Acid Mordant Orange 14

Acid Mordant Orange 14 Structure
CAS No.
568-93-4
Chemical Name:
Acid Mordant Orange 14
Synonyms
C.I.58015;3-Nitroalizarine;Mordant orange 14;Alizarine Orange A;C.I.Mordant Orange 14;Acid mordant Orange 14;C.I.Mordant Orange 14:C.I.58015;1,2-Dihydroxy-3-nitroanthraquinone;1,2-dihydroxy-3-nitroanthracene-9,10-dione;9,10-Anthracenedione, 1,2-dihydroxy-3-nitro-
CBNumber:
CB1921627
Molecular Formula:
C14H7NO6
Molecular Weight:
285.21
MOL File:
568-93-4.mol
Modify Date:
2023/4/23 13:52:06

Acid Mordant Orange 14 Properties

Melting point 244°C (rough estimate)
Boiling point 427.65°C (rough estimate)
Density 1.3989 (rough estimate)
refractive index 1.4700 (estimate)
storage temp. -20°C Freezer, Under inert atmosphere
solubility Dichloromethane (Slightly), DMSO (Slightly)
form Solid
pka 3.95±0.20(Predicted)
color Dark Yellow to Very Dark Yellow
NIST Chemistry Reference 3-Nitroalizarine(568-93-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338

Acid Mordant Orange 14 Chemical Properties,Uses,Production

Uses

Dyes cloth mordanted with Al orange, with Fe red to violet. As indicator in satd alcohol solution. pH 2.0-4.0, color change from golden orange to flat yellow (in water). pH 5.0-6.5 from yellow to purplish red.

Preparation

(a) in the presence of boric acid 1,2-Dihydroxyanthracene-9,10-dione?in sulfuric acid in the nitration; (b) 1,2-Dihydroxyanthracene-9,10-dione?in glacial acetic acid, toluene, petroleum ether or the nitration of nitrobenzene.

Purification Methods

Crystallise the dye from AcOH (m 244-245o). It has max at 494nm (H2SO4) and forms Cu salts. [Beilstein 8 H 447, 8 II 491, 8 III 3774, 8 IV 2359.]

Acid Mordant Orange 14 Preparation Products And Raw materials

Raw materials

Preparation Products

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Alizarine Orange A C.I.58015 C.I.Mordant Orange 14 Acid mordant Orange 14 1,2-dihydroxy-3-nitroanthracene-9,10-dione Mordant orange 14 1,2-Dihydroxy-3-nitroanthraquinone 3-Nitroalizarine 9,10-Anthracenedione, 1,2-dihydroxy-3-nitro- C.I.Mordant Orange 14:C.I.58015 568-93-4