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Sodium tetraborate

Sodium tetraborate Structure
CAS No.
1330-43-4
Chemical Name:
Sodium tetraborate
Synonyms
BORAX;Na2B4O7;SODIUM BORATE;BUFFER SOLUTION;Anhydrous borax;DI-SODIUM TETRABORATE;Sodium borate anhydrous;pH standard;Sodium tetraborate, anhydrous, for analysis, 99.5%;fr28
CBNumber:
CB6233954
Molecular Formula:
B4Na2O7
Molecular Weight:
201.22
MOL File:
1330-43-4.mol
MSDS File:
SDS
Modify Date:
2024/5/28 19:59:05

Sodium tetraborate Properties

Melting point 741 °C (lit.)
Boiling point 1575°C
Density 2.367 g/mL at 25 °C (lit.)
vapor pressure 7.3 hPa (1200 °C)
refractive index 1.501
Flash point 1575°C
storage temp. Store at +5°C to +30°C.
solubility H2O: 0.1 M at 20 °C, clear, colorless
form Solid
color White
Specific Gravity 2.367
PH 9.0-10.5 (25℃, 0.1M in H2O)
Water Solubility 26 g/L (20 ºC)
Sensitive Hygroscopic
λmax λ: 260 nm Amax: ≤0.020
λ: 280 nm Amax: ≤0.015
Merck 14,8590
Exposure limits ACGIH: TWA 2 mg/m3; STEL 6 mg/m3
NIOSH: TWA 1 mg/m3
Stability Stable. Incompatible with powdered metals.
InChIKey UQGFMSUEHSUPRD-UHFFFAOYSA-N
NIST Chemistry Reference Sodium borate(1330-43-4)
EPA Substance Registry System Sodium tetraborate (1330-43-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS08
Signal word  Danger
Hazard statements  H319-H360FD
Precautionary statements  P202-P264-P280-P305+P351+P338-P308+P313-P337+P313
Hazard Codes  Xn,Xi,T
Risk Statements  62-63-36/38-36/37/38-61-60
Safety Statements  36/37-24/25-26-36-23-45-53
RIDADR  UN 1760 8/PG 2
OEB C
OEL TWA: 1 mg/m3
WGK Germany  1
RTECS  ED4588000
34
TSCA  Yes
HS Code  28401100
NFPA 704
0
2 1

Sodium tetraborate price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 71997 Borax Anhydrous BioUltra, anhydrous, ≥99% 1330-43-4 100G ₹8595.05 2022-06-14 Buy
Sigma-Aldrich(India) 71997 Borax Anhydrous BioUltra, anhydrous, ≥99% 1330-43-4 500G ₹28242.43 2022-06-14 Buy
Sigma-Aldrich(India) 71997 Borax Anhydrous BioUltra, anhydrous, ≥99% 1330-43-4 1KG ₹33362.65 2022-06-14 Buy
Sigma-Aldrich(India) 71996 Borax Anhydrous puriss. p.a., anhydrous, ≥98.0% (T) 1330-43-4 250G ₹9471.88 2022-06-14 Buy
Sigma-Aldrich(India) 229946 Sodium tetraborate 99.998% trace metals basis 1330-43-4 5G ₹2478.93 2022-06-14 Buy
Product number Packaging Price Buy
71997 100G ₹8595.05 Buy
71997 500G ₹28242.43 Buy
71997 1KG ₹33362.65 Buy
71996 250G ₹9471.88 Buy
229946 5G ₹2478.93 Buy

Sodium tetraborate Chemical Properties,Uses,Production

Chemical Properties

Sodium borate, Na2B407.10H20, also known as sodium tetraborate and sodium pyrobomte, is a white crystalline powder that melts at 120°C (248 °F). Sodium borate in its natural impure form is also known as borax, Borax is a noncombustible (an inherent fire retardant), bluish-gray or green, odorless crystalline powder or granules. Sodium borate is used in glass and ceramic enamel mixes,detergents, fertilizers, pharmaceuticals, and photograph.

Uses

Sodium Tetraborate, is an important boron compound, which has a wide variety of applications. It is a component of many detergents, cosmetics, and enamel glazes. It is also used to make buffer solutions in biochemistry, as a fire retardant, as an anti-fungal compound for fiberglass, as a flux in metallurgy, neutron-capture shields for radioactive sources, a texturing agent in cooking, and as a precursor for other boron compounds.

Production Methods

Anhydrous borax is produced from borax through high temperature fusion. On cooling, the clear, glass-like material is ground into fine white granules. Because of its higher bulk density, it is preferred where storage space is limited. It is used principally in the manufacture of glass, ceramics, and enamel.

General Description

Pale yellow solid or thick liquid with a faint odor of detergent. Mixes with water. Soap bubbles may be produced.

Air & Water Reactions

Water soluble.

Reactivity Profile

SODIUM PEROXOBORATE is incompatible with the following: Zirconium, strong acids, metallic salts . The true peroxoborate has been reported to detonate on light friction. The common "tetrahydrate" is not a peroxoborate, Sodium tetraborate is relatively stable under mild grinding with other substances.

Health Hazard

No adverse effects from inhaling borax have been reported. Ingestion may cause acute or chronic effects; initial symptoms are nausea, vomiting, and diarrhea; these may be followed by weakness, depression, headaches, skin rashes, drying skin, cracked lips, and loss of hair; shock may follow ingestion of large doses and may interfere with breathing. Eye contact with powder or solutions may cause irritation; no chronic effects have been recognized, but continued contact should be avoided. Local skin irritation may result from contact with powder or strong solutions; the latter may cause chronic dermatitis on prolonged contact, and if skin is broken, enough boron may be absorbed to cause boron poisoning (symptoms are similar to those for ingestion).

Agricultural Uses

Sodium tetraborate, also called borax, sodium borate, sodium pyroborate and sodium tetraborate decahydrate (Na2B4O7.10H2O) is a type of borate, and is used as a fertilizer to reduce boron deficiency. It is a white salt, finely ground for fertilizer application.
Sodium tetraborate(Na2B4O7) and sodium metaborate (Na2B2O4) are non-selective, taken up by roots, and have an unknown mechanism of action. Boron accumulates in reproductive structures after translocation from roots. Boron compounds are used for long-term, nonselective weed control in industrial and power line areas in combination with triazine and urea herbicides.

Safety Profile

A nuisance dust. Experimental reproductive effects. When heated to decomposition it emits toxic vapors of B.

Potential Exposure

Borax is used as a soldering flux, preservative against wood fungus; and as an antiseptic. Used in ant poisons, for fly control around refuse and manure piles, as a larvicide. It is used in the manufacture of enamels and glazes, fiberglass insulation; sodium perborate bleach; in tanning, cleaning compounds; for fireproofing fabrics and wood; and in artificial aging of wood.

Purification Methods

Most of the water of hydration is removed from the decahydrate (see below) by evacuation at 25o for three days, followed by heating to 100o and evacuation with a high-speed diffusion pump. The dried sample is then heated gradually to fusion (above 966o), allowed to cool gradually to 200o, then tranferred to a desiccator containing P2O5 [Grenier & Westrum J Am Chem Soc 78 6226 1956]. [Becher in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I pp 794-795 1963.]

Incompatibilities

Dissolves in water forming a basic solution. Boron dust may form explosive mixture with air. Contact with strong oxidizers may be violent. Boron is incompatible with ammonia, bromine tetrafluoride, cesium carbide, chlorine, fluorine, interhalogens, iodic acid, lead dioxide, nitric acid, nitric oxide, nitrosyl fluoride, nitrous oxide, potassium nitrite, rubidium carbide, silver fluoride.

Waste Disposal

Borax, dehydrated: The material is diluted to the recommended provisional limit (0.10 mg/L) in water. The pH is adjusted to between 6.5 and 9.1 and then the material can be discharged into sewers or natural streams.

Sodium tetraborate Preparation Products And Raw materials

Global( 377)Suppliers
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Sodium tetraborate Spectrum

Buffer solution pH 9.00 (20°C) ZINC CHLORIDE - FORMIC ACID SOLUTION PHE ZINC ACETATE SOLUTION PHE sodiumborate,anhydrous sodiumboronoxide sodiumtetraborate(anhydrous) sodiumtetraborate(na2b4o7) sodiumtetraborate,anhydrous Sodium tetraborate, anhydrous (99.998%-B) (50 ppm K) PURATREM Borax glass-ground SodiuM tetraborate, anhydrous, for analysis, 99.5% 100GR BORAX, FUSED BORAX GLASS ANHYDROUSDISODIUMTETRABORATE Sodium tetraborate, anhydrous, Puratronic(R), 99.998% (metals basis) Sodium tetraborate, anhydrous, 99.95% (metals basis) Sodium tetraborate, anhydrous, 99.5% (metals basis) Borax, 5 Mole (Pentahydrate) BORAX ANHYDROUS extrapure AR Sodium tetraborate, anhydrous, Puratronic, 99.998% (metals basis) Boric acid - Sodium tetraborate buffer solution, Sodium tetraborate buffer solution Buffer solution HPCE pH 9.0 Sodium tetraborate buffer solution Sodium tetraborate buffer Sodium borate solution Sodium tetraborate, 99.5%, anhydrous, for analysis Sodium tetraborate, anhydrous, for analysis Sodium tetraborate,99.5%,for analysis,anhydrous pH standard-Borax pH standard-Sodium Tetraborate Decahydrate(Borax) di-Sodium tetraborate anhydrous, extra pure "Sodium tetraborate, anhydrous/ 98+%" "Sodium tetraborate, anhydrous/ 99.9%" "Sodium tetraborate, anhydrous/ 99.998%" anhydrousborax Antipyoninum B4-Na2-O7 borates,tetra,sodiumsalt,anhydrous borates,tetra,sodiumsalts(anhydrous) borates,tetra,sodiumsalts(pentahydrate) borax(anhydrous) borax,dehydrated di-Sodium tetraborate anhydrous 99.99 Suprapur di-Sodium tetraborate anhydrous for analysis ZIRCONYL NITRATE SOLUTION PHE boricacid(h2b4o7),disodiumsalt boricacid(h2b4o7),sodiumsalt Dehybor di-Sodiumtetraborate,anhydrou FB 48 fr28 fusedsodiumborate rasorite65 BORIC ACID DISODIUM SALT BUFFER 4.01 BUFFER SOLUTION SODIUM TETRABORATE Buffer solution pH 9.2 BUFFER/INDICATOR SOLUTION