Geranyl acetate
- CAS No.
- 105-87-3
- Chemical Name:
- Geranyl acetate
- Synonyms
- GERANIOL ACETATE;(2E)-3,7-Dimethyl-2,6-octadienyl acetate;FEMA 2509;GERANYL ACETATE 60;ACETIC ACID GERANYL ESTER;(E)-3,7-diMethylocta-2,6-dien-1-yl acetate;3,7-DIMETHYL-TRANS-2,6-OCTADIEN-1-YL-ACETATE;Meraneine;NCI-C54728;Geranylacetat
- CBNumber:
- CB5334054
- Molecular Formula:
- C12H20O2
- Molecular Weight:
- 196.29
- MOL File:
- 105-87-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/22 15:01:55
| Melting point | 25°C |
|---|---|
| Boiling point | 236-242 °C(lit.) |
| Density | 0.916 g/mL at 25 °C |
| vapor density | 6.8 (vs air) |
| vapor pressure | 0.07 mm Hg ( 20 °C) |
| refractive index |
n |
| FEMA | 2509 | GERANYL ACETATE |
| Flash point | 220 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly) |
| form | Liquid |
| color | Colourless |
| Specific Gravity | 0.916 |
| Odor | at 100.00 %. floral rose lavender green waxy |
| Odor Type | floral |
| Water Solubility | <0.1 g/100 mL at 20 ºC |
| JECFA Number | 58 |
| LogP | 4.04 at 20℃ |
| CAS DataBase Reference | 105-87-3(CAS DataBase Reference) |
| NIST Chemistry Reference | 2,6-Octadien-1-ol, 3,7-dimethyl-, acetate, (E)-(105-87-3) |
| EPA Substance Registry System | trans-Geraniol acetate (105-87-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H317-H412 | |||||||||
| Precautionary statements | P261-P264-P272-P273-P280-P302+P352 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36-24/25 | |||||||||
| RIDADR | UN1230 - class 3 - PG 2 - Methanol, solution | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | RG5920000 | |||||||||
| F | 10-23 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29153900 | |||||||||
| Toxicity | The acute oral UD 50 value in rats was reported as 6.33 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964). | |||||||||
| NFPA 704 |
|
Geranyl acetate price More Price(16)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W250910 | Geranyl acetate natural, FCC | 105-87-3 | 100G | ₹7241.93 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W250910 | Geranyl acetate natural, FCC | 105-87-3 | 1SAMPLE-K | ₹8010.5 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W250910 | Geranyl acetate natural, FCC | 105-87-3 | 1KG | ₹29032.65 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W250910 | Geranyl acetate natural, FCC | 105-87-3 | 5KG | ₹111854.73 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W250902 | Geranyl acetate FCC | 105-87-3 | 1SAMPLE-K | ₹5141.88 | 2022-06-14 | Buy |
Geranyl acetate Chemical Properties,Uses,Production
Description
Geranyl acetate has a pleasant, flowery odor reminiscent of rose lavender. It has a burning taste, initially somewhat bitter and then sweet. It is produced from geraniol by acetylation or by fractional distillation of essential oils in which it is present.
Chemical Properties
Geranyl Acetate occurs in varying amounts in many essential oils: up to 60% in oils from Callitris and Eucalyptus species and up to 14% in palmarosa oil. A smaller amount occurs in, for example, geranium, citronella, petitgrain, and lavender oils. Geranyl acetate is a liquid with a fruity rose note, reminiscent of pear and slightly of lavender. It is used frequently in perfumery not only to create floral, fruity nuances (e.g., rose) but also for citrus and lavender notes. A small amount is added to fruit aromas for shading.
Occurrence
Reported found in a large number of essential oils; Ceylon citronella, palmarose, lemongrass, petitgrain, neroi bigarade, geranium, coriander, lavender, carrot, sassafras, in various Callitris species (C verrucosa, C robusta, and others) and Eucalyptus species (E acervula, E urnigera, etc ) A 60% level has been reported in the essential oil of Eucalyptus macar- thuri and up to 50% in the essential oil of Orthodon citraliferum; also identifed in bitter orange essential oil and Cymbopogon citratus oil Also reported found in citrus peel oils and juices, black currants, pineapple, celery seed, cinnamon, ginger, pepper- mint oil, corn mint oil, nutmeg, mace, thymus, hop oil, beer, rum, grape wines, coffee, tea, passion fruit, tomato, almond, muscal grape, cardamom, coriander leaf and seed, tarragon, lovage, Ocimum basilicum, laurel, myrtle leaf and berry, rosemary, clary sage and calabash nutmeg
Uses
β-Geranyl Acetate is found in essential oils such as Moroccan commercial essential oils which has anti-oxidant, anti-inflammatory and anti-proliferative activities; and in Salvia scabiosifolia from Bulgaria.
Preparation
From geraniol by acetylation or by fractional distillation of essential oils in which it is present.
Definition
ChEBI: A monoterpenoid that is the acetate ester derivative of geraniol.
General Description
Clear colorless liquid with an odor of lavender.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Geranyl acetate should be protected from light. Geranyl acetate reacts with strong oxidizing agents.
Fire Hazard
Geranyl acetate is probably combustible.
Safety Profile
Mildly toxic by ingestion. A human skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
Purification Methods
Purify the fragrant smelling geranyl acetate by fractional distillation at as high a vacuum as possible. It is very soluble in EtOH but insoluble in H2O. [Beilstein 2 H 140, 2 I 65, 2 II 153, 2 III 299, 2 IV 204.]
Geranyl acetate Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Jayshree Aromatics Pvt.Ltd. | +91-9925031256 +91-9925031256 | Gujarat, India | 89 | 58 | Inquiry |
| Mruchem | +91-8087147166 +91-8087147166 | Gujarat, India | 52 | 58 | Inquiry |
| Privi Speciality Chemicals Ltd. | +91-2233043500 +91-2233043500 | Mumbai, India | 63 | 58 | Inquiry |
| Rossari Biotech Ltd. | +91-2261233800 +91-2261233800 | Mumbai, India | 57 | 58 | Inquiry |
| Silverline Chemicals | +91-9810339289 +91-9810339289 | Haryana, India | 71 | 58 | Inquiry |
| PSC Aromatics | +91-9655115000 +91-9443115000 | Tamil Nadu, India | 23 | 58 | Inquiry |
| Bhagat Aromatics Ltd | +91-1204044300 +91-9321155125 | Uttar Pradesh, India | 24 | 58 | Inquiry |
| U K Aromatics And Chemicals | +91-9820021461 +91-7057388635 | Maharashtra, India | 29 | 58 | Inquiry |
| Arpan Aromatics | +91-9824514546 +91-9824029204 | Gujarat, India | 59 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Jayshree Aromatics Pvt.Ltd. | 58 |
| Mruchem | 58 |
| Privi Speciality Chemicals Ltd. | 58 |
| Rossari Biotech Ltd. | 58 |
| Silverline Chemicals | 58 |
| PSC Aromatics | 58 |
| Bhagat Aromatics Ltd | 58 |
| U K Aromatics And Chemicals | 58 |
| Arpan Aromatics | 58 |
| A.J Chemicals | 58 |
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