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Acid Orange 7

Acid Orange 7 Structure
CAS No.
633-96-5
Chemical Name:
Acid Orange 7
Synonyms
Ao 7;15510;ORANGE1;CI 4600;OrangeⅡ;ORANGE I;CI 14600;orangeya;orangeyz;ORANGE 4
CBNumber:
CB0144029
Molecular Formula:
C16H13N2NaO4S
Molecular Weight:
352.34
MOL File:
633-96-5.mol
MSDS File:
SDS
Modify Date:
2024/5/21 14:26:55

Acid Orange 7 Properties

Melting point 164°C
Density 1.525[at 20℃]
vapor pressure 0Pa at 25℃
storage temp. Amber Vial, -20°C Freezer, Under inert atmosphere
solubility Very soluble in water; very slightly soluble in ethanol
pka 8.26, 11.4(at 25℃)
Colour Index 15510
form Crystalline Powder
color Green to blue
PH Range Amber (7.4) to orange (8.6);Orange (10.2) to red (11.8)
Odor Odorless
Water Solubility 116 g/L (30 ºC)
λmax 483nm
Merck 14,6858
BRN 3898201
Stability Light Sensitive
Biological Applications Cosmetics; wound dressing materials
Major Application Organic light emitting diodes (OLEDs), nanoparticles, inks, wood preservatives, textiles, hair dyes, cosmetics, wound dressing materials, biofuel cells
LogP -0.95 at 20℃
CAS DataBase Reference 633-96-5(CAS DataBase Reference)
EPA Substance Registry System C.I. Acid Orange 7, monosodium salt (633-96-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
RTECS  DB7084000
HS Code  32041200
NFPA 704
0
2 0

Acid Orange 7 price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 75370 Orange II sodium salt for microscopy (Hist.), indicator (pH 11.0-13.0) 633-96-5 25G ₹2863.8 2022-06-14 Buy
Sigma-Aldrich(India) 75370 Orange II sodium salt for microscopy (Hist.), indicator (pH 11.0-13.0) 633-96-5 100G ₹6193.8 2022-06-14 Buy
Sigma-Aldrich(India) 195235 Orange II sodium salt (Certified by the Biological Stain Commission), Dye content ≥85?% 633-96-5 25G ₹5217 2022-06-14 Buy
Sigma-Aldrich(India) 69143 Orange II sodium salt analytical standard 633-96-5 25MG ₹13453.2 2022-06-14 Buy
Sigma-Aldrich(India) 195235 Orange II sodium salt (Certified by the Biological Stain Commission), Dye content ≥85?% 633-96-5 100G ₹12143.4 2022-06-14 Buy
Product number Packaging Price Buy
75370 25G ₹2863.8 Buy
75370 100G ₹6193.8 Buy
195235 25G ₹5217 Buy
69143 25MG ₹13453.2 Buy
195235 100G ₹12143.4 Buy

Acid Orange 7 Chemical Properties,Uses,Production

Chemical Properties

Orange-red powder

Definition

ChEBI: Acid orange 7 is a member of naphthalenes. Orange allergenic extract is used in allergenic testing.

Preparation

Acid Orange 7, commonly known as acidic orange II. 4-Aminobenzenesulfonic acid diazo, and Naphthalen-2-ol coupling. It is produced by azo coupling of β-naphthol and diazonium derivative of sulfanilic acid.

Purification Methods

Purification is as for Orange I. Its solubility in H2O is 40g/L at 25o. [Müller et al. Helv Chim Acta 35 2579 1952.] Also purify it by extracting it with a small volume of cold water, then crystallising it by dissolving in boiling water, cooling to ca 80o, adding two volumes of EtOH and cooling. When cold, the precipitate is filtered off, washed with a little EtOH and dried in air. It can be salted out from aqueous solution with sodium acetate, then repeatedly extracted with EtOH. Meggy and Sims [J Chem Soc 2940 1956], after crystallising the sodium salt twice from water, dissolved it in cold water (11mL/g) and added conc HCl to precipitate the acid dye which was separated by centrifugation, redissolved and again precipitated with acid. After washing the precipitate three times with 0.5M acid, it was dried over NaOH, recrystallised twice from absolute EtOH, washed with a little Et2O, dried over NaOH and stored over conc H2SO4 in the dark. It can then be converted to the pure salt with the calculated amount of NaOH or Na2CO3. [Beilstein 16 IV 408.]

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Golden Orange Ⅱ Orange II sod Orange II, Pure ORANGE1 ORANGE I NAPHTHOL ORANGE TROPAEOLIN 000 NO 1 TROPAEOLIN OOO-1 TROPAEOLIN OOO NO 1 Orange II Certifed≥ 90% (dye content) 15510 KEYACID ORANGE 7 11550orange 2-naphtholorangeii METANIL ORANGE CI NO 14600 CI 4600 CI 14600 LABOTEST-BB LT00847535 4-((2-hydroxy-1-naphthalenyl)azo)-benzenesulfonicacimonosodiumsalt 4-[(2-hydroxy-1-naphthalenyl)azo]-benzenesulfonicacimonosodiumsalt abcolacidorangeiicrude acidleatherorangeextra acidleatherorangeextrag acidleatherorangeextraprw acidorange acilanorangeii airedaleorangeii amacidorangey atulacidorangeii benzenesulfonicacid,-[(2-hydroxy-1-naphthalenyl)azo]-,monosodiumsalt Benzenesulfonicacid,4-[(2-hydroxy-1-naphthalenyl)azo]-,monosodiumsalt betanaphtholorange beta-naphtholorange beta-naphthylorange brasilanorangea bucacidorangea C.1.AcidOrange7(15510) C.I.Acidorange7 c.i.acidorange7,monosodiumsalt calcocidorangey certiqualorangeii colacidorange curolorange diacidorangeii fenazoorange hidacidorangeii hispacidorangeaf javaorangeii kitonorangeii kromonlakeorangetoner lakeorangea lakeorangeiiys leatherorangeextra lurazolorangee lutetiaorange3jr naphthalenelakeorangeg naphthaleneorangeg