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Bromoacetic acid

Bromoacetic acid Structure
CAS No.
79-08-3
Chemical Name:
Bromoacetic acid
Synonyms
2-BROMOACETIC ACID;MONOBROMOACETIC ACID;bromoacetic;Bromoethanoic acid;2-Bromoethanoic acid;alpha-Bromoacetic acid;Bromoacetic acid in ethyleneglycol, ca. 10% BrCH2CO2H, 35% glycol balance ester;tontu;To ntu;CH2BrCOOH
CBNumber:
CB7486096
Molecular Formula:
C2H3BrO2
Molecular Weight:
138.95
MOL File:
79-08-3.mol
MSDS File:
SDS
Modify Date:
2023/10/13 18:16:27

Bromoacetic acid Properties

Melting point 46-49 °C
Boiling point 208 °C(lit.)
Density 1
vapor pressure 1 mm Hg @ 550C
refractive index 1.4804 (estimate)
Flash point >110°C
storage temp. Store below +30°C.
solubility chloroform: soluble10%, clear, colorless
pka 2.69(at 25℃)
form Crystalline Mass or Crystalline Powder, Flakes, Crystals and/or Chunks
color White to yellow
Water Solubility miscible
Sensitive Light Sensitive & Hygroscopic
Merck 14,1400
BRN 506167
LogP -2.3 at 22℃
CAS DataBase Reference 79-08-3(CAS DataBase Reference)
NIST Chemistry Reference Acetic acid, bromo-(79-08-3)
EPA Substance Registry System Bromoacetic acid (79-08-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS06,GHS09
Signal word  Danger
Hazard statements  H301+H311+H331-H314-H317-H400
Precautionary statements  P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T,C,N,Xi,F
Risk Statements  23/24/25-35-50-40-36/37/38-43-38
Safety Statements  26-36/37/39-45-61-36-16
RIDADR  UN 3425 8/PG 2
WGK Germany  2
RTECS  AF5950000
3-19-23
Hazard Note  Toxic/Corrosive
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29159000
NFPA 704
1
3 1

Bromoacetic acid price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) B56307 Bromoacetic acid reagent grade, 97% 79-08-3 100G ₹1905.2 2022-06-14 Buy
Sigma-Aldrich(India) B56307 Bromoacetic acid reagent grade, 97% 79-08-3 500G ₹3399.05 2022-06-14 Buy
Sigma-Aldrich(India) B56307 Bromoacetic acid reagent grade, 97% 79-08-3 2KG ₹24291.3 2022-06-14 Buy
Sigma-Aldrich(India) 901610 Bromoacetic acid solution 1.0?M in DMF 79-08-3 25ML ₹7178.85 2022-06-14 Buy
Sigma-Aldrich(India) 901610 Bromoacetic acid solution 1.0?M in DMF 79-08-3 100ML ₹13797.23 2022-06-14 Buy
Product number Packaging Price Buy
B56307 100G ₹1905.2 Buy
B56307 500G ₹3399.05 Buy
B56307 2KG ₹24291.3 Buy
901610 25ML ₹7178.85 Buy
901610 100ML ₹13797.23 Buy

Bromoacetic acid Chemical Properties,Uses,Production

Chemical Properties

WHITE TO LIGHT YELLOW CRYSTALLINE MASS

Uses

Bromoacetic acid is used in organic synthesis and as an alkylating agent. It is also used as a biochemical for proteomics research. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, dyes and agrochemicals.

General Description

Aqueous solution.

Air & Water Reactions

Water soluble.

Hazard

Strong irritant to skin and tissue.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

Poison by ingestion, intraperitoneal, and intravenous routes. Irritating and corrosive to skin and mucous membranes. Mutation data reported. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.

Purification Methods

Crystallise bromoacetic acid from pet ether (b 40-60o). A diethyl ether solution of it is passed through an alumina column, and the ether is evaporated at room temperature under vacuum. It is best obtained by distillation from a Claisen (flask immersed in an oil bath) fitted with an insulated Vigreux column (p 11) and the fraction b 108-110o/30mm is collected. It is light and moisture sensitive. [Natelson & Gottfried Org Synth Coll Vol III 381 1955, Beilstein 2 IV 526.] LACHRYMATORY and is a skin IRRITANT.

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RARECHEM AL BO 0099 Bromaceticacid bromoacetateion bromo-aceticaci bromoaceticacid,solution bromoethanoicacid CH2BrCOOH Kyselina bromoctova Bromessigsure BROMOACETIC ACID REAGENT GRADE 97% BROMOACETIC ACID, REAGENTPLUS, >=99% BROMOACETIC ACID, 100MG, NEAT BROMOACETIC ACID, STANDARD FOR GC BromoaceticAcidForSynthesis Bromoacetic acid, 98+% Bromoaceticacid,98%min BromoaceticAcide Bromoacrtic 2-Bromoacetic acid 97% Aceticacid,bromo- Acide bromacetique acidebromacetique alpha-Bromoethanoic acid alpha-bromoethanoicacid kyselinabromoctova Monobromessigsaeure To ntu tontu BROMOACETIC ACID BROMOACETIC ACID IN ETHYLENEGLYCOL 1,4-Dihydroxy-1-methylbutane 1,4-Dihydroxypentane 2,5-Pentanediol 4-Hydroxy-1-pentanol Bromoacetic acid,99% 2-broMo ethanoyl broMide BroMoacetic acid, 99% 1KG YA10697000MB BroMoacetic BroMoacetic acid reagent grade, 97% BroMoacetic acid ReagentPlus(R), >=99.0% BroMoacetic acid, Standard for GC,>=99.5%(GC) BroMide acetic acid Bromoacetic acid in ethylene glycol, approx. 10% BrCH2CO2H, 35% glycol balance ester Bromoacetic acid, 98.5% Bromoacetic Acid > BromoaceticAcidSolution,1000mg/L,1ml Acetic acid, 2-bromo- MONOBROMOACETIC ACID bromoacetic Bromoethanoic acid Bromoacetic acid in ethyleneglycol, ca. 10% BrCH2CO2H, 35% glycol balance ester alpha-Bromoacetic acid 2-BROMOACETIC ACID 2-Bromoethanoic acid Bromoacetic Acid Standard Solution (3R,4S)-N-(isoquinolin-5-yl)-4-phenylpyrrolidine-3-carboxamide Bromoacedic acid 79-08-3