N-Phenyl-bis(trifluoromethanesulfonimide)
- CAS No.
- 37595-74-7
- Chemical Name:
- N-Phenyl-bis(trifluoromethanesulfonimide)
- Synonyms
- PHENYL TRIFLIMIDE;N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE;N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE);1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide;N-PHENYLTRIFLUOROMETHANESULFONIMIDE;phenyltrifluoromethanesulfonimide;N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE);trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide;N-PHENYLT;NSC 240874
- CBNumber:
- CB5289550
- Molecular Formula:
- C8H5F6NO4S2
- Molecular Weight:
- 357.25
- MOL File:
- 37595-74-7.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/4/25 9:47:11
Melting point | 100-102 °C(lit.) |
---|---|
Boiling point | 305.3±52.0 °C(Predicted) |
Density | 1.766±0.06 g/cm3(Predicted) |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
solubility | Soluble in methanol. Slightly soluble in chloroform and ethyl acetate. |
pka | -13.12±0.50(Predicted) |
form | Crystals or Crystalline Powder |
color | White or colorless |
Sensitive | Moisture Sensitive |
BRN | 1269141 |
Stability | Moisture Sensitive |
InChI | InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H |
InChIKey | DIOHEXPTUTVCNX-UHFFFAOYSA-N |
SMILES | C(F)(F)(F)S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(=O)=O |
CAS DataBase Reference | 37595-74-7(CAS DataBase Reference) |
NIST Chemistry Reference | N-phenyltrifluoromethanesulfonimide(37595-74-7) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
WGK Germany | 3 | |||||||||
F | 21 | |||||||||
TSCA | No | |||||||||
HazardClass | IRRITANT | |||||||||
HS Code | 29242100 | |||||||||
NFPA 704 |
|
N-Phenyl-bis(trifluoromethanesulfonimide) price More Price(14)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 78175 | N-Phenyl-bis(trifluoromethanesulfonimide) ≥98.0% (HPLC) | 37595-74-7 | 5G | ₹5639.83 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 78175 | N-Phenyl-bis(trifluoromethanesulfonimide) ≥98.0% (HPLC) | 37595-74-7 | 25G | ₹21606.7 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 78175 | N-Phenyl-bis(trifluoromethanesulfonimide) ≥98.0% (HPLC) | 37595-74-7 | 50G | ₹45378.4 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 295973 | N-Phenyl-bis(trifluoromethanesulfonimide) 99% | 37595-74-7 | 5G | ₹3658.85 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 295973 | N-Phenyl-bis(trifluoromethanesulfonimide) 99% | 37595-74-7 | 25G | ₹23468.6 | 2022-06-14 | Buy |
N-Phenyl-bis(trifluoromethanesulfonimide) Chemical Properties,Uses,Production
Description
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation.
Chemical Properties
white to off-white crystalline powder
Synthesis
Add methylene chloride, aniline, 4-dimethylaminopyridine (DMAP), and triethylamine to a reactor equipped with a thermometer, distillation device, and mechanical stirring. When the vacuum of the reactor is evacuated to -0.095MPa and cooled to -40°C, trifluoromethanesulfonyl fluoride gas is introduced and then stirred at -20°C ~ 0°C and 0.02MPa ~ 0.1MPa reaction pressure, and react for 6 hours Finally, the excess trifluoromethanesulfonyl fluoride gas in the reactor is released and collected by cooling. After the inside of the reactor is brought to normal pressure, 500 mL of water is added, and the liquid is separated. A light yellow solid is obtained after the organic phase is heated to 40°C and methylene chloride is distilled. The light yellow solid is recrystallized with toluene to obtain 650g of white crystal N-Phenyl-bis(trifluoromethanesulfonimide).
N-Phenyl-bis(trifluoromethanesulfonimide) Preparation Products And Raw materials
Raw materials
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Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
SURVIVAL TECHNOLOGIES LIMITED | +91 8108285261 | Gujarat, India | 294 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
Covalent Incorporation | +91-9033666099 +91-9033666099 | Gujarat, India | 50 | 58 | Inquiry |
MANPICK LABORATORIES PVT LTD | +91-9949460828 +91-9949460828 | Hyderabad, India | 71 | 58 | Inquiry |
Noble Molecular Research | +91 9717706044 | Uttar Pradesh, India | 85 | 58 | Inquiry |
ALS INDIA LIFE SCIENCES | +91-8977036379 +91-8977036379 | Hyderabad, India | 1879 | 58 | Inquiry |
Aravali Pharma And Lifesciences | +91-9350857917 +91-9810502945 | New Delhi, India | 119 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
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