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Sodium fluorosilicate

Sodium fluorosilicate Structure
CAS No.
16893-85-9
Chemical Name:
Sodium fluorosilicate
Synonyms
SODIUM SILICOFLUORIDE;SSF;SODIUM HEXAFLUOROSILICATE;ens-zemweevilbait;SODIUM FLUOSILICATE;Sodium flurosilicate;safsan;salufer;ent1,501;氟硅酸钠生产厂家价格
CBNumber:
CB7423572
Molecular Formula:
F6Na2Si
Molecular Weight:
188.06
MOL File:
16893-85-9.mol
Modify Date:
2024/7/24 17:31:20

Sodium fluorosilicate Properties

Melting point melts at red heat, decomposing [MER06]
Boiling point 620℃[at 101 325 Pa]
Density 2.68 g/mL at 25 °C(lit.)
vapor pressure 0.01Pa
refractive index 1.310
solubility insoluble in ethanol
form Crystals
Specific Gravity 2.68
color White
Odor odorless
Water Solubility Slightly soluble in water. Solubility increases with temperature. Insoluble in alcoholSlightly soluble in water. Insoluble in alcohol.
Merck 14,8624
Exposure limits ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
Stability Stable. Incompatible with oxidizing agents, water. Moisture sensitive.
LogP 0.001
CAS DataBase Reference 16893-85-9(CAS DataBase Reference)
EPA Substance Registry System Sodium fluosilicate (16893-85-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06
Signal word  Danger
Hazard statements  H301+H311+H331
Precautionary statements  P280-P301+P310+P330-P302+P352+P312-P304+P340+P311
Hazard Codes  T,Xi
Risk Statements  23/24/25
Safety Statements  26-45
RIDADR  UN 2674 6.1/PG 3
WGK Germany  2
RTECS  VV8410000
Hazard Note  Irritant
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  2826908090
Toxicity LD in rabbits (mg F/kg): 76 intragastric; in rats (mg F/kg): 42 s.c. (Muehlberger); LD in guinea pigs (mg/kg): 250 orally, 500 s.c. (Waldbott)
NFPA 704
0
3 0

Sodium fluorosilicate price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 250171 Sodium hexafluorosilicate 16893-85-9 500G ₹7555.85 2022-06-14 Buy
Sigma-Aldrich(India) 250171 Sodium hexafluorosilicate 16893-85-9 2KG ₹8595.05 2022-06-14 Buy
ALFA India ALF-069106-A3 Sodium hexafluorosilicate, >99% 16893-85-9 2kg ₹9906 2022-05-26 Buy
ALFA India ALF-069106-36 Sodium hexafluorosilicate, 99+% 16893-85-9 500g ₹4953 2022-05-26 Buy
ottokemi S 2380 Sodium silicofluoride 98% 16893-85-9 500gm ₹342 2022-05-26 Buy
Product number Packaging Price Buy
250171 500G ₹7555.85 Buy
250171 2KG ₹8595.05 Buy
ALF-069106-A3 2kg ₹9906 Buy
ALF-069106-36 500g ₹4953 Buy
S 2380 500gm ₹342 Buy

Sodium fluorosilicate Chemical Properties,Uses,Production

Chemical Properties

white powder

Uses

In enamels for china and porcelain; manufacture of opal glass; as insecticide, rodenticide; mothproofing of woolens. Fluoridating agent for drinking water. Intermediate in production of synthetic cryolite.

General Description

Fine, white, odorless, powdered solid. Toxic by ingestion, inhalation and skin absorption. Used as a rodenticide.

Air & Water Reactions

Water soluble.

Reactivity Profile

Sodium fluorosilicate has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive.

Hazard

Toxic by ingestion and inhalation, strong irritant to tissue.

Health Hazard

Inhalation of dust may irritate nose and throat. Ingestion causes symptoms similar to fluoride poisoning; compound is highly toxic; initial symptoms include nausea, cramps, vomiting, diarrhea, and dehydration; in severe cases, convulsions, shock, and cyanosis are followed by death in 2-4 hr. Contact with eyes causes irritation. Contact with skin causes rash, redness, and burning, sometimes followed by ulcer formation.

Fire Hazard

Behavior in Fire: Decomposes at red heat

Industrial uses

Sodium fluorosilicate (Na2SiF6) is a white, isomorphous powder. Solubility in water is similar to that of NaF. In acid pH, solubility improves.
Commercially, Na2SiF6 is produced by treatment of fluorosilic acid with sodium chloride, as shown in the following reaction: H2SiF6 + 2NaCl = Na2SiF6 + 2HCl

Safety Profile

Poison by ingestion and subcutaneous routes. A skin and severe eye irritant. An insecticide. When heated to decomposition it emits very toxic fumes of Fand Na2O.

Potential Exposure

Sodium hexafluorosilicate is as a rodenticide; as an intermediate in production of synthetic cyrolite; as an insecticide in delousing and in mothproofing of woolens.

Shipping

UN2674/Sodium fluorosilicate, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Crystallise it from hot water (40mL/g) by cooling.

Incompatibilities

Reacts with acids to produce hydrogen fluoride, a highly corrosive and poisonous gas.

Global( 457)Suppliers
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