Dimethyl chlorothiophosphate
- CAS No.
- 2524-03-0
- Chemical Name:
- Dimethyl chlorothiophosphate
- Synonyms
- MCT;Dimethyl thiophosphorochloridate;DMPCT;NA 2267;U.N. 2267;METHYL PCT;(CH3O)2P(S)Cl;AURORA KA-1651;Dimethylthiophosphoryl;Dimethylchlorthiofosfat
- CBNumber:
- CB0150185
- Molecular Formula:
- C2H6ClO2PS
- Molecular Weight:
- 160.56
- MOL File:
- 2524-03-0.mol
- Modify Date:
- 2024/3/14 15:18:25
Boiling point | 66-67 °C16 mm Hg(lit.) |
---|---|
Density | 1.322 g/mL at 25 °C(lit.) |
vapor pressure | 0.67 psi ( 20 °C) |
refractive index |
n |
Flash point | 221 °F |
solubility | Chloroform (Sparingly), Methanol (Slightly) |
form | Oil |
color | Colourless |
Water Solubility | slowly hydrolyzes |
Stability | Moisture Sensitive |
CAS DataBase Reference | 2524-03-0(CAS DataBase Reference) |
NIST Chemistry Reference | Phosphorochloridothioic acid, o,o-dimethyl ester(2524-03-0) |
EPA Substance Registry System | Dimethyl chlorothiophosphate (2524-03-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05,GHS06 |
---|---|
Signal word | Danger |
Hazard statements | H318-H412-H330-H335-H302-H315-H312 |
Precautionary statements | P273-P501-P264-P270-P301+P312-P330-P501-P280-P302+P352-P312-P322-P363-P501-P264-P280-P302+P352-P321-P332+P313-P362-P280-P305+P351+P338-P310-P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501 |
Hazard Codes | T |
Risk Statements | 23/24/25-34-23-21/22 |
Safety Statements | 23-26-36/37/39-45-24/25 |
RIDADR | UN 2267 6.1/PG 2 |
WGK Germany | 3 |
RTECS | TD1830000 |
HazardClass | 6.1(a) |
PackingGroup | II |
HS Code | 29309099 |
Toxicity | mouse,LC50,inhalation,320mg/m3/2H (320mg/m3),"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 56, 1982. |
Dimethyl chlorothiophosphate Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light yellow liquid
Uses
Dimethyl chlorothiophosphate is used as an intermediate in the manufacture of insecticides, pesticides, fungicides, oil and gasoline additives, plasticizers, corrosion inhibitors, flame-retardants, and flotation agents.
Preparation
Dimethyl chlorothiophosphate is prepared by reaction of phosphorus pentasulfide & methyl alcohol followed by reaction of the resulting dimethyl phosphorodithioate with chlorine.
General Description
Dimethyl chlorothiophosphate is a colorless to light amber liquid. Used as a chemical intermediate for insecticides, pesticides, and fungicides; oil and gasoline additives; plasticizers; corrosion inhibitors; flame retardants; and flotation agents. Not registered as a pesticide in the U.S. (EPA, 1998)
Reactivity Profile
Organothiophosphates, such as Dimethyl chlorothiophosphate, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Health Hazard
Dimethyl chlorothiophosphate is a strong irritant to the eyes, skin, and mucous membranes.
Fire Hazard
Dimethyl chlorothiophosphate may burn but does not ignite readily. Dimethyl chlorothiophosphate may ignite combustibles (wood, paper, oil, etc.). When heated Dimethyl chlorothiophosphate emits very toxic fumes of chlorine containing compounds, phosphorus oxides, and sulfur oxides.
Safety Profile
Poison by inhalation. Moderately toxic by ingestion and skin contact. Corrosive. When heated to decomposition it emits very toxic fumes of Cl-, POx, and SOx
Dimethyl chlorothiophosphate Preparation Products And Raw materials
Raw materials
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