ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Sulfonyl halide >N-Phenyl-bis(trifluoromethanesulfonimide)

N-Phenyl-bis(trifluoromethanesulfonimide)

N-Phenyl-bis(trifluoromethanesulfonimide) Structure
CAS No.
37595-74-7
Chemical Name:
N-Phenyl-bis(trifluoromethanesulfonimide)
Synonyms
PHENYL TRIFLIMIDE;N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE;N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE);1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide;N-PHENYLTRIFLUOROMETHANESULFONIMIDE;phenyltrifluoromethanesulfonimide;N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE);trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide;N-PHENYLT;NSC 240874
CBNumber:
CB5289550
Molecular Formula:
C8H5F6NO4S2
Molecular Weight:
357.25
MOL File:
37595-74-7.mol
MSDS File:
SDS
Modify Date:
2024/4/25 9:47:11

N-Phenyl-bis(trifluoromethanesulfonimide) Properties

Melting point 100-102 °C(lit.)
Boiling point 305.3±52.0 °C(Predicted)
Density 1.766±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.
pka -13.12±0.50(Predicted)
form Crystals or Crystalline Powder
color White or colorless
Sensitive Moisture Sensitive
BRN 1269141
Stability Moisture Sensitive
InChI InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
InChIKey DIOHEXPTUTVCNX-UHFFFAOYSA-N
SMILES C(F)(F)(F)S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(=O)=O
CAS DataBase Reference 37595-74-7(CAS DataBase Reference)
NIST Chemistry Reference N-phenyltrifluoromethanesulfonimide(37595-74-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
21
TSCA  No
HazardClass  IRRITANT
HS Code  29242100
NFPA 704
1
2 1

N-Phenyl-bis(trifluoromethanesulfonimide) price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 78175 N-Phenyl-bis(trifluoromethanesulfonimide) ≥98.0% (HPLC) 37595-74-7 5G ₹5639.83 2022-06-14 Buy
Sigma-Aldrich(India) 78175 N-Phenyl-bis(trifluoromethanesulfonimide) ≥98.0% (HPLC) 37595-74-7 25G ₹21606.7 2022-06-14 Buy
Sigma-Aldrich(India) 78175 N-Phenyl-bis(trifluoromethanesulfonimide) ≥98.0% (HPLC) 37595-74-7 50G ₹45378.4 2022-06-14 Buy
Sigma-Aldrich(India) 295973 N-Phenyl-bis(trifluoromethanesulfonimide) 99% 37595-74-7 5G ₹3658.85 2022-06-14 Buy
Sigma-Aldrich(India) 295973 N-Phenyl-bis(trifluoromethanesulfonimide) 99% 37595-74-7 25G ₹23468.6 2022-06-14 Buy
Product number Packaging Price Buy
78175 5G ₹5639.83 Buy
78175 25G ₹21606.7 Buy
78175 50G ₹45378.4 Buy
295973 5G ₹3658.85 Buy
295973 25G ₹23468.6 Buy

N-Phenyl-bis(trifluoromethanesulfonimide) Chemical Properties,Uses,Production

Description

N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation. 

Chemical Properties

white to off-white crystalline powder

Synthesis

Add methylene chloride, aniline, 4-dimethylaminopyridine (DMAP), and triethylamine to a reactor equipped with a thermometer, distillation device, and mechanical stirring. When the vacuum of the reactor is evacuated to -0.095MPa and cooled to -40°C, trifluoromethanesulfonyl fluoride gas is introduced and then stirred at -20°C ~ 0°C and 0.02MPa ~ 0.1MPa reaction pressure, and react for 6 hours Finally, the excess trifluoromethanesulfonyl fluoride gas in the reactor is released and collected by cooling. After the inside of the reactor is brought to normal pressure, 500 mL of water is added, and the liquid is separated. A light yellow solid is obtained after the organic phase is heated to 40°C and methylene chloride is distilled. The light yellow solid is recrystallized with toluene to obtain 650g of white crystal N-Phenyl-bis(trifluoromethanesulfonimide).

Global( 504)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
SURVIVAL TECHNOLOGIES LIMITED +91 8108285261 Gujarat, India 294 58 Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
Covalent Incorporation +91-9033666099 +91-9033666099 Gujarat, India 50 58 Inquiry
MANPICK LABORATORIES PVT LTD +91-9949460828 +91-9949460828 Hyderabad, India 71 58 Inquiry
Noble Molecular Research +91 9717706044 Uttar Pradesh, India 85 58 Inquiry
ALS INDIA LIFE SCIENCES +91-8977036379 +91-8977036379 Hyderabad, India 1879 58 Inquiry
Aravali Pharma And Lifesciences +91-9350857917 +91-9810502945 New Delhi, India 119 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry

Related articles

1,1,1-TRIFLUORO-N-PHENYL-N-[(TRIFLUOROMETHYL)SULFONYL]METHANESULFONAMIDE N-Phenylbis(trifluoromethanesulphonimide), Phenyl triflimide N-Phenyl bis trifluorosulphonamide N-Bis(trifluoromethylsulfonyl)aniline 1,1,1-trifluoro-N-(methylsulfonyl)methanesulfonamide N- phenyl-bis (trifluoromethanesulfonyl) imide N-Phenylbis(trifluoroMethanesulfoniMide), 97% 5GR N,N-Bis(trifluoromethylsulfonyl)aniline Phenyl Triflimide N-Phenyltrifluoromethanesulfonimide N,N-Bis(trifluoroMethylsufonyl)aniline N,N-Bis(trifluoroMethylsulfonyl)aniline SynonyMs N-Phenylbis(trifluoroMethanesulfon)iMide N-phenyldouble(threefluoro Methanesulfonic acidiMide N-Phenyl-bis(trifluoroMethanesulfoniMide) >=98.0% (HPLC) N,N-Bis(trifluoromethanesulphonyl)aniline~Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide N-PHENYL-BIS-(TRIFLUORMETHANSULFONIMID) N,N-BIS-(TRIFLUOROMETHANESULFONYL)ANILINE 1,1,1-Trifluoro-N-phenyl-N-(trifluoromethyl)sulphonylmethanesulphonamide n-phenylbis(trifluorometanesulfonimide) N-Phenyl-bis(trifluoromethyl)sulfonimide N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent] N-phenyl-bis(trifluoromethanesulfonamide) N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Phenyl triflimide, 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide N-Phenyltrifluoromethanesulfonimide ,98% N-Phenyl-bis(trifluoromethanesulfonimide),1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide, N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Pheny N,N-Bis(trifluoromethylsulphonyl)aniline 98% N-Phenylbis(trifluoromethanesulfonyl)amine N-Phenylbis(trifluoromethylsulfonyl)amine N-Phenyl-N,N-bis(trifluoromethylsulfonyl)amine N-Phenylbis(trifluoromethanesulphonimide)97% N-Phenylbis(trifluoromethanesulfonimide),97% N-Phenylbis(trifluromethanesulphonimide)99% N-phenyl bis(trifluoromethanesulfonyl)amide N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7 N,N-Bis(trifluoromethylsulfonyl)aniline 37595-74-7 -bis(trifL fonimide) N-Phenylbis(trifluoromethanesulfonimide)[TriflatingReagent]> Methanesulfonamide, 1,1,1-trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]- 1,1,1-trifluoro-N-phenyl-N TIANFUCHEM--37595-74-7--N-Phenyl-bis(trifluoromethanesulfonimide) factory price phenyltrifluoromethanesulfonimide N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE) N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE) N-PHENYLTRIFLUOROMETHANESULFONIMIDE N-PHENYLTRIFLUOROMETHANESULPHONIMIDE N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE NSC 240874 1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide PHENYL TRIFLIMIDE trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide N-PHENYLT Bis(trifluoromethylsulfonyl)aniline N- phenylbis (trifluoromethanesulfonyl) imine N-PHENYL-BIS(TRIFLUROMETHANSULPHONIMIDE) N-phenylbis (trifluoromesulfonimide) 37595-74-7 7595-74-7 37595-74-4