Tetraethylene glycol dimethyl ether
- CAS No.
- 143-24-8
- Chemical Name:
- Tetraethylene glycol dimethyl ether
- Synonyms
- TETRAGLYME;DIMETHYLTETRAGLYCOL;DIMETHOXYTETRAGLYCOL;BIS[2-(2-METHOXYETHOXY)ETHYL] ETHER;glyme5;Glyme-5;etraglyme;Me-PEG4-Me;Ansol E-181;e181(ether)
- CBNumber:
- CB5350092
- Molecular Formula:
- C10H22O5
- Molecular Weight:
- 222.28
- MOL File:
- 143-24-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/8/13 9:40:06
| Melting point | -30 °C (lit.) |
|---|---|
| Boiling point | 275-276 °C (lit.) |
| Density | 1.009 g/mL at 25 °C (lit.) |
| vapor density | 7.7 (vs air) |
| vapor pressure | <0.01 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 285 °F |
| storage temp. | Store below +30°C. |
| solubility | Chloroform (Sparingly), Methanol (Slightly) |
| form | Liquid |
| Specific Gravity | 1.01 |
| color | Clear |
| explosive limit | 0.8%(V) |
| Water Solubility | Soluble |
| Merck | 14,9208 |
| BRN | 1760005 |
| InChIKey | ZUHZGEOKBKGPSW-UHFFFAOYSA-N |
| LogP | -0.84 at 23℃ |
| CAS DataBase Reference | 143-24-8(CAS DataBase Reference) |
| NIST Chemistry Reference | CH3O[CH2CH2O]4CH3(143-24-8) |
| EPA Substance Registry System | Tetraglyme (143-24-8) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H360FD | |||||||||
| Precautionary statements | P201-P308+P313 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 19-43-62-61 | |||||||||
| Safety Statements | 36-24-45-36/37-53-26 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | SB0400000 | |||||||||
| Autoignition Temperature | 510 °F | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 2909 19 90 | |||||||||
| Toxicity | LD50 orally in rats: 5.14 g/kg (Smyth) | |||||||||
| NFPA 704 |
|
Tetraethylene glycol dimethyl ether price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 8.20959 | Tetraethylene glycol dimethyl ether for synthesis | 143-24-8 | 250ML | ₹3390 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.20959 | Tetraethylene glycol dimethyl ether for synthesis | 143-24-8 | 1L | ₹13680 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 172405 | Tetraethylene glycol dimethyl ether ≥99% | 143-24-8 | 250G | ₹3031 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 172405 | Tetraethylene glycol dimethyl ether ≥99% | 143-24-8 | 1KG | ₹8465.15 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 02659 | Tetraethylene glycol dimethyl ether analytical standard | 143-24-8 | 5ML | ₹10143.03 | 2022-06-14 | Buy |
Tetraethylene glycol dimethyl ether Chemical Properties,Uses,Production
Chemical Properties
clear liquid
Uses
Tetraethylene glycol dimethyl ether is used as a solvent.
General Description
Tetraethylene glycol dimethyl ether or tetraglyme is an organic aprotic colourless solvent with film forming ability.
Safety Profile
Mildly toxic by ingestion. Experimental reproductive effects. An eye irritant. Many glycol ethers are suspected of having dangerous human reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS
Purification Methods
Stand the ether over CaH2, LiAlH4 or sodium, and distil it when required. [Beilstein 1 IV 2404.]
Advantages
Tetraethylene glycol dimethyl ether (TEGDME) could be used as a bifunctional solvent which serves as both the casting solvent and active component by controlling the residual amount of TEGDME from excessive to appropriate. This method could avoid the negative impact of the residual organic solvent (such as acetonitrile) in polymer electrolytes prepared by the solution-casting method on battery performance. The residual TEGDME serves as a plasticizer in HSE that is beneficial for improving the plasticity and decreasing the crystallinity of PEO so that it can increase the mobility of lithium ions and flexibility of solid electrolytes. TEGDME can also improve the plasticity and interfacial contact[1].
Environmental considerations
Tetraethylene glycol dimethyl ether is a polar, non-aromatic compound. It is nonionic but water-soluble due to its polarity. However, it has been detected in municipal effluents, runoff from fields irrigated with treated wastewater, and wastewaters of two different waste oil refineries Citation[2].
References
[1] Hao-Ran Wang, Ya-Nan Yang and Tao Zhang*. “Tape-Casting Method of Hybrid Solid Electrolytes with a Residual Active Solvent of Tetraethylene Glycol Dimethyl Ether.” ACS Applied Energy Materials 6 3 (2023): 2031–2038.
[2] Holger Gulyas. “Combining activated carbon adsorption with heterogeneous photocatalytic oxidation: lack of synergy for biologically treated greywater and tetraethylene glycol dimethyl ether.” Environmental Technology 34 9–12 (2013): 1393–403.
Tetraethylene glycol dimethyl ether Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| BTC pharm India | +918790379245 | AndhraPradesh, India | 1269 | 58 | Inquiry |
| HiMedia Laboratories | 91-22-61471919 | Maharashtra, India | 1843 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
| Arrobiochem | 08048372617Ext 911 | Mumbai, India | 34 | 58 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Grr Fine Chem/Grr Exports | 91-79-40031771 | Gujarat, India | 405 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| BTC pharm India | 58 |
| HiMedia Laboratories | 58 |
| Clearsynth Labs | 58 |
| Central Drug House(P) Ltd. | 58 |
| Arrobiochem | 58 |
| Otto Chemie Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Grr Fine Chem/Grr Exports | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| CLEARSYNTH LABS LTD. | 58 |
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