-BUTYL SULPHINAMIDE;(S)-(-)-T-BUTYLMETHYLSULFINAMIDE;(S)-(-)-2-Methylpropane-2-sulphinamide 98%
Price5 Properties Safety Information Description
5 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberB2908
  • Product description(S)-(-)-tert-Butylsulfinamide min. 98.0 %
  • Packaging1G
  • Price₹2000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2908
  • Product description(S)-(-)-tert-Butylsulfinamide min. 98.0 %
  • Packaging5G
  • Price₹5500
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number513210
  • Product description(S)-(−)-2-Methyl-2-propanesulfinamide 97%
  • Packaging1G
  • Price₹6408.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number513210
  • Product description(S)-(−)-2-Methyl-2-propanesulfinamide 97%
  • Packaging5G
  • Price₹19647.38
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number513210
  • Product description(S)-(−)-2-Methyl-2-propanesulfinamide 97%
  • Packaging25G
  • Price₹61269.5
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B2908 (S)-(-)-tert-Butylsulfinamide min. 98.0 % 1G ₹2000 2022-05-26 Buy
TCI Chemicals (India) B2908 (S)-(-)-tert-Butylsulfinamide min. 98.0 % 5G ₹5500 2022-05-26 Buy
Sigma-Aldrich(India) 513210 (S)-(−)-2-Methyl-2-propanesulfinamide 97% 1G ₹6408.4 2022-06-14 Buy
Sigma-Aldrich(India) 513210 (S)-(−)-2-Methyl-2-propanesulfinamide 97% 5G ₹19647.38 2022-06-14 Buy
Sigma-Aldrich(India) 513210 (S)-(−)-2-Methyl-2-propanesulfinamide 97% 25G ₹61269.5 2022-06-14 Buy

Properties

Melting point :97-101 °C(lit.)
alpha :-4.5 º (c=1, CHCl3)
Boiling point :220.0±23.0 °C(Predicted)
Density :1.124
storage temp. :2-8°C
solubility :Chloroform (Slightly), Methanol (Slightly)
pka :10.11±0.50(Predicted)
form :Crystalline Powder
color :White
optical activity :[α]20/D 4.5°, c = 1 in chloroform
Stability :store cold
InChI :InChI=1/C4H11NOS/c1-4(2,3)7(5)6/h5H2,1-3H3/t7-/s3
InChIKey :CESUXLKAADQNTB-SSDOTTSWSA-N
SMILES :CC(C)([S@@](N)=O)C |&1:3,r|
CAS DataBase Reference :343338-28-3(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

(S)-(-)-2-Methyl-2-propanesulfinamide is used in Suzuki reaction. It is also employed as a reagent for synthesizing chiral amines. It acts as a chiral auxiliary used in an asymmetric synthesis of trifluoroethylamines by conversion of trifluoroacetaldehyde to a chiral imine. It is also involved in the transformation of P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins. Further, it serves as a reagent for the preparation of chemicals and pharmaceutical intermediates.

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