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Citraconic anhydride

Citraconic anhydride Structure
CAS No.
616-02-4
Chemical Name:
Citraconic anhydride
Synonyms
CTA;2,5-Furandione, 3-Methyl-;3-Methylmaleic anhydride;3-methyl-furan-2,5-dione;alpha-methylmaleicanhydride;CITRACONIC ANHYDRIDE;methyl-maleicanhydrid;3-methyl-5-furandione;Indobufen Impurity 53;METHYLMALEIC ANHYDRIDE
CBNumber:
CB9761753
Molecular Formula:
C5H4O3
Molecular Weight:
112.08
MOL File:
616-02-4.mol
MSDS File:
SDS
Modify Date:
2023/11/28 16:31:43

Citraconic anhydride Properties

Melting point 6-10 °C (lit.)
Boiling point 213-214 °C (lit.)
Density 1.247 g/mL at 25 °C (lit.)
vapor density 4 (vs air)
refractive index n20/D 1.471(lit.)
Flash point 215 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
color Clear colorless to very slightly yellow
Water Solubility decomposes
Sensitive Moisture Sensitive
BRN 1835
Dielectric constant 40.3(20℃)
LogP -0.232 (est)
CAS DataBase Reference 616-02-4(CAS DataBase Reference)
NIST Chemistry Reference 2,5-Furandione, 3-methyl-(616-02-4)
EPA Substance Registry System 2,5-Furandione, 3-methyl- (616-02-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS08
Signal word  Danger
Hazard statements  H314-H317-H334
Precautionary statements  P261-P272-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T
Risk Statements  23/24/25-36/37/38-42/43-34-24
Safety Statements  26-36/37/39-45-28A-23-36/37
RIDADR  UN 2810 6.1/PG 3
WGK Germany  3
RTECS  GE6825000
10-21
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29171990
NFPA 704
1
3 1

Citraconic anhydride price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 125318 Citraconic anhydride 98% 616-02-4 25G ₹2132.53 2022-06-14 Buy
Sigma-Aldrich(India) 125318 Citraconic anhydride 98% 616-02-4 100G ₹4979.5 2022-06-14 Buy
Sigma-Aldrich(India) 125318 Citraconic anhydride 98% 616-02-4 500G ₹16324.1 2022-06-14 Buy
TCI Chemicals (India) M0365 Citraconic Anhydride min. 98.0 % 616-02-4 25G ₹2100 2022-05-26 Buy
TCI Chemicals (India) M0365 Citraconic Anhydride min. 98.0 % 616-02-4 100G ₹4000 2022-05-26 Buy
Product number Packaging Price Buy
125318 25G ₹2132.53 Buy
125318 100G ₹4979.5 Buy
125318 500G ₹16324.1 Buy
M0365 25G ₹2100 Buy
M0365 100G ₹4000 Buy

Citraconic anhydride Chemical Properties,Uses,Production

Chemical Properties

clear colorless to very slightly yellow liquid

Uses

Citraconic anhydride is used as a monomer for specialty unsaturated polyester resins. It is used to prepare bicyclic pyrrolidines, maleimides and co- and terpolymers. It is also used for the protection of N-terminal amino acids. Further, it is involved in the preparation of clothing ping acid and its amide. In addition to this, it is selectively used for the isolation of histidyl peptides.

Purification Methods

Possible contamination is from the acid formed by hydrolysis. If the IR has OH bands, then reflux with Ac2O for 30minutes, evaporate, then distil the residue in a vacuum, otherwise distil in a vacuum. Store in a dry atmosphere. [Vaughan & Andersen J Am Chem Soc 77 6702 1955, Vaughan & Andersen J Org Chem 21 680 1956, Beilstein 17 H 440, 17 I 234, 17 II 448, 17 III/IV 5912, 17/11 V 65.]

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Anhydrid kyseliny citrakonove anhydridkyselinycitrakonove Citraconic acid anhydride citraconicacidanhydride Maleic anhydride, methyl- methyl-maleicacidanhydride methyl-maleicanhydrid Monomethylmaleic anhydride monomethylmaleicanhydride Citraconicanhydride,98% 3-methyl-2,5-pentanedione lpha-methylmaleic anhydride cis-Methylbutenedioic anhydride 2-METHYLMALEIC ANHYDRIDE CITRACONIC ANHYDRIDE METHYLMALEIC ANHYDRIDE 3-Methylfuran-2,5-dione, 2-Methylmaleic anhydride Citraconic anhydride, 98% 100GR Citraconic anhydride, 98% 250GR Citraconic anhydride 98% Citraconic Anhydride, 98.0%(GC) 2,5-Furanedione, 3-methyl 3-Methyl-2,5-furandione 3-methyl-5-furandione 3-methylmaleicanhydride alpha-Methylmaleic anhydride CitraconicAnhydride> alpha-methylmaleicanhydride CTA 3-methyl-furan-2,5-dione 3-Methylmaleic anhydride 2,5-Furandione, 3-Methyl- Citraconic anhydride (6CI, 8CI) Indobufen Impurity 53 616-02-4 516-02-4 C5H4O3OCO Carbonyl Compounds Carboxylic Acid Anhydrides BioChemical Building Blocks Specific Amino Acid Modification Reagents for lysine modification Proteomics Proteomics and Protein Expression Protein Modification Organic Building Blocks Anhydride Monomers Monomers Polymer Science Carbonyl Compounds Carboxylic Acid Anhydrides Organic Building Blocks Rubber & Plastic Auxiliary Agent