Chinese english Japanese Germany Korea
ChemicalBook > Product Catalog >Organic Chemistry >Heterocyclic Compounds >1,1'-Thiocarbonyldiimidazole

1,1'-Thiocarbonyldiimidazole

1,1'-Thiocarbonyldiimidazole Structure
CAS No.
6160-65-2
Chemical Name:
1,1'-Thiocarbonyldiimidazole
Synonyms
TCDI;Di(1H-imidazol-1-yl)methanethione;1,1-THIOCARBONYLDIIMIDAZOLE;Thiocarbonyl diimidazole;bis(1H-imidazol-2-yl)methanethione;DiiMidaz;diimidazoL;1,1'-THIOCARBONYL;1,1'-Thiocarbonyldii;Thiocarbonylbisimidazole
CBNumber:
CB0280138
Molecular Formula:
C7H6N4S
Molecular Weight:
178.21
MOL File:
6160-65-2.mol
MSDS File:
SDS
Modify Date:
2024/5/29 17:03:55
Request For Quotation

1,1'-Thiocarbonyldiimidazole Properties

Melting point 98-102 °C(lit.)
Boiling point 342°C (rough estimate)
Density 1.3046 (rough estimate)
refractive index 1.5500 (estimate)
storage temp. 2-8°C
solubility Soluble in terahydrofuran, toluene and dichloromethane.
pka 1.96±0.10(Predicted)
form Powder
color Bright yellow
Water Solubility decomposes
Sensitive Moisture Sensitive
BRN 609349
Stability Stable, but air and moisture sensitive. Incompatible with strong oxidizing agents, strong acids.
InChIKey RAFNCPHFRHZCPS-UHFFFAOYSA-N
CAS DataBase Reference 6160-65-2(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  22-34
Safety Statements  22-24/25-45-36/37/39-26
WGK Germany  3
F  9-21
Hazard Note  Irritant/Keep Cold/Moisture Sensitive
HS Code  29332900
NFPA 704
1
2 1

1,1'-Thiocarbonyldiimidazole price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 88545 1,1′-Thiocarbonyldiimidazole ≥95.0% (S) 6160-65-2 1G ₹2175.83 2022-06-14 Buy
Sigma-Aldrich(India) 88545 1,1′-Thiocarbonyldiimidazole ≥95.0% (S) 6160-65-2 5G ₹6776.45 2022-06-14 Buy
Sigma-Aldrich(India) 88545 1,1′-Thiocarbonyldiimidazole ≥95.0% (S) 6160-65-2 25G ₹18922.1 2022-06-14 Buy
Sigma-Aldrich(India) 156051 1,1′-Thiocarbonyldiimidazole technical grade, 90% 6160-65-2 5G ₹4611.45 2022-06-14 Buy
Sigma-Aldrich(India) 156051 1,1′-Thiocarbonyldiimidazole technical grade, 90% 6160-65-2 10G ₹7913.08 2022-06-14 Buy
Product number Packaging Price Buy
88545 1G ₹2175.83 Buy
88545 5G ₹6776.45 Buy
88545 25G ₹18922.1 Buy
156051 5G ₹4611.45 Buy
156051 10G ₹7913.08 Buy

1,1'-Thiocarbonyldiimidazole Chemical Properties,Uses,Production

Chemical Properties

yellow powder

Uses

1,1'-Thiocarbonyldiimidazole is used as a reagent for the deoxygenation of alcohols with tributyltin hydride and diols with lithium aluminum hydride. It is also used to deoxygenate carboxylic monosaccharide analogues. Further, it is a useful reagent involved in biochemical synthesis. In addition to this, it is used to prepare 1-[bis-(4-methoxy-phenyl)-methyl]-1H-imidazole by reacting with 4,4'-dimethoxy-benzhydrol.

Application

1,1′-Thiocarbonyldiimidazole (TCDI) is generally used as a reagent to carry out the deoxygenation of vicinal diols by forming cyclic thionocarbonate in Corey-Winter alkene synthesis.
It is used as a reagent in the enantioselective total synthesis of (+)-hapalindole Q, 12-epi-fischerindole U and welwitindolinone A.
It is also used in the preparation of trithiocarbonates, xanthates, and dithiocarbamates as chain transfer agents for the reversible addition fragmentation chain transfer and macromolecular design (RAFT/ MADIX) polymerization.

Purification Methods

It forms yellow crystals on recrystallisation from tetrahydrofuran or by sublimation at 10-3torr (bath temperature 70-80o). It is hydrolysed by H2O and should be stored dry. [Staab & Walther Justus Liebigs Ann Chem 657 98 1962; Pullukat et al. Tetrahedron Lett 1953 1967, Hanessian et al. Can J Chem 65 1859 1987, Rajanbabu et al. J Am Chem Soc 111 1759 1989.] Thiochrome {2,7-dimethyl-5H -thiachromine-8-ethanol; 3,8-dimethyl-2-hydroxyethyl-5H -

1,1'-Thiocarbonyldiimidazole Preparation Products And Raw materials

Raw materials

Preparation Products

1-Methyl-2-imidazolidinethione 3-PHENYLPROPYL ISOTHIOCYANATE (S)-4-PHENYL-1,3-OXAZOLIDINE-2-THIONE bis(benzylsulfanyl)methanethione 4-Isothiocyanatobenzene-1-sulfonamide
4,4-DIMETHYL-2-OXAZOLIDINONE Di-o-tolythiourea 3-CHLOROPHENYL ISOTHIOCYANATE 4-(TRIFLUOROMETHYL)PHENYL ISOTHIOCYANATE NAPHTHALENE, 1-CYCLOPROPYL-4-ISOTHIOCYANATO-
3-CHLORO-4-FLUOROPHENYL ISOTHIOCYANATE 1,2,4-Triazolo[4,3-b]pyridazine-6-carboxylic acid, 2,3-dihydro-3-thioxo-, methyl ester N-(1H-INDAZOL-6-YL)THIOUREA 1H-Imidazole-1-carbothioic acid, O-propyl ester Benzene, 1-fluoro-4-(2-isothiocyanatoethyl)-
Dimorpholino thioketone
chevron_left

1of4

chevron_right

1,1'-Thiocarbonyldiimidazole Suppliers

Global( 481)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
GLR Innovations +91 9891111994 New Delhi, India 4542 58 Inquiry
SURVIVAL TECHNOLOGIES LIMITED +91 8108285261 Gujarat, India 294 58 Inquiry
Navone Specialties (OPC) Pvt Ltd +91-9323789882 +91-9323789882 Maharashtra, India 144 58 Inquiry
Spectrochem Private Limited 08048372608Ext 246 Maharashtra, India 1056 58 Inquiry
Survival Technologies Private Limited 08879997937 Mumbai, India 153 58 Inquiry
Moksha Lifesciences 91-8660245672 Karnataka, India 51 58 Inquiry
VASIN BIO LIFE SCIENCES PVT LTD 9491644688 Hyderabad, India 2096 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
Supplier Advantage
GLR Innovations 58
SURVIVAL TECHNOLOGIES LIMITED 58
Navone Specialties (OPC) Pvt Ltd 58
Spectrochem Private Limited 58
Survival Technologies Private Limited 58
Moksha Lifesciences 58
VASIN BIO LIFE SCIENCES PVT LTD 58
TCI Chemicals (India) Pvt. Ltd. 58
CLEARSYNTH LABS LTD. 58
A.J Chemicals 58

Related articles

1,1'-Thiocarbonyldiimidazole Spectrum

1,1'-Thiocarbonyldiimidazole(6160-65-2)MS1,1'-Thiocarbonyldiimidazole(6160-65-2)1HNMR1,1'-Thiocarbonyldiimidazole(6160-65-2)13CNMR1,1'-Thiocarbonyldiimidazole(6160-65-2)IR11,1'-Thiocarbonyldiimidazole(6160-65-2)IR21,1'-Thiocarbonyldiimidazole(6160-65-2)Raman

6160-65-2(1,1'-Thiocarbonyldiimidazole)Related Search:

1,1'-Carbonyldiimidazole Imidazole Fenbendazole Albendazole N,O-Bis(trimethylsilyl)acetamide
N,N'-Dibenzyl ethylenediamine diacetate N,N'-Diisopropylcarbodiimide N,N-Dimethyl-p-toluidine N,N'-Disuccinimidyl carbonate 1,1,2-TRICHLORO-2,3,3-TRIFLUOROCYCLOBUTANE
Nickel carbonyl powder Sodium thiosulfate pentahydrate Adapalene Methimazole 1-Methylimidazole
1,1'-Thiocarbonyldiimidazole
chevron_left

1of4

chevron_right
N,N'-THIOCARBONYLDIIMIDAZOLE 1,1'-thiocarbonylbis(imidazole) 1,1'-THIOCARBONYLDIIMIDAZOLE 1-(1H-IMidazol-1-ylcarbothioyl)-1H-iMidazole DiiMidaz 1,1'-CARBONOTHIOYLBIS-1H-IMIDAZOLE N, N - sulfur carbonyl iMidazole 1,1'-Thiocarbonyldiimidazole >=95.0% (S) 1,1'-Thiocarbonyldiimidazole technical grade, 90% 1,1'-Thiocarbonyldiimidazole, technical, 90% 1,1'-THIOCARBONYLDIIMIDAZOLE, TECH., 90% N,N'-THIOCARBONYLDIIMIDAZOLE(TCDI) 1,1,-ThiocarbonyldiimidazoleTech90% 1,1'-Thiocarbonyldiimidazole,95% 1H-Imidazole, 1,1-carbonothioylbis- N,N’-Thiocarboryldiimidazole 1,1''-THIOCARBONYLDIIMIDAZOLE (TCDI) Bis(1H-imidazole-1-yl) thioketone Bis(1-imidazolyl) thioketone Di(imidazol-1-yl)methanethione Thiocarbonylbisimidazole 1,1'-Thiocarbonyldiimidazole,90%,tech. 1.1'-Thiocarbonyldiimidazole 100mg [6160-65-2] 1,1'-Thiocarbonyldiimidazole, tech 90% 1,1'-Thiocarbonyldii N'-ThiocarbonyldiiMidazole(TCDI) 1,1'-Thiocarbonyldi(1H-imidazole) 90% 1,1'-THIOCARBONYL diimidazoL 1,1'-Thiocarbonyldiimidazole > Methanethione, di-1H-imidazol-1-yl- 1,1'-Thicarbonyldiimidazole TIANFU-CHEM 6160-65-2 1,1'-Thiocarbonyldiimidazole TCDI 1,1-THIOCARBONYLDIIMIDAZOLE Thiocarbonyl diimidazole Di(1H-imidazol-1-yl)methanethione bis(1H-imidazol-2-yl)methanethione THEOCARBONYL DIIMIDAZOLE 1,1'-Thiocarbonyldiimidazole 6160-65-2 228-183-4 Building Blocks Carbonyldiimidazole Derivatives Synthetic Reagents Imidazoles Coupling Heterocyclic Building Blocks Carbonyldiimidazole Derivatives Coupling Synthetic Reagents Carbonyldiimidazole DerivativesBuilding Blocks Heterocyclic Building Blocks Imidazoles