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Methyl eugenol

Methyl eugenol Structure
CAS No.
93-15-2
Chemical Name:
Methyl eugenol
Synonyms
4-ALLYL-1,2-DIMETHOXYBENZENE;EUGENOL METHYL ETHER;1,2-DIMETHOXY-4-(2-PROPENYL)BENZENE;EUGENYL METHYL ETHER;jiaji;O-Methyleugenol;Benzene, 1,2-dimethoxy-4-(2-propenyl)-;3-METHYLEUGENOL;4-Allylveratrol;4-ALLYLVERATROLE
CBNumber:
CB8198972
Molecular Formula:
C11H14O2
Molecular Weight:
178.23
MOL File:
93-15-2.mol
MSDS File:
SDS
Modify Date:
2024/7/24 13:33:21
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Methyl eugenol Properties

Melting point -4 °C (lit.)
Boiling point 254-255 °C (lit.)
Density 1.036 g/mL at 25 °C (lit.)
vapor pressure 0.463-1.983Pa at 25℃
refractive index n20/D 1.534(lit.)
Flash point >230 °F
storage temp. 2-8°C
solubility 0.5g/l
form Oil
color Colourless to Pale Yellow
Odor at 1.00 % in dipropylene glycol. sweet fresh warm spicy clove carnation cinnamon
Odor Type spicy
Water Solubility insoluble
Merck 14,6073
BRN 1910871
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey ZYEMGPIYFIJGTP-UHFFFAOYSA-N
LogP 2.74-3.03
CAS DataBase Reference 93-15-2(CAS DataBase Reference)
IARC 2B (Vol. 101) 2013
NIST Chemistry Reference Benzene, 1,2-dimethoxy-4-(2-propenyl)-(93-15-2)
EPA Substance Registry System Methyleugenol (93-15-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS08,GHS09
Signal word  Warning
Hazard statements  H302-H341-H351-H411
Precautionary statements  P201-P273-P301+P312+P330-P308+P313
Hazard Codes  Xn
Risk Statements  22-36/37/38-40
Safety Statements  26-36/37/39
WGK Germany  1
RTECS  CY2450000
HS Code  29093090
Toxicity LD50 orally in rats: 1560 mg/kg (Jenner)
NFPA 704
1
0 0

Methyl eugenol price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) W247502 Methyl eugenol ≥98%, FCC 93-15-2 1SAMPLE-K ₹5141.88 2022-06-14 Buy
Sigma-Aldrich(India) W247502 Methyl eugenol ≥98%, FCC 93-15-2 1KG ₹8281.13 2022-06-14 Buy
Sigma-Aldrich(India) W247502 Methyl eugenol ≥98%, FCC 93-15-2 10KG ₹70189.3 2022-06-14 Buy
Sigma-Aldrich(India) W247502 Methyl eugenol ≥98%, FCC 93-15-2 25KG ₹172853.6 2022-06-14 Buy
Sigma-Aldrich(India) 284424 4-Allyl-1,2-dimethoxybenzene 99% 93-15-2 5G ₹1602.1 2022-06-14 Buy
Product number Packaging Price Buy
W247502 1SAMPLE-K ₹5141.88 Buy
W247502 1KG ₹8281.13 Buy
W247502 10KG ₹70189.3 Buy
W247502 25KG ₹172853.6 Buy
284424 5G ₹1602.1 Buy

Methyl eugenol Chemical Properties,Uses,Production

Chemical Properties

colourless to light yellow liquid

Occurrence

Reported in the essential oils of Myrtaceae and Luraceae; it was identifed originally in the essential oil from roots of Asarum europaeum L and Asarum canadense L Subsequently, it was identifed as the main constituent of the oil from wood of Dacrydium franklinii Hook (97 5%), in Melaleuca bracteata F v M (leaves, 90 to 95%), in Cinnamomum oliveri Bail (leaves, 90 to 95%), and as a minor constituent in the oils of betel, citronella, Japanese calamus, pimenta, hyacinth, rose, basil, bay, cajeput and others Reported found in heated blackberry, pepper, lovage seed, chervil, lemon balm, alpinia species, clove buds, nutmeg, pepper, mace, tarragon, Ocimum sanctum, laurel, myrtle leaf and berry, rosemary, pimento berry and mastic gum leaf oil

Uses

Methyl eugenol may be used as an analytical reference standard for the quantification of the analyte in the following:????????

  • Essential oil of Pimenta pseudocaryophyllus using high-performance liquid chromatography (HPLC). The purity of the extracted compound is then determined by gas chromatography coupled to flame ionization detector (GC/FID).???????
  • Stem bark of Cinnamomum zeylanicum Blume using reversed-phase high-performance liquid chromatography (RP-HPLC) with UV-visible detection.???????
  • Rosa hybrida using gas-chromatography coupled to mass spectrometry (GC-MS) technique.

Preparation

Usually prepared by methylation of eugenol.

General Description

Clear colorless to pale yellow liquid with a spicy earthy odor. Bitter burning taste.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Methyl eugenol is incompatible with strong oxidizers . May react exothermically with reducing agents to release hydrogen gas.

Hazard

Possible carcinogen.

Fire Hazard

Methyl eugenol is combustible.

Safety Profile

Confirmed carcinogen. Poison by intravenous route. Moderately toxic by ingestion and intraperitoneal routes. A skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. Some other alkenylbenzenes have carcinogenic activity. See also EUGENOL, ALLYL COMPOUNDS, and ETHERS

Potential Exposure

Methyl eugenol is a naturally occurring substance found in the essential oils of several plant species. Methyleugenol is used as a flavoring agent in jellies, baked goods, nonalcoholic beverages, chewing gum, candy, pudding, relish, and ice cream. Methyleugenol has been used as an anesthetic in rodents. It also is used as an insect attractant in combination with insecticides.

Carcinogenicity

Methyleugenol is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.

Solubility in organics

Soluble in alcohol and oils

Shipping

UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Purification Methods

Recrystallise the ether from hexane at low temperature and redistil it (preferably in vacuo). [Hillmer & Schorning Z Phys Chem [A] 167 407 1934, Briner & Fliszár Helv Chim Acta 42 2063 1959, Beilstein 6 H 963, 6 IV 6337.]

Incompatibilities

Methyleugenol is Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with reducing agents may cause the release of hydrogen gas

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Methyl eugenol Preparation Products And Raw materials

Raw materials

Eugenol 4-Bromoveratrole ALLYL TOLUENE-4-SULFONATE 3,4-DIMETHOXYPHENYLMAGNESIUM BROMIDE 4-chloro-1,2-dimethoxy-benzene
3,4-DIMETHOXYPHENYLBORONIC ACID, PINACOL ESTER ALLYL METHYL ETHER Allyl methyl sulfide Allyltrimethylsilane 1,2-Dimethoxybenzene
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Preparation Products

BENZENE,1,2,4-TRIMETHOXY-5-(2-PROPENYL)- FW 358.2 4-trans-propenylveratrole ISOEUGENYLMETHYLETHER 3,4-Dimethoxyphenylacetone
2-CHLORO-3-(3,4-DIMETHOXYPHENYL)-1-PROPENE 23EPOXYEUGENOLMETHYLETHER
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Methyl eugenol Suppliers

Global( 532)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
Ramsun Bio Organics +91-9742930655 +91-9742475780 Karnataka, India 42 58 Inquiry
Yasho Industries Ltd +91-2262510100 +91-8291955977 Mumbai, India 70 58 Inquiry
Spectrochem Private Limited 08048372608Ext 246 Maharashtra, India 1056 58 Inquiry
Natural Remedies Pvt Ltd +91 (80) 4020-9999 New Delhi, India 110 50 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
Pharmaffiliates Analytics and Synthetics P. Ltd +91-172-5066494 Haryana, India 6773 58 Inquiry
Supplier Advantage
JSK Chemicals 58
Ramsun Bio Organics 58
Yasho Industries Ltd 58
Spectrochem Private Limited 58
Natural Remedies Pvt Ltd 50
TCI Chemicals (India) Pvt. Ltd. 58
CLEARSYNTH LABS LTD. 58
A.J Chemicals 58
Otto Chemie Pvt. Ltd. 58
Pharmaffiliates Analytics and Synthetics P. Ltd 58

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Methyl eugenol Spectrum

Methyl eugenol(93-15-2)MSMethyl eugenol(93-15-2)1HNMRMethyl eugenol(93-15-2)13CNMRMethyl eugenol(93-15-2)IR1Methyl eugenol(93-15-2)Raman

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1-ALLYL-3,4-DIMETHOXYBENZENE Eugenolmethylether,98% Methyl eugenol (technical) 1-ALLYL-3,4-DIMETHYOXYBENZENE methyleugenol,1,2-dimethoxy-4-(2-propenyl)-benzene,veratrolemethylether 1-ALLYL-3,4-DIMENTHOXYBENZENE Eugenol methyl ether Methyl eugenol EUGENOL METHYLETHER WITH GC Methyl Eugenol/Eugenol methyl ether METHYL EUGENOL 98+% FCC EUGENOL METHYL ETHER 99% eugenal methyl ether METHYL EUGENOL extrapure 1,3,4-Eugenol methyl ether 1,3,4-eugenolmethylether 4-allyl-1,2-dimethoxy-benzen 4-Allyl-1,2-dimethyoxybenzene Allyl veratrole Allyl-1,2-dimethoxybenzene Benzene, 4-(2-propenyl)-1,2-dimethoxy Benzene, 4-allyl-1,2-dimethoxy- Dimethoxy-4-(2-propenyl)benzene Ent 21040 ent21040 4-Allyl-1,2-dimethoxybenzene, Eugenol methyl ether 1,2-Dimethoxy-4-(2-propenyl)benzene,98% 1-(3,4-Dimethoxyphenyl)-2-propen 1,2-dimethoxy-4-(2-propenyl)-benzen 1,2-Dimethoxy-4-allylbenzene Eugenol Methyl Ether 1-Allyl-3,4-dimethoxybenzene Methyl eugenol ,98% 4-Allyl-1.2-dimethoxybenzene 1g [93-15-2] 4-Allyl-1,2-dimethoxybenzene,4-Allyl-1,2-dimethoxybenzene, Eugenol methyl ether Methyl eugenol,4-Allyl-1,2-dimethoxybenzene, Eugenol methyl ether, Eugenyl methyl ether LEVO-ROSE OXIDE 1,2-DiMethoxy-4-(2-propenyl)benzene, 98% 100ML Eugenol Methyl Ether Methyleugenol 4-Allylveratrole Allyl-3,4-diMethoxybenzene Benzene,1,2-diMethoxy-4-(2-propen-1-yl)- Eugenol-Methyl TIMTEC-BB SBB007916 1-(3,4-Dimethoxyphenyl)-2-propene femanumber2475 Methyl eugenol ether Methyl eugenyl ether methyleugenylether o-Methyl eugenol ether Veratrole methyl ether veratrolemethylether METHYL EUGENOL FEMA 2475 3,4-DIMETHOXYALLYLBENZENE 3-(3,4-DIMETHOXYPHENYL)-1-PROPENE Eugenol Impurity 5（Eugenol EP Impurity E） 4-Allyl-1,2-dimethoxybenzene> Methyleugenol@1000 μg/mL in EtOH 1,2-dimethoxy-4-(prop-2-en-1-yl)benzene Methyl eugenol USP/EP/BP