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Chlorpyrifos-methyl

Chlorpyrifos-methyl Structure
CAS No.
5598-13-0
Chemical Name:
Chlorpyrifos-methyl
Synonyms
tumar;m3196;M 3196;RELDAN;Zertell;Noltran;ent27520;dowco214;Reldan F;nsc60380
CBNumber:
CB8332228
Molecular Formula:
C7H7Cl3NO3PS
Molecular Weight:
322.53
MOL File:
5598-13-0.mol
Modify Date:
2023/5/18 11:31:19

Chlorpyrifos-methyl Properties

Melting point 45.5-46.5°C
Boiling point 347.3±52.0 °C(Predicted)
Density 1.64 g/cm3(Temp: 23 °C)
Flash point >100 °C
storage temp. APPROX 4°C
solubility Chloroform: Slightly Soluble
pka -5.59±0.10(Predicted)
form Crystalline Solid
color Amber
Water Solubility 4mg/L(25 ºC)
Merck 13,2208
BRN 1541078
CAS DataBase Reference 5598-13-0(CAS DataBase Reference)
NIST Chemistry Reference o,o-Dimethyl-o-(3,5,6-trichloro-2-pyridyl)phosphorothioate(5598-13-0)
EPA Substance Registry System Chlorpyrifos-methyl (5598-13-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS09
Signal word  Danger
Hazard statements  H302-H317-H331-H410
Precautionary statements  P261-P273-P280-P301+P312-P302+P352-P304+P340+P311
Hazard Codes  Xi;N,N,Xi,Xn,F
Risk Statements  43-50/53-36-20/21/22-11
Safety Statements  36/37-60-61-36-26-16
RIDADR  UN 3077
WGK Germany  2
RTECS  TG0700000
HS Code  29333990

Chlorpyrifos-methyl price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 45396 Chlorpyrifos-methyl PESTANAL?, analytical standard 5598-13-0 250MG ₹8497.63 2022-06-14 Buy
Sigma-Aldrich(India) 18647 Chlorpyrifos-methyl certified reference material, TraceCERT? 5598-13-0 50MG ₹13238.98 2022-06-14 Buy
Product number Packaging Price Buy
45396 250MG ₹8497.63 Buy
18647 50MG ₹13238.98 Buy

Chlorpyrifos-methyl Chemical Properties,Uses,Production

Description

Chlorpyrifos-methyl is a general use organophosphate insecticide registered in 1985. It is used for the control of stored grain pests, weevils, moths, borers, beetles and mealworms, red flour beetle, and grain moth; for seed treatment; and for warehouse. It is effective against rice stem borer, aphids, cutworms, plant and leaf hoppers, mole crickets and some moths, and stored grain pests. It is poorly soluble in water, moderately soluble in hexane and alcohols, and readily soluble in other organic solvents such as acetone, benzene, and chloroform.

Chemical Properties

Chlorpyrifos-methyl is a general use organophosphate insecticide registered in 1985. It is used for the control of stored grain pests, weevils, moths, borers, beetles and mealworms, red fl our beetle, grain moth, for seed treatment. It is effective against rice stem borer, aphids, cutworms, plant and leaf hoppers, mole crickets, moths and stored grain pests. It is poorly soluble in water, moderately soluble in hexane and alcohols, and readily soluble in other organic solvents, such as acetone, benzene, and chloroform

Uses

Chlorpyriphos-methyl is an derivative of Chlorpyrifos (C425300), an insecticide that acts on the nervous system of insects by inhibiting acetylcholinesterase.

Definition

ChEBI: An organic thiophosphate that is O,O-dimethyl hydrogen phosphorothioate in which the hydrogen of the hydroxy group has been replaced by a 3,5,6-trichloropyridin-2-yl group.

General Description

Colorless crystals. Corrosive to copper, brass, iron, and tin plate. Used as an insecticide.

Air & Water Reactions

Hydrolyzed by strong acid and base.

Reactivity Profile

A chlorinated organophosphate derivative. Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Chlorpyrifos-methyl is incompatible with strong acids and bases.

Health Hazard

Exposures to chlorpyrifos-methyl cause excessive salivation, sweating, rhinorrhea and tearing, muscle twitching, blurred vision/dark vision, slurred speech, weakness, tremor, incoordination, headache, dizziness, nausea, vomiting, abdominal cramps, diarrhea, respiratory depression, tightness in chest, wheezing, productive cough, fl uid in lungs, and pin-point pupils. In cases of severe exposure and poisoning, chlorpyrifos-methyl causes seizures, incontinence, respiratory depression, loss of consciousness, respiratory paralysis, and death. Exposures to chlorpyrifos-methyl cause cholinesterase inhibition in workers, and the systemic toxicity includes body weight loss, decreased food consumption, and liver, kidney, and adrenal pathology

Agricultural Uses

Insecticide: Chlorpyrifos-methyl is used on stored grain (for protection of stored food, feed oil, and seed grains against injury from stored grain weevils, moths, borers, beetles and mealworms including granary weevil, rice weevil, red flour beetle, confused flour beetle, saw-toothed grain beetle, Indian meal moth, and Angoumois grain moth, lessor grain borers), seed treatment, grain bin and warehouse. [14] In 2000, the registrants of chlorpyrifos-methyl requested voluntary cancellation of their products rather than committing to develop additional data for reregistration

Trade name

DOWCO-217®; NOLTRAN®; RELDAN®; RELDANE® , STORCIDE®; ZERTELL®

Safety Profile

Moderately toxic by ingestion, intraperitoneal, and skin contact routes. A skin irritant. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of Cl-, NOx POx and SOxA pesticide.

Potential Exposure

Chlorpyrifos-methyl is a general use organophosphate insecticide for use on stored grain (for protection of stored food, feed oil, and seed grains against injury from stored grain weevils, moths, borers, beetles, and mealworms including granary weevil, rice weevil, red flour beetle, confused flour beetle, saw-toothed grain beetle, Indian meal moth, and Angoumois grain moth, lessor grain borers), seed treatment, grain bin, and warehouse.

Shipping

UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

Strong oxidizers, strong acids, and alkalies. In the presence of strong reducing agents such as hydrides, organophosphates form highly toxic and flammable phosphine gas. Contact with oxidizers can cause the release of toxic oxides of phosphorus. Corrosive to copper, brass, iron, and tin plate.

Waste Disposal

This compound is 50% hydrolyzed in aqueous methanol solution @ pH 6 in 1930 days; and in 7.2 days at pH 9.96. Spray mixtures of <1% concentration are destroyed with an excess of 5.25% sodium hypochlorite in ,30 minutes @ 100°C; and in 24 hours @ 30°C. Concentrated (61.5%) mixtures are essentially destroyed by treatment with 100:1 volumes of the above sodium hypochlorite solution and steam in 10 minutes. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

Precautions

Workplaces should have adequate washing facilities at all times during handling and these should be close to the site of handling. Eating, drinking, and smoking should be prohibited during handling and before washing after handling. Containers of chlorpyrifosmethyl should be kept away from foodstuffs, animal feed and their containers, and out of reach of children

Global( 119)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Bhagiradha Chemicals And Industries Limited +91-4042212323 +91-4042221212 Telangana, India 12 58 Inquiry
Aimco Pesticides Limited +91-9444137807 +91-9825358545 Maharashtra, India 22 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Hangzhou FandaChem Co.,Ltd. 008657128800458; +8615858145714 China 9338 55 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49391 58 Inquiry
TargetMol Chemicals Inc. +1-781-999-5354 +1-00000000000 United States 19892 58 Inquiry
Hefei TNJ Chemical Industry Co.,Ltd. 0551-65418671 China 34571 58 Inquiry
Xi'an MC Biotech, Co., Ltd. 029-89275612 +8618991951683 China 2255 58 Inquiry
Alfa Chemistry +1-5166625404 United States 21317 58 Inquiry
Chloropyrifos-methyl Chloropyriphos-methyl Cooper graincote Dowco 214 dowco214 Dowco-214 Dursban methyl dursbanmethyl ENT 27520 ent27520 M 3196 Phosphorothioicacid,O,O-dimethylO-(3,5,6-trichloro-2-pyridyl)ester Reldan 50 Reldan F reldan50ec Trichlormethylfos tumar Zertell RELDAN RELDAN(R) PYRIBAN-M O,O-DIMETHYL O-(3,5,6-TRICHLORO-2-PYRIDINYL) PHOSPHOROTHIOATE O,O-DIMETHYL O-(3,5,6-TRICHLORO-2-PYRIDYL) PHOSPHOROTHIOATE CHLORPYRIPHOS-METHYL CHLORPYRIFOS METHYL Dimethyl O-(3,5,6-trichloro-2-pyridyl) phosophorothioate METHYL DURSBAN O,O-dimethyl O-3,5,6-trichloro-2-pyridyl phosphorodithioate m3196 Methyl chlorpyrifos Methyl chlorpyriphos methylchlorpyrifos methylchlorpyriphos Noltran NSC 60380 nsc60380 o,o-Dimethyl o-(3,5,6-trichloro-2-pyridinyl) thiophosphate O,O-dimethylO-3,5,6-trichloropyridin-2-ylphosphorothioate OMS-1155 Phosphorothioic acid, O,O-dimethyl O-(3,5,6-trichloro-2-pyridinyl) ester Phosphorothioic acid, O,O-dimethyl O-(3,5,6-trichloro-2-pyridyl) ester phosphorothioicacid,O,O-dimethylO-(3,5,6-trichloro-2-pyridinyl)ester CHLORPYRIPHOS-METHYL PESTANAL, 250 MG CHLORPYRIFOS METHYL, 250MG, NEAT chlorpyrifos-methyl (bsi,e-iso,ansi,esa) chlorpyrifos-methyl solution chlorpyriphos-methyl (f-iso,jmaf) Graincot Dimethoxy-sulfanylidene-(3,5,6-trichloropyridin-2-yl)oxyphosphorane Thiophosphoric acid O,O-dimethyl O-(3,5,6-trichloro-2-pyridyl) dimethoxy-sulfanylidene-(3,5,6-trichloropyridin-2-yl)oxy-$l^{5}-phosphane dimethoxy-thioxo-[(3,5,6-trichloro-2-pyridyl)oxy]phosphorane Chlorpyrifos Methyl 250mg [5598-13-0] Chlorpyrofos-methyl Clhorpyrifos-methyl Chlorpyrifos-Methyl Standard Chlorprifos Methyl Chlorpyrifos-methyl Solution, 100ppm