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Michler's ketone

CAS No.: 90-94-8

Chemical Name:: Michler's ketone

Synonyms: Bis(4-(dimethylamino)phenyl)methanone;BIS-DIMETHYLAMINOPHENYLMETHANONE;MICHLERS KETONE;nsc9602;ai3-22412;michler’s;NCI-C02006;Ketone base;MICHLER KETONE;MICHLER'S KETONE

CBNumber:: CB1703263

Molecular Formula:: C17H20N2O

Molecular Weight:: 268.35

MOL File:: 90-94-8.mol

MSDS File:: SDS

Modify Date:: 2024/3/14 15:18:25

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Michler's ketone Properties

Melting point	174 -176 °C(lit.)
Boiling point	360 °C
Density	1.0208 (rough estimate)
refractive index	1.5486 (estimate)
Flash point	220 °C
storage temp.	Store below +30°C.
solubility	ethanol: 5 mg/mL, clear
form	Powder
pka	2.55±0.12(Predicted)
color	Blue to dark blue or gray
Water Solubility	400 mg/L (20 ºC)
Merck	14,6177
BRN	790733
Stability	Stable. Combustible. Incompatible with strong oxidizing agents, strong reducing agents.
InChIKey	VVBLNCFGVYUYGU-UHFFFAOYSA-N
CAS DataBase Reference	90-94-8(CAS DataBase Reference)
IARC	2B (Vol. 99) 2010
NIST Chemistry Reference	Methanone, bis[4-(dimethylamino)phenyl]-(90-94-8)
EPA Substance Registry System	Michler's ketone (90-94-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS08

Signal word

Danger

Hazard statements

H318-H341-H350

Precautionary statements

P201-P280-P305+P351+P338+P310-P308+P313

Hazard Codes

T,Xi

Risk Statements

45-41-68-36/37/38

Safety Statements

53-45-36-26

RIDADR

2811

WGK Germany

RTECS

DJ0250000

Autoignition Temperature

480 °C

TSCA

Yes

HazardClass

6.1

PackingGroup

III

HS Code

29223990

Toxicity

LD50 orally in Rabbit: > 6400 mg/kg

NFPA 704

	0
2		0

Michler's ketone price More Price(8)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	8.08125	4,4′-Bis(dimethylamino)-benzophenone for synthesis	90-94-8	250G	₹7600.01	2022-06-14	Buy
Sigma-Aldrich(India)	8.08125	4,4′-Bis(dimethylamino)-benzophenone for synthesis	90-94-8	1KG	₹18180	2022-06-14	Buy
Sigma-Aldrich(India)	56614	Michler′s ketone certified reference material, TraceCERT?	90-94-8	100MG	₹8844.03	2022-06-14	Buy
Sigma-Aldrich(India)	147834	Michler′s ketone 98%	90-94-8	100G	₹2998.53	2022-06-14	Buy
Sigma-Aldrich(India)	147834	Michler′s ketone 98%	90-94-8	500G	₹6960.48	2022-06-14	Buy

Product number	Packaging	Price	Buy
8.08125	250G	₹7600.01	Buy
8.08125	1KG	₹18180	Buy
56614	100MG	₹8844.03	Buy
147834	100G	₹2998.53	Buy
147834	500G	₹6960.48	Buy

Michler's ketone Chemical Properties,Uses,Production

Chemical Properties

white to light greenish crystals

Uses

In manufacture of dyes and pigments.

General Description

White to greenish crystalline leaflets or blue powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4,4'-Bis(dimethylamino)benzophenone is incompatible with strong oxidizing agents and strong reducing agents .

Hazard

Possible carcinogen.

Fire Hazard

Literature sources indicate that 4,4'-Bis(dimethylamino)benzophenone is combustible.

Safety Profile

Confirmed human carcinogen with experimental carcinogenic and neoplastigenic data. A poison by ingestion. Mutation data reported. A flammable liquid. When heated to decomposition it emits toxic fumes of NOx.

Potential Exposure

Mutagen. Animal Carcinogen. Michler’s ketone is a dye intermediate and derivative of dimethylaniline. It is also used in antifreeze formulations, cosmetics, cleaning compounds; heat transfer fluids; as a chemical intermediate in the synthesis of at least 13 dyes and pigments, especially auramine derivatives.

Carcinogenicity

Michler’s ketone is reasonably anticipated to be a human cagen based on sufficient evidence of carcinogenicity from stud rcinoies in experimental animals.

Shipping

UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poison Inhalation Hazard. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN1602 Dyes, liquid, toxic, n.o.s or Dye intermediates, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Dissolve the ketone in dilute HCl, filter and precipitate it by adding ammonia (to remove water-insoluble impurities such as benzophenone). Then crystallise it from EtOH or pet ether. [Suppan J Chem Soc, Faraday Trans1 71 539 1975.] It is also purified by dissolving in *benzene, then washing with water until the aqueous phase is colourless. The *benzene is evaporated off, and the residue is recrystallised three times from *benzene and EtOH [Hoshino & Kogure J Phys Chem 72 417 1988]. [Beilstein 14 IV 255.]

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from aldehydes, alkaline materials, strong acids, strong bases, strong reducing agents such as hydrideds and active metals. Contact with hydrogen peroxide may form heat- and shock- sensitive explosives.

Waste Disposal

Do not discharge into drains or sewers. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. If allowed, Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Michler's ketone Preparation Products And Raw materials

Raw materials

Ethanol N-Methylaniline ETHYLENE OXIDE Formaldehyde Oxygen

N,N-Dimethylaniline Chloranil Methanol

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Preparation Products

Basic Blue 11 Crystal Violet Basic Blue 26 4,4'-Bis(dimethylamino)thiobenzophenone 4,4'-VINYLIDENEBIS(N,N-DIMETHYLANILINE)

4,4'-Bis(dimethylamino)benzhydrol ACID VIOLET 6BN Methanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(2-naphthalenylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride, disulfo deriv. Crystal Violet

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Michler's ketone Suppliers

Global( 263)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
CLEARSYNTH LABS LTD.	+91-22-45045900	Hyderabad, India	6351	58	Inquiry
CHEMSWORTH	+91-261-2397244	New Delhi, India	6707	30	Inquiry
A.J Chemicals	91-9810153283	New Delhi, India	6124	58	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Alfa Aesar	1 800 209 7001	Maharashtra, India	6913	58	Inquiry
Chemosol Inds. (India) Private Limited	+91 22 - 2341 1018	Mumbai, India	25	58	Inquiry
Clearsynth Labs	91-22-45045900	Maharashtra, India	3889	58	Inquiry
HiMedia Laboratories	91-22-61471919	Maharashtra, India	1843	58	Inquiry
Hebei Mojin Biotechnology Co., Ltd	+86 13288715578 +8613288715578	China	12447	58	Inquiry
Hebei Yanxi Chemical Co., Ltd.	+86-17531190177; +8617531190177	China	5873	58	Inquiry

Supplier	Advantage
CLEARSYNTH LABS LTD.	58
CHEMSWORTH	30
A.J Chemicals	58
TCI Chemicals (India) Pvt. Ltd.	58
Alfa Aesar	58
Chemosol Inds. (India) Private Limited	58
Clearsynth Labs	58
HiMedia Laboratories	58
Hebei Mojin Biotechnology Co., Ltd	58
Hebei Yanxi Chemical Co., Ltd.	58

Michler's ketone Spectrum

Michler's ketone(90-94-8)MS Michler's ketone(90-94-8)¹HNMR Michler's ketone(90-94-8)¹³CNMR Michler's ketone(90-94-8)IR1 Michler's ketone(90-94-8)IR2 Michler's ketone(90-94-8)Raman Michler's ketone(90-94-8)ESR

90-94-8(Michler's ketone)Related Search:

4,4'-Bis(dimethylamino)thiobenzophenone 2-Aminobenzophenone Benzophenone Primidone 2,2',4,4'-Tetrahydroxybenzophenone

Tetramethylammonium chloride Ethylenebis(nitrilodimethylene)tetraphosphonic acid (3,4-Diaminophenyl)phenylmethanone 3,4-Dihydroxybenzophenone Pyromellitic Dianhydride

Benzophenone imine 4,4'-Dimethylbenzophenone 4,4'-Dihydroxybenzophenone 2,4-Difluorobenzophenone 2,4-Dihydroxybenzophenone

Bis(4-fluorophenyl)-methanone Benzophenone oxime 4,4'-Methylenedianiline

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BIS(P-DIMETHYLAMINOPHENYL)KETONE LABOTEST-BB LT00086928 TETRAMETHYL-P,P'-DIAMINOBENZOPHENONE MICHLER'S KETONE MICHLER KETONE P,P'-TETRAMETHYLDIAMINOBENZOPHENONE N,N,N',N'-TETRAMETHYL-4,4'-DIAMINOBENZOPHENONE N,N,N,N'-TETRAMETHYL-4,4'-DIAMINOBENZOPHENONE 4,4'-di(Dimethylamino)benzophenone ai3-22412 Benzophenone, 4,4'-bis(dimethylamino)- bis(dimethylamino)-4,4’benzophenone bis(p-(n,n-dimethylamino)phenyl)ketone bis[4-(dimethylamino)phenyl]-methanon Bis[4-(dimethylamino)phenyl]methanone bis[4-(dimethylamino)phenyl]-Methanone Bis[p-(N,N-dimethylamino)phenyl] ketone Bis-4,4'-(dimethylamino)-benzophenon (michlers keton) Di-p-dimethylaminophenylketone Ketone base michler’s N,N'-Bisdimethylamino NCI-C02006 nsc9602 p,p’-bis(dimethylamino)benzophenone p,p’bis(n,ndimethylamino)benzophenone p,p’-bis(n,n-dimethylamino)benzophenone p,p’-michler’sketone p,p'-bis(Dimethylamino)benzophenone p,p'-Bis(N,N-dimethylamino)benzophenone p,p'-Michler's ketone p,p'-Tetramethyl-4,4'-diaminobenzophenone tetramethyldiaminobenzophenone 4,4'-BIS(DIMETHYLAMINO)BENZOPHENONE (Tetramethyldiamino)benzophenone 4,4’-bis(dimethylamino)-benzophenon 4,4’-bis(n,n-dimethylamino)benzophenone 4,4’-Di(N,N-dimethylamino)benzophenone 4,4’-di(N,N-Dimethylamino)diphenylketone 4,4’-Tetramethyldiaminobenzophenone Michler`s krtone 4,4'-Bis(dimethylamine)benzophenone Michler'sKetone,98% N,N'-Tetramethyl-4,4'-diaminobenzophenone Methanone, bis4-(dimethylamino)phenyl- BIS(DIMETHYLAMINO)BENZOPHENONE 4,4''-BIS(DIMETHYLAMINO)-BENZOPHENONE 98+% 3,6-DIMETHYL-1,4-DIOXANE-2,5-DIONE (4,4''-BIS(DIMETHYLAMINO)BENZOPHENONE) Bis[4-(dimethylamino)phenyl] ketone 3,6-Dimethyl-1,4-dioxane-2,5-dione (4,4'-Bis(dimethylamino)benzo Michlers Ketone[4,4-Bis(dimethylamino)benzophenone] Michler's Ketone N,N,N',N'-Tetramethyl-4,4'-diaminobenzophenone 4,4'-BIS(DIMETHYLAMINO)-BENZOPHENONE FOR Michler's ketone 98% 4-[4-(Dimethylamino)benzoyl]-N,N-dimethylaniline Michlers ketone 4,4'-Bis(dimethylamino)benzophenone N,N,N',N'-Tetramethyl-4,4'-diaminobenzophenone 4,4'-Bis(dimethylamino)-benzophenone for synthesis 4,4'-Bis(dimethyL