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TRIFORINE

TRIFORINE Structure
CAS No.
26644-46-2
Chemical Name:
TRIFORINE
Synonyms
w524;cw524;SAPROL;cela50;ca70203;Denarin;TRIFORIN;FUNGINEX;cme74770;riforine
CBNumber:
CB0169257
Molecular Formula:
C10H14Cl6N4O2
Molecular Weight:
434.96
MOL File:
26644-46-2.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

TRIFORINE Properties

Melting point 155℃ (decomposition)
Boiling point 561.5±50.0 °C(Predicted)
Density 1.5269 (rough estimate)
vapor pressure 8 x 10-2 Pa (25 °C)
refractive index 1.6000 (estimate)
storage temp. 0-6°C
solubility DMSO (Slightly)
pka 10.6 (base)
Water Solubility 9 mg l-1 (20 °C)
color White to Off-White
Merck 13,9762
BRN 626358
CAS DataBase Reference 26644-46-2
EPA Substance Registry System Triforine (26644-46-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H332
Precautionary statements  P261-P271-P304+P340+P312
Hazard Codes  Xn
Risk Statements  52/53-20
Safety Statements  61
RIDADR  UN3077 (solid); UN3082 (liquid)
WGK Germany  2
RTECS  TK9200000
Toxicity LD50 oral in rat: 6gm/kg

TRIFORINE price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 45701 Triforin PESTANAL?, analytical standard 26644-46-2 250MG ₹6722.33 2022-06-14 Buy
Product number Packaging Price Buy
45701 250MG ₹6722.33 Buy

TRIFORINE Chemical Properties,Uses,Production

Description

Triforine is a clear light yellow colour with an ethanol (alcohol) odour and a highly flammable liquid. It is used as a fungicide for the control of black spot, powdery mildew, and diseases of rust in roses, fruits, vegetables, cereals, and ornamentals. Application of triforine acts both as a preventative and a curative fungicide and is known to destroying diseases already in the plant and also preventing disease infestations. It is also used as a post-harvest control of brown rot on peaches, nectarines, apricots, cherries, and plums.

Uses

Triforine is used to control powdery mildews on cereals, fruits, vines, hops, ornamentals, cucurbits and some vegetables, rusts on cereals, fruit, ornamentals and beans. It also controls Munilia spp. on stone fruit, Ascochyta blight on chrysanthemums, black spot on roses, scab on apples and fairy rings on turf. Triforine also suppresses tetranychid mite activity.

Definition

ChEBI: A member of the class of N-alkylpiperazines in which the two amino groups of piperazine are replaced by 1-formamido-2,2,2-trichloroethyl groups. A fungicide active against a range of diseases including powdery mildew, scab and rust.

General Description

Colorless crystals. Non corrosive. Used as a fungicide.

Reactivity Profile

A piperazine, trichloromethylformamide derivative. Decomposed in strong acid to trichloroacetaldehyde and piperazine salts, and in strongly alkaline media to chloroform and piperazine.

Hazard

Low toxicity by ingestion, inhalation, and skin contact. Human systemic effects.

Agricultural Uses

Fungicide: Triforine is a systemic fungicide with protectant, eridicant, and curative activity. It is locally systemic, is quickly absorbed by the plant and should be applied on or before an infection occurs. Triforine is used for control of black spot, brown rot, scab, petal blight, rust and other diseases on fruits such as apples, peaches, plumbs, nectarines, apricots, and strawberry; in hops, vegetables, cereals, and ornamentals such as roses and chrysanthemums. Triforine breaks down rapidly in the environment. Not approved for use in EU countries . Registered for use in the U.S.

Trade name

CELA50®; CW524®; DENARIN® FUNGINEX®; SAPROL®; TRIFORIN®; W524®

Contact allergens

This pesticide is widely used in flower growing. Cross- reactions are expected to dichlorvos.

Safety Profile

Low toxicity by ingestion, inhalation, and skin contact. Human systemic effects: change in taste function. When heated to decomposition emits toxic fumes of NOx and Cl-.

Metabolic pathway

Thermal reaction of triforine with several alcohols in a closed glass tube gives N-(1-alkoxy-2,2,2- trichloroethyl) formamides.

TRIFORINE Preparation Products And Raw materials

Raw materials

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Preparation Products

Global( 72)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
TargetMol Chemicals Inc. +1-781-999-5354 +1-00000000000 United States 19892 58 Inquiry
LEAP CHEM CO., LTD. +86-852-30606658 China 24738 58 Inquiry
Hebei Guanlang Biotechnology Co., Ltd. +86-19930503259 +86-19930503259 China 18446 58 Inquiry
SUZHOU SENFEIDA CHEMICAL CO.,LTD +86-0512-83500002 +8615195660023 China 10814 58 Inquiry
Shanghai Acmec Biochemical Technology Co., Ltd. +undefined18621343501 China 33350 58 Inquiry
Hebei Fengmu Trading Co., Ltd. +8613393234347 China 2989 58 Inquiry
LGC Standards +44 (0)20 8943 8480 United Kingdom 6495 0 Inquiry
United States Biological 800.520.3011 or 781.639.5092 United States 6256 80 Inquiry
SAPROL SAPROL(R) N,N'-[PIPERAZINE-1,4-DIYLBIS(TRICHLOROMETHYL)METHYLENE]-DIFORMAMIDE PIPERAZIN-1,4-DIYL-BIS-[1-(2,2,2-TRICHLOROETHYL)FORMAMIDE] TRIFORIN TRIFORINE 1,4-bis(1-formamido-2,2,2-trichloroethyl)-piperazin 1,4-bis(1-formamido-2,2,2-trichloroethyl)piperazine biformychlorazin biformylchlorazin ca70203 w524 CELA W524 DENARIN(R) FUNDINEX(R) FUNGINEX Denarin(Cela Merck) TRIFORIN PESTANAL, 250 MG TRIFORINE, 100M, NEAT Formamide, N,N-1,4-piperazinediylbis(2,2,2-trichloroethylidene)bis- triforine (bsi,iso,ansi,jmaf) 1,4-di(2,2,2-trichloro-1-formamidoethyl) piperazine N,N'-[Piperazine-1,4-diylbis(2,2,2-trichloroethane-1,1-diyl)]bisformamide 1,4-BIS(2,2,2-TRICHLORO-1-FORMAMIDOETHYL)-PIPERAZINE Denarin cela50 cme74770 cw524 n,n’-(1,4-piperazinediylbis(2,2,2-trichloroethylidene))bis-formamid n,n’-(piperazinediylbis(2,2,2-trichloroethylidene))bis(formamide) N,N’-[1,4-Piperazinediylbis(2,2,2-trichloro-ethylidene)]-bisformamide n,n’-bis(1-formamido-2,2,2-trichloroethyl)piperazine Triforine 100mg [26644-46-2] 1,4-Bis(2,2,2-trichoro-1-formamidoethyl)piperazine Asepta Funginex NSC 263493 Triforine 0.25 Triforine Solution, 1000ppm Triforine @100 μg/mL in MeOH Triforine Standard (mixture of isomers) riforine Benzoylprop-ethyl Impurity 15 26644-46-2 26644462 C10H14Cl6N4O2 Amide structureAlphabetic Fungicides Pesticides TP - TZ Alpha sort Amide structurePesticides&Metabolites Q-ZAlphabetic