Cupric acetate monohydrate
- CAS No.
- 6046-93-1
- Chemical Name:
- Cupric acetate monohydrate
- Synonyms
- COPPER ACETATE;COPPER(II) ACETATE MONOHYDRATE;CuAc;COPPER ACETATE MONOHYDRATE;205-553-3;COPPER(II) ACETATE HYDRATE;Copper acetate hydrate;Copperdiacetatemonohydrate;VERDIGRIS;Cupricacetatr
- CBNumber:
- CB5299326
- Molecular Formula:
- C4H8CuO5
- Molecular Weight:
- 199.65
- MOL File:
- 6046-93-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/14 20:44:35
| Melting point | 115 °C |
|---|---|
| Boiling point | 240 °C |
| Density | 1.88 |
| vapor density | 6.9 (vs air) |
| storage temp. | Store at +5°C to +30°C. |
| solubility | 72g/l |
| form | Solid |
| color | Dark Green |
| Specific Gravity | 1.882 |
| Odor | Slight acetic acid odor |
| PH Range | 5.2 - 5.5 |
| PH | 5.2-5.5 (20g/l, H2O, 20℃) |
| Water Solubility | 72 g/L (20 ºC) |
| Hydrolytic Sensitivity | 0: forms stable aqueous solutions |
| Merck | 14,2624 |
| BRN | 3730548 |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 |
| Stability | Stable. Incompatible with oxidizing agents. |
| InChIKey | NWFNSTOSIVLCJA-UHFFFAOYSA-L |
| LogP | -0.285 (est) |
| CAS DataBase Reference | 6046-93-1(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H314-H410 | |||||||||
| Precautionary statements | P260-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,N,Xi,C | |||||||||
| Risk Statements | 22-36/37/38-50/53-34 | |||||||||
| Safety Statements | 36/37/39-60-61-36-26-45 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | AG3500000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29152900 | |||||||||
| Toxicity | LD50 orally in Rabbit: 501 mg/kg | |||||||||
| NFPA 704 |
|
Cupric acetate monohydrate price More Price(23)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 61148 | Copper(II) acetate monohydrate puriss. p.a., ≥99.0% (RT) | 6046-93-1 | 100G | ₹4362.48 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 217557 | Copper(II) acetate monohydrate ACS reagent, ≥98% | 6046-93-1 | 100G | ₹5152.7 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 217557 | Copper(II) acetate monohydrate ACS reagent, ≥98% | 6046-93-1 | 500G | ₹9266.2 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 1.02711 | Copper(II) acetate monohydrate for analysis EMSURE? ACS | 6046-93-1 | 250G | ₹11360.01 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 1.02711 | Copper(II) acetate monohydrate for analysis EMSURE? ACS | 6046-93-1 | 25KG | ₹567750 | 2022-06-14 | Buy |
Cupric acetate monohydrate Chemical Properties,Uses,Production
Chemical Properties
Dark green small crystal with odour of acetic acid
Uses
Cupric acetate monohydrate can be used in preparation of Fehling's reagent for sugars
Preparation
Copper(II) acetate monohydrate can easily be produced by the reaction of acetic acid solutions with copper(II) carbonate or copper(II) hydroxide or by the reaction of copper(II) oxide with hot acetic acid. Large-scale commercial production uses copper metal in the presence of air and refluxing acetic acid.
Copper(II) acetate monohydrate is used as a catalyst in the polymerization of organic materials and as a mordant in the dying of textiles. It is also used as a ceramic pigment and as a fungicide.
General Description
Copper (II) acetate monohydrate is soluble in water and slightly soluble in methanol, diethylether and acetone. It can be synthesized by reacting acetic acid with copper (II) carbonate or copper(II) hydroxide or copper (II) oxide. Large scale commercial production is undertaken by placing copper metal in the presence of air and refluxing acetic acid. As a transition metal acetate, it can be used to form oxide nanoparticles by sonochemical methods.
Potential Exposure
Cupric acetate is used as a fungicide, as a catalyst for organic reactions; in textile dyeing and as a pigment for ceramics.
Shipping
UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
Purification Methods
Recystallise it twice from warm dilute acetic acid solutions (5mL/g) by cooling. [Beilstein 2 IV 111.]
Incompatibilities
Forms explosive materials with acetylene gas, ammonia, caustic solutions; sodium hypobromite; notromethane. Keep away from chemically active metals; strong acids; nitrates. Decomposes above 240C forming acetic acid fumes
Waste Disposal
Copper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill.
Cupric acetate monohydrate Preparation Products And Raw materials
Raw materials
Preparation Products
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| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
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| Alpha Chemicals | 08048618650 | Vadodara, India | 32 | 58 | Inquiry |
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| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| Vardhaman P Golechha | 58 |
| JSK Chemicals | 58 |
| Kronox Lab Sciences Pvt Ltd | 58 |
| Satyam Pharma Chem Pvt Ltd | 58 |
| Parshva Chemicals | 58 |
| Kemona Impex | 58 |
| Alpha Chemicals | 58 |
| Parshva Chemicals | 58 |
| CLEARSYNTH LABS LTD. | 58 |
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